Crystallisation of sodium sulfate: supersaturation and metastable phases   总被引：1，自引：0，他引：1  

Selma Genkinger  Andrew Putnis 《Environmental Geology》2007,52(2):329-337

Crystallisation of sodium sulfate solutions by evaporation under controlled climatic conditions has revealed the existence of crystalline hydrated sodium sulfate salts not previously reported. The sodium sulfate phase crystallising and the concentration of the solution at the point of crystallisation depends on the climatic conditions (temperature and evaporation rate). During the rehydration of the anhydrous sodium sulfate phase, thenardite, another previously unreported phase was formed prior to the nucleation of the stable phase, mirabilite Na₂SO₄ · 10H₂O. The addition of organic inhibitors changes both the crystallisation and the rehydration behavior in this system.  相似文献   

Fluid flow during exhumation of deeply subducted continental crust: zircon U-Pb age and O-isotope studies of a quartz vein within ultrahigh-pressure eclogite   总被引：15，自引：0，他引：15  

Y.-F. ZHENG  T.-S. GAO  Y.-B. WU  B. GONG  X. M. LIU 《Journal of Metamorphic Geology》2007,25(2):267-283

Quartz veins in high‐pressure to ultrahigh‐pressure metamorphic rocks witness channelized fluid flow that transports both mass and heat during collisional orogenesis. This flow can occur in the direction of changing temperature/pressure during subduction or exhumation. SHRIMP U‐Pb dating of zircon from a kyanite‐quartz vein within ultrahigh‐pressure eclogite in the Dabie continental collision orogen yields two age groups at 212 ± 7 and 181 ± 13 Ma, which are similar to two groups of LA‐ICPMS age at 210 ± 4 and 180 ± 5 Ma for the same sample. These ages are significantly younger than zircon U‐Pb ages of 224 ± 2 Ma from the host eclogite. Thus the two age groups from the vein date two episodes of fluid flow involving zircon growth: the first due to decompression dehydration during exhumation, and the second due to heating dehydration in response to a cryptic thermal event after continental collision. Laser fluorination O‐isotope analyses gave similar δ¹⁸O values for minerals from both vein and eclogite, indicating that the vein‐forming fluid was internally derived. Synchronous cooling between the vein and eclogite is suggested by almost the same quartz–mineral fractionation values, with regularly decreasing temperatures that are in concordance with rates of O diffusion in the minerals. While the quartz veining was caused by decompression dehydration at 700–650 °C in a transition from ultrahigh‐pressure to high‐pressure eclogite‐facies retrogression, the postcollisional fluid flow was retriggered by heating dehydration at ～500 °C without corresponding metamorphism. In either case, the kyanite–quartz vein formed later than the peak ultrahigh‐pressure metamorphic event at the Middle Triassic, pointing to focused fluid flow during exhumation rather than subduction. The growth of metamorphic zircon in the eclogite appears to have depended on fluid availability, so that their occurrence is a type of geohygrometer besides geochronological applicability to dating of metamorphic events in orogenic cycles.  相似文献   

When epitaxy controls garnet growth     

R. SPIESS  C. GROPPO  R. COMPAGNONI 《Journal of Metamorphic Geology》2007,25(4):439-450

Within a mica schist from the coesite-bearing Brossasco-Isasca Unit (Western Alps), microstructural analysis shows that Alpine garnet grains are aligned with the crenulated foliation. Garnet crystallographic orientation was analysed with electron backscatter diffraction (EBSD): the obtained crystallographic dispersion patterns and distribution patterns of misorientation axes suggest a strong parallelism of {110} garnet planes with a 56°W-dipping foliation. The data are interpreted as evidence for an epitaxial growth of garnet upon (001) biotite planes, sometime during and/or after dispersion of the biotite/garnet crystals from their initially foliation-parallel orientation by rotation about the Alpine crenulation axis. This interpretation is based on the comparison of the measured EBSD data with: (i) theoretical dispersion trajectories of garnet crystallographic data, (ii) numerically modelled pole figures, and (iii) numerically modelled misorientation axis distribution patterns. Our data suggest that epitaxial growth of garnet upon biotite is allowed by distortion of the pseudohexagonal basal oxygen ring structure on (001) biotite surfaces, and that distortion is driven by introduction of missing ions. Our data further suggest that the spatial distribution of precursor phases influences the distribution patterns of garnet within mica schists.  相似文献   

Thermal evolution of the Earth: Secular changes and fluctuations of plate characteristics   总被引：1，自引：0，他引：1  

S. Labrosse  C. Jaupart 《Earth and Planetary Science Letters》2007,260(3-4):465-481

The average secular cooling rate of the Earth can be deduced from compositional variations of mantle melts through time and from rheological conditions at the onset of sub-solidus convection at the end of the initial magma ocean phase. The constraint that this places on the characteristics of mantle convection in the past are investigated using the global heat balance equation and a simple parameterization for the heat loss of the Earth. All heat loss parameterization schemes depend on a closure equation for the maximum age of oceanic plates. We use a scheme that accounts for the present-day distribution of heat flux at Earth's surface and that does not depend on any assumption about the dynamics of convection with rigid plates, which remain poorly understood. We show that heat supply to the base of continents and transient continental thermal regimes cannot be ignored. We find that the maximum sea floor age has not changed by large amounts over the last 3 Ga. Calculations lead to a maximum temperature at an age of about 3 Ga and cannot be extrapolated further back in time. By construction, these calculations are based on the present-day tectonic regime characterized by the subduction of large oceanic plates and hence indicate that this regime did not prevail until an age of about 3 Ga. According to this interpretation, the onset of rapid continental growth occurred when the current plate regime became stable.  相似文献   

Cenozoic basin development and its indication of plateau growth in the Xunhua-Guide district   总被引：1，自引：0，他引：1  

LIU ShaoFeng  ZHANG GuoWei  P.L.HELLER 《中国科学D辑(英文版)》2007,50(Z2):277-291

The Xunhua, Guide and Tongren Basins are linked with the Laji Mountain and the northern West Qinling thrust belts in the Xunhua-Guide district. Basin depositional stratigraphy consists of the Oligocene Xining Group, the uppermost Oligocene-Pliocene Guide Group and the Lower Pleistocene. They are divided into three basin phases by unconformities. Basin phase 1 is composed of the Xining Group, and Basin phase 2 of the Zharang, Xiadongshan, Herjia and Ganjia Conglomerate Formations in the Guide Group, and Basin phase 3 of the Gonghe Formation and the Lower Pleistocene. Three basin phases all develop lacustrine deposits at their lower parts, and alluvial-braided channel plain depositional systems at upper parts, which constitute a coarsening-upward and progradational sequence. Basin deposition, paleocurrent and provenance analyses represent that large lacustrine basin across the Laji Mountain was developed and sourced from the West Qinling thrust belt during the stage of the Xining Group (Basin phase 1), and point-dispersed alluvial fan-braided channel plain deposition systems were developed beside the thrust and uplifted Laji Mountain and sourced from it, as thrusting migrated northwards during the stage of the Guide Group (Basin phase 2). Evolution of basin-mountain system in the study area significantly indicates the growth process of the distal Tibetan Plateau. The result shows that the Tibetan Plateau expanded to the northern West-Qinling at Oligocene (29―21.4 Ma) by means of northward folded-and-thrust thickening and uplifting and frontal foreland basin filling, and across the study area to North Qilian and Liupan Mountain at the Miocene-Pliocene (20.8―2.6 Ma) by means of two-sided basement-involved-thrust thickening and uplifting and broken foreland basin filling, and the distant end of Tibetan Plateau behaved as regional erosion and intermontane basin aggradational filling during the Pliocene and early Pleistocene (2.6―1.7 Ma).  相似文献   

A simple approach for determining particle size enlargement mechanisms in nickel reduction     

V.C. Taty Costodes  C.F. MausseK. Molala  A.E. Lewis 《International Journal of Mineral Processing》2006

This paper examines the active mechanisms responsible for the size enlargement of nickel metal particles during reduction by hydrogen gas. The population balance, related to particle size distribution, is discretized and solved with the method of moments to model the experimental data. This data was generated in a solution of intermittently constant supersaturation during the batch reduction in an 11,000 l of autoclave. PSD and mass distributions were determined by periodically removing suspension samples. In the proposed model, only the growth mechanism is taken into account and aggregation is ignored. Comparison of simulated and experimental PSD and mass distributions show that growth was not the only active mechanisms. Results from the plant indicate that there is an increase in particle size as the cycle progresses. The model generally underpredicts the growth shift in the PSDs' for the early and the larger densifications although it correctly predicts the growth shift in the middle densifications. Constant growth is therefore not the exclusive controlling mechanism. The findings have been confirmed by the trend of the zeroth moment as a function of time.  相似文献   

Heterogeneous growth of cordierite in low P/T Tsukuba metamorphic rocks from central Japan     

K. Miyazaki 《Journal of Metamorphic Geology》2001,19(2):155-164

This paper examines the spatial statistics of matrix minerals and complex patterned cordierite porphyroblasts in the low‐pressure, high‐temperature (low P/T) Tsukuba metamorphic rocks from central Japan, using a density correlation function. The cordierite‐producing reaction is sillimanite + biotite + quartz = K‐feldspar + cordierite + water. The density correlation function shows that quartz is distributed randomly. However, the density correlation functions of biotite, plagioclase and K‐feldspar show that their spatial distributions are clearly affected by the formation of cordierite porphyroblasts. These observations suggest that cordierite growth occurred through a selective growth mechanism: quartz adjacent to cordierite has a tendency to prevent the growth of cordierite, whereas other matrix minerals adjacent to cordierite have a tendency to enhance the growth of cordierite. The density correlation functions of complex patterned cordierite porphyroblasts show power‐law behaviour. A selective growth mechanism alone cannot explain the origin of the power‐law behaviour. Comparison of the morphology and fractal dimension of cordierite with two‐dimensional sections from a three‐dimensional diffusion‐limited aggregation (DLA) suggests that the formation of cordierite porphyroblasts can be modelled as a DLA process. DLA is the simple statistical model for the universal fractal pattern developed in a macroscopic diffusion field. Diffusion‐controlled growth interacting with a random field is essential to the formation of a DLA‐like pattern. The selective growth mechanism will provide a random noise for the growth of cordierite due to random distribution of quartz. Therefore, a selective growth mechanism coupled with diffusion‐controlled growth is proposed to explain the power‐law behaviour of the density correlation function of complex patterned cordierite. The results in this paper suggest that not only the growth kinetics but also the spatial distribution of matrix minerals affect the progress of the metamorphic reaction and pattern formation of metamorphic rocks.  相似文献   

Bioenergetic responses in green lipped mussels (Perna viridis) as indicators of pollution stress in Xiamen coastal waters, China     

Wang S  Hong H  Wang X 《Marine pollution bulletin》2005,51(8-12):738-743

Samples of green lipped mussels (Perna viridis) were collected from three sites (Huoshao, I’Maluan and Tong’an) around Xiamen coastal waters, where levels of various trace organic pollutants have been studied. Samples were also collected at a “cleaner” reference site near Dongshan Island for comparison. Clearance rate, absorption efficiency and oxygen consumption of the mussels were measured under controlled laboratory condition; organic pollutants in their tissues were also analyzed. Scope for growth (SFG) was employed as a general biomarker to evaluate the stress of pollutants. Specimens from Tong’an site had the lowest SFG values (1.14 J/h/g); while specimens from the I’Maluan site and Huoshao site had SFG values of 5.01 and 6.72 J/h/g, respectively. Specimens from Dongshan (reference site) had a relatively high SFG value of 10.96 J/h/g. There was a significant negative correlation between the SFG of the different populations of green lipped mussels and the concentration of DDT in their tissues.  相似文献   

成矿动力系统在混沌边缘分形生长——一种新的成矿理论与方法论(上)   总被引：21，自引：3，他引：18  

於崇文 《地学前缘》2001,8(3):9-28

“成矿动力系统在混沌边缘分形生长”理论是笔者将复杂性理论及非线性科学与矿床地质学相结合 ,对中国扬子古陆周缘六个矿集区的基本范式进行长期系统研究所取得的总结性成果。研究指出 ,成矿系统总体上是开放、远离平衡、时空延展的动力学系统。它们具有复杂性和自组织临界性的内禀基本属性 ,并且在混沌边缘分形生长。该理论以“地质作用与时 空结构是一切地质现象的本质与核心”的自然哲学理念作为根本立足点 ,建立起一种具有普适性的理论框架。然后进一步将其具体化为三大组成部分 ,即 ( 1)矿床的动力学属性 ,( 2 )矿床地质学场 ,( 3 )成矿系统的演化。体现了成矿作用 (其核心为成矿作用动力学 )、空间结构 (矿床地质学场 )和时间结构 (成矿系统的演化 )三位一体的整体耦合与交织 ,从而又使该理论具有包容性。在此基础上进而归纳出“成矿动力系统在混沌边缘分形生长”的 5项判定准则以及表征这些准则的 10项相应的动力学行为特征。最后笔者提出“矿质局部活化导致成矿的发生”的命题 ,拟定了“成矿的发生”的重要科学问题 ,以“元胞非线性网络”(CNN)作为复杂性的范式 ,定量揭示成矿的发生 ,并对矿床在混沌边缘作精确定位 ,对“成矿动力系统在混沌边缘”理论作进一步的延伸、深化与发展。该理论在矿?  相似文献   

成矿动力系统在混沌边缘分形生长——一种新的成矿理论与方法论(下)   总被引：11，自引：2，他引：9  

於崇文 《地学前缘》2001,8(4):471-489

:“成矿动力系统在混沌边缘分形生长”理论是笔者将复杂性理论及非线性科学与矿床地质学相结合 ,对中国扬子古陆周缘六个矿集区的基本范式进行长期系统研究所取得的总结性成果。研究指出 ,成矿系统总体上是开放、远离平衡、时空延展的动力学系统。它们具有复杂性和自组织临界性的内禀基本属性 ,并且在混沌边缘分形生长。该理论以“地质作用与时 空结构是一切地质现象的本质与核心”的自然哲学理念作为根本立足点 ,建立起一种具有普适性的理论框架。然后进一步将其具体化为三大组成部分 ,即 ( 1)矿床的动力学属性 ,( 2 )矿床地质学场 ,( 3 )成矿系统的演化。体现了成矿作用 (其核心为成矿作用动力学 ) ,空间结构 (矿床地质学场 )和时间结构 (成矿系统的演化 )三位一体的整体耦合与交织 ,从而又使该理论具有包容性。在此基础上进而归纳出“成矿动力系统在混沌边缘分形生长”的 5项判定准则以及表征这些准则的 10项相应的动力学行为特征。最后笔者提出“矿质局部活化导致成矿的发生”的命题 ,拟定了“成矿的发生”的重要科学问题 ,以“元胞非线性网络”(CNN)作为复杂性的范式 ,定量揭示成矿的发生 ,并对矿床在混沌边缘作精确定位 ,对“成矿动力系统在混沌边缘”理论作进一步的延伸、深化与发展。该理论在?  相似文献