金矿样品的几种溶样方法   总被引：4，自引：0，他引：4  

杨明荣  孙鹏  牟长贤  石爱萍 《黄金地质》2004,10(1):68-70

通过王水、封闭和烧杯敞口及聚乙烯溶样瓶封闭溶样等方法，对含Au矿样的试样分解、溶样体系及各种溶样方法的对比表明，利用聚乙烯溶样瓶，采用HNO3 NaCl KMnO4 NH4HF2溶样体系，在水浴锅中封闭溶样40min，矿样中的Au即可完全分解。经国家标准物质分析验证，结果与标准值相符。封闭溶样可以避免样品外溢、进溅，使分析结果更准确可靠，降低成本，减少环境污染，适用于大批量样品分析。  相似文献   

贵州百花湖分层晚期有机质降解过程与溶解N₂O循环   总被引：7，自引：0，他引：7       下载免费PDF全文

王仕禄  刘丛强  万国江  陶发祥  李军  朱兆洲  吕迎春 《第四纪研究》2004,24(5):569-577

百花湖是一个具有季节性分层的富营养小型湖泊,在秋季湖水倒转期经常发生水质恶化事件,碳氮循环出现异常。文章研究特选择在秋初,湖泊分层开始消失时,测定了湖水中不同深度的N₂O,CH₄,CO₂,有机和无机碳同位素以及其他化学参数变化。结果发现:采样时百花湖在约6m和16m深度附近出现了两个温度不连续层(SDL和PDL),并影响到有机颗粒的沉降和分解。相对而言,有较多的有机质在这两个层内发生降解,但降解的途径有所不同,上部主要是有氧降解,下部则主要是无氧降解过程。N₂O的产生和消耗与有机质的降解过程完全对应:PDL层以上,ΔN₂O与AOU的线性关系反映了N₂O主要形成于硝化作用;PDL层以下反硝化作用导致N₂O严重不饱和;PDL内位于硝化作用和反硝化作用过渡带的N₂O峰,显然是硝化与反硝化联合作用的结果。PDL层内较大的CH₄浓度变化梯度,说明嗜甲烷细菌可能通过氧化NH+4贡献了部分N₂O。百花湖秋、冬季表层湖水N₂O都是过饱和的,都是大气N₂O的源,依据分子扩散模型计算湖泊N₂O的释放通量在12～14μmol/m·day之间,秋、冬季没有明显的差别。秋季底层湖水的反硝化作用是湖泊N₂O的汇,其消耗通量与表层的释放通量基本相当。  相似文献   

Approximate modal decomposition of inelastic dynamic responses of wall buildings     

C. Sangarayakul  P. Warnitchai 《地震工程与结构动力学》2004,33(9):999-1022

Two approximate methods for decomposing complicated inelastic dynamic responses of wall buildings into simple modal responses are presented. Both methods are based on the equivalent linear concept, where a non‐linear structure is represented by a set of equivalent linear models. One linear model is used for representing only one vibration mode of the non‐linear structure, and its equivalent linear parameters are identified from the inelastic response time histories by using a numerical optimizer. Several theoretical relations essential for the modal decomposition are derived under the framework of complex modal analysis. Various numerical examinations have been carried out to check the validity of the proposed modal decomposition methods, and the results are quite satisfactory in all cases. Fluctuating bending moment and shear at any location along the wall height contributed by each individual vibration mode can be obtained. Modal contributions to shear and flexural strength demands, as well as the corresponding modal properties, under various seismic loading conditions can also be identified and examined in detail. Furthermore, the effects of higher vibration modes on seismic demands of wall buildings are investigated by using the modal decomposition methods. Several new insights into the complicated inelastic dynamics of multi‐story wall buildings are presented. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

湖南汛期降水异常的时空分布特征研究   总被引：16，自引：5，他引：16  

刘会玉  林振山  张明阳 《热带气象学报》2004,20(4):409-418

利用湖南19个测站23年(1959～2001年)4～9月的降水量资料，用EOF、REOF、小波分析对湖南汛期降水的特征场分布、分区特征、周期性和突变性等时空分布特征进行了诊断研究。研究结果表明：EOF分析得到的前三个典型场可以很好的反映湖南汛期降水空间分布的异常结构，即具有整体一致的空间结构，南北相反的空间结构，中部和周围地区相反变化的空间结构。旋转后的前6个空间模态可以较好地代表湖南汛期降水的6个异常敏感区：湘北、湘中、湘南、湘东南、湘西、湘东北。利用小波分析方法研究湖南汛期降水的周期性及其突变性发现，湖南汛期降水存在着明显的3年、7年和23年的特征时间尺度和周期性振荡；并且在今后相当长的一段时间内，湖南汛期的降水将逐年减少，并将转入干旱时期。  相似文献   

基于小波分解的西太平洋副热带高压模糊推理预测   总被引：3，自引：2，他引：3  

董兆俊  张韧 《热带气象学报》2004,20(4):419-425

基于NCEP/NCAR再分析资料,讨论了西太平洋副高脊线与其前期位置的相互关系,并在此基础上用小波分解和自适应模糊推理方法,对副高脊线进行集成建模和预测.基于小波分解重构的副高脊线短期活动集成预测结果表明,该方法可有效降低预报难度,明显改进和提高了副高脊线短期活动的预报准确率.  相似文献   

沙尘暴常规观测资料中若干问题的解析   总被引：3，自引：2，他引：3       下载免费PDF全文

周自江  艾 《应用气象学报》2004,15(Z1):60-67

沙尘暴常规观测资料主要来自地面气象观测系统,是揭示沙尘暴的时空分布特征和变化规律的重要基础,其内在属性明显地受到地面气象观测规范和统计规范的制约,而且同样明显地受到两个规范变革的影响,但是这些问题在以往的沙尘暴研究中没有引起足够的重视,常常被忽视掉了,因此最终形成了一些似是而非的认识.该文从中国沙尘暴的观测规范和统计规范入手,探讨了其变革对沙尘暴内在统计特征的影响.另外,文章还分析了沙尘暴与其它沙尘天气的同日出现问题,以及沙尘暴资料时间序列的统计分布特征.  相似文献   

相空间中划分大尺度异常雨型的初步研究   总被引：5，自引：2，他引：5  

任宏利  高丽  张培群  李维京 《气象学报》2004,62(4):459-467

文中针对以往雨型研究中的不足 ,从动力学角度将相空间引入到大尺度异常雨型的划分 ,通过估计EOF相平面上的概率密度函数、并确定局部极大值区域来划分主要雨型。分析表明 ,新雨型不仅再现了传统的 3类雨型特征 ,还得到了其他分型 ,并且能够反映出异常降水分布的季节内低频变化 ;分别采用 10和 2 0d低通滤波数据划分的雨型形态比较接近 ,但其种类、持续性和季节内分布等特征存在一定差异 ;雨型的气候分布与季风雨带有一定对应关系 ,其形成与夏季风异常关系密切。通过对简单直观的二维相平面问题的探讨 ,不仅证实了在相空间中划分大尺度雨型的可行性 ,也为进一步在高维空间中讨论雨型问题提供了依据。  相似文献   

Paleozoic serpentinite-enclosed chromitites from Tehuitzingo (Acatlán Complex, southern Mexico): a petrological and mineralogical study     

J. A. Proenza  F. Ortega-Gutirrez  A. Camprubí  J. Tritlla  M. Elías-Herrera  M. Reyes-Salas 《Journal of South American Earth Sciences》2004,16(8):129

The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe³⁺ and Fe²⁺.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex.  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献   

Asymptotic Analysis and Layer Decomposition for the Couplex Exercise     

Stephane Del Pino  Olivier Pironneau 《Computational Geosciences》2004,8(2):149-162

This document explores the possibilities of multiscale expansions and domain decomposition to solve part of the Couplex 1 exercise. We concentrate on the hydrostatic pressure and show that the slenderness of the domain and the large variations of the Darcy constants allows an analytical approximation which our test reveals to be true to relative errors smaller than 10^–3. The numerical tests are done in 2D with freefem+ and in 3D with freefem3D. Some considerations are also given for Iodine transport.  相似文献