安徽省大别山南部宿松杂岩变质作用研究   总被引：7，自引：13，他引：7  

魏春景  单振刚 《岩石学报》1997,13(3):356-368

宿松杂岩的变质作用可分为３个阶段：早期、主期和晚期阶段。主期阶段的矿物组合在云母片岩中为石榴石＋多硅白云母＋石英＋磁铁矿±钠云母±绿帘石／黝帘石；在白云母钠长（二长）片岩和片麻岩中为石榴石＋多硅白云母＋钠长石＋石英＋绿帘石／黝帘石±冻蓝闪石；在石榴石钠长角闪岩中为石榴石＋冻蓝闪石＋钠长石＋黝帘石＋石英±钠云母±金红石／磁铁矿。根据多种地质温压计和变质反应可以推测主期变质条件为：Ｔ＝５２０℃～５８０℃，Ｐ＝１．２～１．４ＧＰａ，地热梯度为１２℃／ｋｍ，相当于高压过渡型。晚期阶段变质条件为：Ｔ＝４６０℃～４８０℃，Ｐ＝０．６～０．７ＧＰａ，为中压绿帘角闪岩相。宿松杂岩的变质条件介于其南部的蓝闪绿片岩相和北部的榴辉岩相之间，三者是扬子板块向华北板块之下俯冲到不同深度的产物。  相似文献   

人工合成宝石级翡翠的研究   总被引：4，自引：0，他引：4  

朱成明  金志升 《矿物学报》1997,17(3):245-249

本文以对化学试剂为原料，用静奇谈怪论同温高压固相转变法合成宝石级翡翠的机理和工艺条件进行了实验研究，测定了与硬玉化学组分相同的玻璃物质的高压熔融曲线和固相转变的区域，提出了在熔融曲线左侧附近固相区生长优质硬玉的观点，以及在宝石级悲翠合成中的若干技术问题。  相似文献   

Partitioning of elements between peridotite and H₂O at 2.0–3.0 GPa and 900–1100°C, and application to models of subduction zone processes     

John C. Ayers  Sondra K. Dittmer  Graham D. Layne 《Earth and Planetary Science Letters》1997,150(3-4):381-398

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Study on simulation of spatial correlative earthquake ground motion field     

Xiao-Jun Li  Feng-Xin Zhao  Yu-Xian Hu 《地震学报(英文版)》1997,10(2):267-271

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Aerosol polarized phase function and single-scattering albedo retrieved from ground-based measurements     

Zhengqiang Li  Philippe Goloub  Claude Devaux  Xingfa Gu  Yanli Qiao  Fengsheng Zhao  Hongbin Chen 《Atmospheric Research》2004,71(4):233-241

Aerosol optical parameters, polarized phase function and single-scattering albdeo, have been retrieved from ground-based sun photometer measurements in Beijing 2003. The measured aerosol optical thickness varies from 0.12 to 0.77 with an average value of 0.39. The measured Ångström coefficient ranges from 0.75 to 1.47 with an average value of 1.21. The retrieved single-scattering albedo at 870 nm is within the 0.76–0.94 range and the average value is 0.85, suggests there are considerable aerosol absorptions in Beijing. The maximum value of retrieved polarized phase function at 870 nm ranges from 0.068 to 0.225 with an average value of 0.16, and it illustrates good correlations with the Ångström coefficient, i.e. the relative size of aerosol particles. Analyses of measurements and theoretical calculations show the polarized phase function is sensitive to aerosol size distribution and complex refractive index, especially the imaginary part of the refractive index which denotes aerosol light absorbing effects. These results suggest that the polarized phase function is an effective and unique aerosol optical parameter and is able to improve the retrieval of aerosol physical properties.  相似文献   

Observational and Numerical Study on the Influence of Large-Scale Flow Direction and Coastline Shape on Sea-Breeze Evolution     

Robert C. Gilliam  Sethu Raman  Dev Dutta S. Niyogi 《Boundary-Layer Meteorology》2004,111(2):275-300

In this study radar, surface observations and numericalsimulations are used to examine the inland penetrationand intensity of the sea breeze during various large-scaleflow regimes along the curved coastline of the Carolinas,U.S.A. The results clearly indicate that the flow directionrelative to the curved coastline has a significant effecton the sea-breeze evolution.Overall, during northerly flow regimes alongthe curved North Carolina coast, observationsand numerical simulations show that the sea-breezefront has a tendency to remain close to the south-facingcoast. During these same flow regimes the frontmoves further inland relative to the east-facingcoast. The sea-breeze front during westerly flowcases progressed further inland relative to the southcoast and less so from the east-facing coastline.South-westerly flow allows the sea breeze to moveinland from both coastlines but the coastal shapeinfluence makes the inland penetration less fromthe easterly facing beaches. During periods of lightonshore flow (south-east), the sea breeze movesconsiderable distances inland but is not discernableuntil later in the afternoon. The simulations indicatedthat the sea-breeze intensity is greatest (least) when thelarge-scale flow direction has an offshore (onshore)component. Model results indicate the existence of astrong front well inland in the late afternoon duringlight onshore flow. Also noted was that the simulatedsea-breeze front develops earlier in the afternoon duringoffshore regimes and later in the day as the large-scaleflow becomes more onshore. It is concluded that thecoastline shape and coast-relative flow direction areimportant factors in determining how the sea-breezecirculation evolves spatially.  相似文献   

Molecular modeling of the 10-Å phase at subduction zone conditions     

Jianwei Wang 《Earth and Planetary Science Letters》2004,222(2):517-527

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.  相似文献   

四川新康风化淋滤型海泡石的热相变研究   总被引：3，自引：0，他引：3  

王吉中  李胜荣  江永宏 《矿物学报》2004,24(1):55-60

以四川新康风化淋滤型海泡石为研究对象，利用X射线衍射分析和红外光谱分析技术，对海泡石的热相变过程及特征进行了研究。结果发现，四川新康风化淋滤型海泡石的相变过程与沉积型、热液型海泡石相变过程明显不同，其相变过程可以划分为两个阶段：800℃以下保持海泡石相；800℃以上海泡石相转化为斜顽辉石相。  相似文献   

Paleozoic serpentinite-enclosed chromitites from Tehuitzingo (Acatlán Complex, southern Mexico): a petrological and mineralogical study     

J. A. Proenza  F. Ortega-Gutirrez  A. Camprubí  J. Tritlla  M. Elías-Herrera  M. Reyes-Salas 《Journal of South American Earth Sciences》2004,16(8):129

The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe³⁺ and Fe²⁺.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex.  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献