The effect of gas-phase chemistry on aqueous-phase sulfur dioxide oxidation rates     

William R. Stockwell 《Journal of Atmospheric Chemistry》1994,19(3):317-329

The rates and mechanisms of both gas and liquid phase reactions for the oxidation of sulfur dioxide play an important role in the production of atmospheric acids and aerosol particles. Rhodeet al. (1981) concluded that sulfate production rates were highly non-linear functions of sulfur dioxide emission rates. Their modelling study used an HO _x termination mechanism for the HO—SO₂ reaction in the gas-phase. Stockwell and Calvert (1983) determined that one of the products of the overall reaction of HO with sulfur dioxide was an HO₂ radical. The National Research Council (1983) using a version of the Rhodeet al. (1981) model modified to include HO₂ production from the HO—SO₂ reaction concluded that sulfate production becomes much more linear with respect to reductions in sulfur dioxide emissions. However, the cause of this increased linearity was not explained by the National Research Council report. It is demonstrated that the increased linearity is due to the coupling of gas-phases and aqueous phase chemistry. The gas-phase sulfur dioxide oxidation mechanism has a very significant effect on hydrogen perodide production rates.  相似文献   

Deposition of trace substances via cloud interception on a coniferous forest at Kleiner Feldberg     

S. Pahl  P. Winkler  T. Schneider  B. Arends  D. Schell  R. Maser  W. Wobrock 《Journal of Atmospheric Chemistry》1994,19(1-2):231-252

A resistance model to calculate the deposition of cloud droplets on a coniferous forest and some improved parameterizations of the indispensable input parameters are described. The deposition model is adapted to the coniferous forest at the Kleiner Feldberg site and verified by the data of a drip water monitoring station below the forest canopy. The measurements of liqud water content, wind speed and trace substance compounds in cloud water of the Ground-based Cloud Experiment (GCE) at Kleiner Feldberg in 1990 are used to calculate the cloud water deposition fluxes and the deposition of trace substances via cloud water interception. The calculated deposition of trace substances via cloud water interceptions is three to six times higher than via rain during the experiment. On a long term data basis the yearly amount of cloud water deposition is 180 mm year^–1 at Kleiner Feldberg site (840 m a.s.l.) while the precipitation amount is 1030 mm year^–1. Due to higher trace substance concentrations in cloud water compared to rain the ionic deposition via cloud water interception and via precipitation were assessed to be of comparable magnitude.  相似文献   

论雾与污染的关系   总被引：7，自引：1，他引：7  

周斌斌 《气象》1994,20(9):19-24

简述了近年来雾的研究进展，并从雾的酸化、雾层内污染物的扩散、雾层对污染物的清除、污染物对雾形成与发展的影响等方面讨论了雾与大气污染的关系。  相似文献   

Physical and chemical characteristics of a metal-contaminated overbank deposit,west-central South Dakota,U.S.A.     

Donna C. Marron 《地球表面变化过程与地形》1989,14(5):419-432

A metal-contaminated overbank deposit in west-central South Dakota resulted from the discharge of a large volume of mine tailings into a river system between the late 1800s and 1977. The deposit along the Belle Fourche River is typically up to 2 m thick and extends about 90 m away from the channel along the insides of meander bends. The sediments contain above-background levels of copper, iron, manganese, zinc, and particularly arsenic, which is commonly two orders of magnitude above background level in the contaminated sediments. Carbonate minerals in the deposit limit the desorption of arsenic by preventing acid formation. Arsenic concentrations provide a measure of the dilution of mine tailings by uncontaminated sediment. The arsenic appears to have been transported and deposited as arsenopyrite, but is now at least partially associated with iron oxides and hydroxides. Within individual samples, arsenic concentration has an inverse relation with grain size that results from the more efficient accumulation of arsenic on the greater surface area of the smaller particles. Arsenic concentration is inversely related to the sample weight percent finer than 16 μm, however, as a consequence of the dilution of the contaminated sediments by uncontaminated sediment with a finer grain-size distribution. Dilution by uncontaminated sediment from tributaries cause arsenic concentrations to decrease by a factor of 3 along 100 km of floodplain. An influx at high streamflow of uncontaminated sediment from terraces and the premining floodplain as well as from tributaries causes arsenic concentrations in parts of the contaminated deposit that are farthest away from the channel to be two to three times less than arsenic concentrations in overbank sediment that is immediately adjacent to the channel.  相似文献   

Trace elements in alluvia of the upper Vistula as indicators of palaeohydrology     

Kazimierz Klimek  Lucyna Zawilinska 《地球表面变化过程与地形》1985,10(3):273-280

In the Vistula valley near Góra, at the northern foreland of the Carpathians Mountains, there are young alluvia deposited in the historical period. These alluvia are difficult to date precisely because of the lack of organic interbedded material. In the Vistula drainage basin upstream of Góra since the second half of 18th century small centres of metal, textile, motor, and petrochemical industries have been developed. Concentrations of trace elements such as: Cr, Mn, Co, Ni, Cu, Zn, Cd, Pb, and of some macroelements were used as indicators of the age of different alluvial fills. The main part of the Vistula valley floor was built up by sediment accumulation before the development of industry but after the medieval phase of rural colonization of the Carpathians. Deposits filling the abandoned channels dissecting the valley floor have an increased content of some trace elements and deposits date from the second half of the 18th century, when the first foundries and blacksmith's shops were developed. A drastic increase of concentration of the most abundant trace elements in the youngest alluvial fill indicates that the fill dates from the last decade of rapid industrial development.  相似文献   

Aspects of the cycle of inorganic nitrogen compounds in the tropical rain forest of the Ivory Coast     

Jean Servant  Robert Delmas  Jacques Rancher  Marcel Rodriguez 《Journal of Atmospheric Chemistry》1984,1(4):391-401

A partial balance of mineral N is given for the basins of two coastal rivers in a forest zone in the Ivory Coast. The dry and wet depositions on the basin surfaces is given for particulate matter (NO₃ ^–, NH₄ ⁺). The quantity of mineral N washed away in the rivers is evaluated. The losses from leaching of the soils by rainwater are about 0.33 to 1.0% of the atmospheric depositions for NH₄ ⁺–N and 2.2 to 5.8% for NO₃ ^––N. The yearly atmospheric input of N compounds to the ecosystem, about 1.4 g N m^–2 y^–1, is at least 14% of mineral N formed in the soils and is therefore quite significant.  相似文献   

尤溪地区侏罗系梨山组沉积岩沉积环境分析     

陈斯盾 《福建地质》1995,14(2):132-138

本文在１：５万尤溪县等四幅区域调研工作的基础上，就本区广泛分布的梨山组沉积岩的沉积环境。通过沉积地层的基本层序划分、地方性剖面模式层序的建立及采用相分析，划分出辫状河及交织河沉积。辫状河积的河道宽、深化值大、沙滩及坝形成侧向连续的带状砂体。细粒沉积薄而少，多呈不连续状，构成“砂包泥”的宏观特征，交织河流具低梯度、低弯度、快速填积的低能及广阔的洪泛盆地，河道沉积的砂体在侧向上包含于细粒沉积物中，由于  相似文献   

Anthropogenic nitrogen deposition induces rapid ecological changes in alpine lakes of the Colorado Front Range (USA)   总被引：10，自引：3，他引：7  

Alexander P. Wolfe  Jill S. Baron  R. Jack Cornett 《Journal of Paleolimnology》2001,25(1):1-7

Recent sediments from two alpine lakes (> 3300 m asl) in the Colorado Front Range (USA) register marked and near-synchronous changes that are believed to represent ecological responses to enhanced atmospheric deposition of fixed nitrogen from anthropogenic sources. Directional shifts in sediment proxies include greater representations of mesotrophic diatoms and increasingly depleted ¹⁵N values. These trends are particularly pronounced since ~ 1950, and appear to chronicle lake responses to excess N derived from agricultural and industrial sources to the east. The rate and magnitude of recent ecological changes far exceed the context of natural variability, as inferred from comparative analyses of a long core capturingthe entire 14,000-year postglacial history of one of the lakes. Nitrogen deposition to these seemingly pristine natural areas has resulted in subtle but detectable limnological changes that likely represent the beginning of a stronger response to nitrogen enrichment.  相似文献   

河南西峡-内乡琥珀矿床的初步研究   总被引：2，自引：0，他引：2  

周世全  赵树林 《矿产与地质》2005,19(1):57-59

河南西峡-内乡琥珀矿床是我国琥珀市场上原料的重要产地。通过对该矿床的地层、岩相、古地理以及水动力条件等因素的分析研究，以及对琥珀矿体地质特征、琥珀物理性质及化学组成特征的研究，认为该琥珀矿床属于晚白垩世河流冲、洪积沉积矿床。  相似文献   

南岭山地湖泊多环芳烃的大气沉降历史记录   总被引：1，自引：0，他引：1  

刘国卿  彭先芝  张干  祁士华  邹世春  李向东 《地球化学》2007,36(4):357-362

高大山脉对大气环流具有阻挡或屏障作用.通过分析测定南岭山地湖泊沉积物中多环芳烃(PAHs)的垂直分布,结合210Pb定年,探讨了大气PAHs污染在南岭山地的沉积历史.结果显示,沉积物中的PAHs主要以低环数化合物为主,其中尤以菲的含量为最高.在剖面深度0～28 cm范围内,总多环芳烃的含量范围为86～778 ng/g.自1970年开始,PAHs含量持续增加,其中20世纪80、90年代中后期PAHs含量略有降低;在2000年后,沉积柱中的PAHs含量呈急剧增加之势态.多环芳烃在大气迁移过程中发生了组成分异,沉积物中相对富集轻组分(低环数)PAHs,与颗粒物结合的大气干湿沉降是PAHs向偏远山地积的主要途径.  相似文献