银催化HDEA电化学发光法测定矿样中的痕量银     

林金明  安镜如 《岩矿测试》1991,10(1):13-16

在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。  相似文献   

高岭石的结晶有序度及其对纸张涂布粘浓度的影响   总被引：5，自引：0，他引：5  

周国平  林毓川 《矿物学报》1991,11(3):267-273

粘浓度是纸张涂布的一项重要指标,测定的变化范围从46.4—72％。用Hinckley方法测定了高岭石的结晶度指数,从0.57变化至1.40。当粘浓度>67％时,结晶度指数>1。粘浓度<67％,结晶度指数<1,有序高岭石有利于粘浓度提高。随着结构无序化,晶粒变小,晶片变薄,比表面增加,晶体边缘和角易破损,使粘浓度降低。结构无序化破坏了颗粒的均匀性,使颗粒长/厚比增加,粘浓度降低。高岭石八面体中Fe~(3+)的存在一定程度上影响了有序度。  相似文献   

延庆、怀来地区地壳深部磁性构造与地震的研究   总被引：4，自引：0，他引：4  

刘明清  刘敏 《华北地震科学》1994,12(3):53-58

应用三维磁性层反演理论和方法，对延庆、怀来地区航磁资料进行了数据处理，反演计算了该区磁性基底埋深、居里等温面埋深和视磁化强度分布。揭示了延庆盆地、矾山盆地、怀来盆地、涿鹿盆地等四个相互联通盆地的磁性基底的定量特征。对该区地震发生的深部原因和地壳内不同特性块体与地震的关系进行了探讨；对该区地震分布的特点进行了研究；初步提出了该区地震的危险区划和今后的重点监测区。  相似文献   

北京城郊近地层湍流实验观测   总被引：13，自引：2，他引：13  

苏红兵  洪钟祥 《大气科学》1994,18(6):739-750

本文利用两台FA-11超声风速温度仪于1992年3月到４月间在北京325 m气象观测塔47 m和120 m两个高度观测到的风速三个正交分量以及声虚温的湍流脉动资料，计算和分析了北京城郊粗糙下垫面近地层湍流特征量及其日变化，无量纲垂直速度和声虚温的方差随稳定度的变化，风速分量和温度的归一化湍流能谱以及动量和热通量的互谱及其随稳定度的变化。并且与平坦均一下垫面近地层湍流观测的结果进行了对比。  相似文献   

1993年北半球环流特征及其对我国天气气候的影响   总被引：4，自引：0，他引：4  

陈桂英 《气象》1994,20(4):23-26

１９９３年北半球主要环流特征表现为：５００ｈＰａ副产持续加强西伸，位置偏南；亚洲中纬度春，夏经向环流发展，东亚太平洋遥相关型稳定；西藏高原５００ｈＰａ位势高度持续偏高，印缅槽持续偏弱；１００ｈＰａ位势高度场低纬持续偏高，中，高纬持续偏低，夏季南亚高压位置异常偏高。热带海洋出现明显异常，一次新的厄尔尼诺现象发生。热带海洋和北半球大气环流的异常对我国天气气候产生明显影响。  相似文献   

苏鲁交界及南黄海地区地震波速比的变化特征   总被引：2，自引：0，他引：2  

周焕鹏 《地震》1994,(2):36-44

本文主要应用多台波速比和单台波速比的方法，计算了苏鲁交界及南黄海（北纬３５°３５′至３６°００′，东经１１７°００′至１２１°００′）范围内，１９８４到１９９１年７月发生在该区域的１６３次ＭＬ≥１．７地震的波速比值，并对波速比结果进行ｔ检验和模糊数学分析识别。分析结果发现，１９８５年１月至１１月出现了不连续的波速比低值异常时段，模糊数学识别的异常从属函数在这段时间也呈现高值。异常恢复后，１９８７年  相似文献   

Correlation of the major late Jurassic —early Tertiary low- and highstand cycles of south-west Egypt and north-west Sudan     

Peter Wycisk 《International Journal of Earth Sciences》1994,83(4):759-772

The mainly continental deposits of northwest Sudan and south-west Egypt have been correlated with coeval shallow marine and marine deposits in northern Egypt along a north-south running cross-section, based on surface and subsurface data. The palaeodepth curve of northern Egypt illustrates the gradual seal-level rise, reaching its maximum during the Late Cretaceous with conspicuous advances during the Aptian and late Cenomanian. A general highstand is also recorded during the Campanian-Maastrichtian in north-west Sudan. A detailed facies correlation is given for the Aptian and late Cenomanian highstand in western Egypt. The correlation of the Cenomanian Bahariya and Maghrabi formations displays short-term relative sealevel fluctuations. The interpretation illustrates the extensiveness of related erosional processes in the hinterland, partly intensified by temporarily uplift of the Uweinat-Aswan High in the south. Regional uplift and constant erosion took place in south-west Egypt during Coniacian and Santonian times. The regional stratigraphic gaps and uncertain interpretation of the Bahariya Uplift are induced by the influence of the Trans-African Lineament, especially during the Late Cretaceous. Low-stand fluvial sheet sandstones characterized by non-cyclic sequence development and high facies stability occur, especially in the Neocomian and early Turonian. During the Barremian and Albian, fluvial architecture changes to more cyclic fluvial sequences and increasing soil formation, due to increasing subsidence, more humid climatic conditions and the generally rising sea level, culminating in the extensive shallow marine Abu Ballas and Maghrabi formations.  相似文献   

Tectonic framework of the Precambrian of Madagascar and its Gondwana connections: a review and reappraisal     

B. F. Windley  A. Razafiniparany  T. Razakamanana  D. Ackermand 《International Journal of Earth Sciences》1994,83(3):642-659

The Precambrian of Madagascar is divided into two sectors by the north-west trending sinistral Ranotsara shear zone, which continues in the Mozambique belt, probably as the Surma shear zone, and in Southern India as the Achankovil shear zone. South of Ranotsara six north-south trending tectonic belts are recognized that consist largely of granulite and high amphibolite facies paragneisses, phlogopite diopsidites, concordant granites and granulites. North of Ranotsara the central-northern segment is traversed by a north-trending axial 100–150 km wide dextral shear zone of probable Pan-African age, which was metamorphosed under granulite and high amphibolite facies conditions and which has reworked older basement. This shear zone continues across southern India as the Palghat-Cauvery shear zone. Major stratiform basic -ultrabasic complexes occur in the axial zone and in the basement to the west. Well preserved low grade continental margin-type sediments (quartzites, mica schists and stromatolitic marbles) of Kibaran age are present in western Madagascar. Two partly greenschist grade sedimentary groups lie unconformably on high grade basement in north-east Madagascar. Isotopic age data suggest the presence in Madagascar of Archaean, Early and Mid-Proterozoic crustal material that was extensively reworked in Pan-African times.  相似文献   

A numerical simulation of gas flow during coal/gas outbursts   总被引：2，自引：0，他引：2  

F. Otuonye  J. Sheng 《Geotechnical and Geological Engineering》1994,12(1):15-34

Summary A model of the gas flow in airways during an instantaneous outburst of coal and gas is formulated and solved numerically using MacCormack's explicit finite-difference scheme. This model is based on the assumption that geological structures, in-situ stresses and high-gas-pressure gradients play important roles in initiating an outburst, with the gas content and gas-pressure gradients being the most dominant factors. The fluid-dynamic processes that occur after an outburst are computed by the numerical integration of the complete time-dependent Navier-Stokes equations. The mixture velocity, the density and the gas-concentration profiles in both time and space domains (immediately after an outburst) are presented. The global results are useful in gaining an improved understanding of gas-flow patterns during coal/gas outbursts and in determining the range of the disturbance so that effective methods of control can be developed.Nomenclature a speed of sound - C gas concentration (mass) - C _v specific heat at constant volume - C _p specific heat at constant pressure - CFL Courant-Friedrichs-Lewy number - E total energy of the mixture - F the vector defined in Equation 27 - G the vector defined in Equation 28 - h entropy - h _i entropy at inlet - J _xi diffusion flux in the i-direction - k thermal conductivity of a gas - M Mach number - P pressure of a mixture (the partial pressure of gas) - P gas pressure - P _a atmospheric pressure  相似文献   

黄河流域旱涝年地面热量收支变化特征   总被引：1，自引：0，他引：1       下载免费PDF全文

朱超群  高国栋 《应用气象学报》1994,5(3):284-289

根据北京、郑州３年热量平衡观测资料，建立波文（Ｂｏｗｅｎ）比计算模式。并用此模式及辐射计算式等估计黄河流域８年５－８月地面月辐射收支、蒸发耗热、湍流热交换量和土壤热交换量，并比较分析旱涝年它们的差异以及随旱涝（用降水距平表示）的变化。   相似文献