Low-temperature thermodynamic properties of disordered zeolites of the natrolite group     

I. E. Paukov  N. K. Moroz  Yu. A. Kovalevskaya  I. A. Belitsky 《Physics and Chemistry of Minerals》2002,29(4):300-306

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001  相似文献   

Structure of the earth's crust in Jordan from potential field data     

A. Al-Zoubi  Z. Ben Avraham   《Tectonophysics》2002,346(1-2)

Gravity and magnetic data were collected and used to study the crustal structure of Jordan. Three new geophysical maps of Jordan were created: a Moho discontinuity map, a crystalline basement surface map, and a map showing the lowest limit of magnetic blocks. Depths of the Curie Isotherm were also calculated. Results indicate that the depth to the Moho discontinuity in Jordan varies from 32 to 33 km in the northwest to 38 km in the southeast. The basement complex rocks outcrop on the surface in the southwest but lie at about 8 km in the northeast. The Curie Isotherm (585 °C) lies at a depth of about 10 km in the area east of the Dead Sea and dips southeastward towards the Al-Sirhan (Wadi Sirhan), southeast Jordan, where it is located at 35 km depth. Local isostasy of rock masses (blocks) in Jordan does not occur. Nevertheless, this does not rule out the possible existence of isostasy in a regional scale at greater depths within the mantle.  相似文献   

EXPERIMENTAL AND FIELD STUDY ON MINING-PIT MIGRATION   总被引：5，自引：0，他引：5  

S.Ali Akbar Salehi NEYSHABOURI  Ali FARHADZADEH  Ata AMINI 《国际泥沙研究》2002,17(4)

1 INTRODUCTION Because of the large quantity of sand and gravel in their beds, rivers have always been considered as a major source of sand and gravel for civil works. Acceptable quality, ease of extraction and economy are some of the reasons could be mentioned. Unfortunately, specific laws and regulations regarding the safe in-stream mining have not been provided for users and officials. What should be taken into account are the effects of over-mining of sand and gravel, which can cause …  相似文献   

Reconstruction of the diagenesis of the fluvial-lacustrine- deltaic sandstones and its influence on the reservoir quality evolution-- Evidence from Jurassic and Triassic sandstones, Yanchang Oil Field, Ordos Basin     

罗静兰  S.Morad  张晓莉  闫世可  武富礼  李玉宏  薛军民 《中国科学D辑(英文版)》2002,45(7)

The reservoir quality of Jurassic and Triassic fluvial and lacustrine-deltaic sandstones of the Yanchang Oil Field in the Ordos Basin is strongly influenced by the burial history and facies-related diagenetic events. The fluvial sandstones have a higher average porosity (14.8%) and a higher permeability (12.7×10?3 ?m2) than those of the deltaic sandstones (9.8% and 5.8 ×10?3 ?m2, respectively). The burial compaction, which resulted in 15% and 20% porosity loss for Jurassic and Triassic sandstones, respectively, is the main factor causing the loss of porosity both for the Jurassic and Triassic sandstones. Among the cements, carbonate is the main one that reduced the reservoir quality of the sandstones. The organic acidic fluid derived from organic matter in the source rocks, the inorganic fluid from rock-water reaction during the late diagenesis, and meteoric waters during the epidiagenesis resulted in the formation of dissolution porosity, which is the main reason for the enhancement of reservoir-quality.  相似文献   

关于水资源承载力理论与方法的研究   总被引：119，自引：3，他引：119  

朱一中  夏军  谈戈 《地理科学进展》2002,21(2):180-188

本文首先明确了水资源承载力的基本概念 ,指出可持续发展理论、水 -生态 -社会经济复合系统理论、二元模式下的水文循环机制和过程是水资源承载力研究的理论基础 ,对水资源承载力研究的基本内容、评价指标体系的建立和评价方法进行了较全面的概括和总结。  相似文献   

资源环境与社会经济协调发展探析   总被引：15，自引：2，他引：15  

李胜芬  刘斐 《地域研究与开发》2002,21(1):78-80

文章首先回顾了资源环境与社会经济发展的理论，提出资源环境与社会经济协调发展内涵：一方面，要在资源环境承载力范围内发展社会经济，追求社会经济发展的最大化，另一方面，环境承载力是动态的，要依靠社会经济发展不断提高，这两个方面是相互作用、相互制约的。在此基础上，详细论述了资源环境与社会经济协调发展的内容,并从社会经济发展、资源环境管理等角度探讨了资源环境与社会经济协调发展的政策调控，通过建立节约型国民经济体系、深化资源环境管理，实现区域一体化，以保证资源环境与社会经济协调发展的实现。  相似文献   

旅游心理容量的测定——以武陵源黄石寨景区为例   总被引：19，自引：0，他引：19  

周年兴 《地理与地理信息科学》2003,19(2):102-104

旅游容量是旅游规划和管理中的重要工具之一。该文引入边际满意度的概念,提出了旅游心理容量的满意度模型,并且以武陵源黄石寨景区为实证研究,进行了旅游心理容量的测定。  相似文献   

旅游生态环境容量的经济学探讨   总被引：10，自引：4，他引：10  

吴志才  彭华 《云南地理环境研究》2003,15(1):69-74

在总结旅游环境容量研究进展的基础上，提出了研究旅游环境容量意义及其概念体系，并就影响旅游环境容量的关键性因子－旅游生态环境容量进行了分析，运用经济学的理论和方法，提出了引起旅游生态环境容量的深层原因是外部不经济性，最后就为了实现资源环境的可持续发展，应该从法律、行政，经济、社会等角度对社会各利益加以协调，构建了有效的制度平台和相应的措施，使外部成本内部化，并提出了解决这些问题的具体对策和建议。  相似文献   

软土地基上静压预制桩承载力的工后增大效应     

肖军华  韩爱民 《江苏地质》2003,27(4):233-236

分析了软土地基上预制桩承载力的时效性机理，介绍了几种研究承载力时效性的经验回归公式，结合工程说明应充分认识承载力时效性的科学性和利用这种规律潜在的巨大经济效益。  相似文献   

大港油田板深22井油气地球化学异常特征     

姚锦其  王国华  付瑞忠 《矿产与地质》2003,17(4):540-544

根据板深22井中不同地球化学指标的背景含量和异常特征，重点探索和总结了不同油气层的化探指纹指标，并根据地表指纹指标的异常组合、配套关系及异常特征，对油气层的埋深进行了初步预测，为今后该地区地表开展预测油气藏埋深的工作提供了一定的地球化学依据。  相似文献