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141.
142.
构建起双向耦合的液固两相流动旋涡动力学模型与数值方法;应用离散涡方法,计算非定常不稳定水流场;采用Lagrange方法模拟颗粒运动,颗粒对流体的反作用通过修正涡泡运动速度来实现。利用所建模型,计算了两种St数的泥沙粒子在圆柱绕流场中的运动。结果证明了液固两相流动中颗粒运动与旋涡存在着明确的相关结构:(1)当水沙混合物中的泥沙颗粒碰上旋涡时,泥沙颗粒被卷入旋涡中,被卷入旋涡中的泥沙颗粒在运动过程中始终分布于旋涡区;(2)均匀水沙混合物绕圆柱流动,由于流体流过圆柱时产生剧烈分离流动,使得在尾迹流内中等St数 (St~o (1))的泥沙颗粒从均匀水沙混合物中分离出来而往旋涡区聚集。 相似文献
143.
结合四川土壤基层分类 ,选取四川紫色雏形土的几个土系 ,对土壤的水分发性能及其与土壤结构性尤其是机械组成和微团聚体组成的相关关系分析发展 ,土壤水分蒸发具有明显的阶段性 ;土壤水分累积蒸发量与蒸发历时之间总体上符合乘幂方程 ;土壤蒸发速度与〈0 .0 0 1mm的颗粒含量呈明显相关关系 ,与 >0 .2 5mm的大团聚体含量呈明显负相关关系。 相似文献
144.
145.
Sorption is an important process in the modelling and prediction of the movement of heavy metals in unsaturated clay barriers. This experimental study investigates the effect of pH changes in the acidic range on the sorption characteristics of heavy metals such as: lead, copper and zinc in an unsaturated soil. A series of one-dimensional coupled solute and moisture leaching column tests, using different heavy metal solutions, were conducted on an unsaturated illitic soil at varying pH values. Variations of volumetric water content (VWC) with distance were measured for different time durations, and concentrations of heavy metals in the liquid and solid phases were analysed. Partitioning coefficient profiles of contaminants along the soil column were determined for each individual layer in the soil.
Results from column leaching tests showed that the sorption characteristics of heavy metals are controlled by many factors which should be taken into consideration, i.e. the VWC, time of wetting, soil pH, and the influent heavy metal concentrations. Simplification of Kd as a constant and of the VWC as a linear function cannot be considered a good assumption and may lead to an improper evaluation of the sorption phenomena and also to serious errors in predicting contaminant transport through unsaturated soils. 相似文献
146.
一次三峡大暴雨的地转螺旋度分析 总被引:5,自引:4,他引:5
本文引入了地转螺旋度概念,并将其用于一次大暴雨的分析,结果发现;在地转螺旋度垂直剖面图上,在雨区上空300hPa附近有一个负的极小值中心,在500hPa有一个正的极大值中心,该分布形成原因可用图6解释。 相似文献
147.
Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds 总被引:15,自引:0,他引:15
Although organic compounds typically constitute a substantial fraction of the fine particulate matter (PM) in the atmosphere, their molecular composition remains poorly characterized. This is largely because atmospheric particles contain a myriad of diverse organic compounds, not all of which extract in a single solvent or elute through a gas chromatograph; therefore, a substantial portion typically remains unanalyzed. Most often the chemical analysis is performed on a fraction that extracts in organic solvents such as benzene, ether or hexane; consequently, information on the molecular composition of the water-soluble fraction is particularly sparse and incomplete.This paper investigates theoretically the characteristics of the water-soluble fraction by splicing together various strands of information from the literature. We identify specific compounds that are likely to contribute to the water-soluble fraction by juxtaposing observations regarding the extraction characteristics and the molecular composition of atmospheric particulate organics with compound-specific solubility and condensibility for a wide variety of organics. The results show that water-soluble organics, which constitute a substantial fraction of the total organic mass, include C2 to C7 multifunctional compounds (e.g., diacids, polyols, amino acids). The importance of diacids is already recognized; our results provide an impetus for new experiments to establish the atmospheric concentrations and sources of polyols, amino acids and other oxygenated multifunctional compounds. 相似文献
148.
株州市土壤重金属污染的对应分析 总被引:3,自引:0,他引:3
株州市土壤重金属污染的主要原因是工厂排放有害气体,或是水体污染物随灌溉进入土壤。采用对应分析方法,将市区土壤重金属污染分析3种类型。靠近人业污染源附近,镉的含量及污染指数高;大部分土壤受多种重金属污染;水稻土主要表现为铅的污染。 相似文献
149.
By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO3 leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type. 相似文献
150.
Heavy metal input into roadside soils and effects of deicing salts are often discussed as separate environmental problems. However, a relationship between salt input and heavy metal mobility has already been detected in laboratory tests. During a 2-year field study, the soil solution of a roadside soil was continuously sampled. The results of soil solution analysis not only showed a strong rise in deicing-salt related sodium, calcium and chloride concentrations, but also high zinc and cadmium values in winter and spring. Additional laboratory tests confirmed the mobilizing effects of salt solution which contained NaCl and CaCl2. Cation exchange and the formation of chlorocomplexes are discussed as the responsible mechanisms. 相似文献