Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system     

V. Di Liberto  P. M. Nuccio  A. Paonita   《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.  相似文献   

3D shear-wave velocity structure of the Eifel plume, Germany     

Matthias KeyserJoachim R.R. Ritter  Michael Jordan 《Earth and Planetary Science Letters》2002,203(1):59-82

The Quaternary Eifel volcanic fields, situated on the Rhenish Massif in Germany, are the focus of a major interdisciplinary project. The aim is a detailed study of the crustal and mantle structure of the intraplate volcanic fields and their deep origin. Recent results from a teleseismic P-wave tomography study reveal a deep low-velocity structure which we infer to be a plume in the upper mantle underneath the volcanic area [J.R.R. Ritter et al., Earth Planet. Sci. Lett. 186 (2001) 7-14]. Here we present a travel-time investigation of 5038 teleseismic shear-wave arrivals in the same region. First, the transverse (T) and radial (R) component travel-time residuals are treated separately to identify possible effects of seismic anisotropy. A comparison of 2044 T- and 2994 R-component residuals demonstrates that anisotropy does not cause any first-order travel-time effects. The data sets reveal a deep-seated low-velocity anomaly beneath the volcanic region, causing a delay for teleseismic shear waves of about 3 s. Using 3773 combined R- and T-component residuals, an isotropic non-linear inversion is calculated. The tomographic images reveal a prominent S-wave velocity reduction in the upper mantle underneath the Eifel region. The anomaly extends down to at least 400 km depth. The velocity contrast to the surrounding mantle is depth-dependent (from −5% at 31-100 km depth to at least −1% at 400 km depth). At about 170-240 km depth the anomaly is nearly absent. The resolution of the data is sufficient to recover the described features, however the anomaly in the lower asthenosphere is underestimated due to smearing and damping. The main anomaly is similar to the P-wave model except the latter lacks the ‘hole’ near 200 km depth, and both are consistent with an upper mantle plume structure. For plausible anhydrous plume material in the uppermost 100 km of the mantle, an excess temperature as great as 200-300 K is estimated from the seismic anomaly. However, 1% partial melt reduces the required temperature anomaly to about 100 K. The temperature anomaly associated with the deeper part of the plume (250 to about 450 km depth) is at least 70 K. However, this estimate is quite uncertain, because the amplitude of the shear-wave anomaly may be larger than the modelled one. Another possibility is water in the upwelling material. The gap at 170-240 km depth could arise from an increase of the shear modulus caused by dehydration processes which would not affect P-wave velocities as much. An interaction of temperature and compositional variations, including melt and possibly water, makes it difficult to differentiate quantitatively between the causes of the deep-seated low-velocity anomaly.  相似文献   

Vegetation influences on water yields from grassland and shrubland ecosystems in the Chihuahuan Desert     

Mel Neave  Athol D. Abrahams 《地球表面变化过程与地形》2002,27(9):1011-1020

This study examines runoff generated under simulated rainfall on Summerford bajada in the Jornada Basin, New Mexico, USA. Forty‐five simulation experiments were conducted on 1 m² and 2 m² runoff plots on grassland, degraded grassland, shrub and intershrub environments located in grassland and shrubland communities. Average hydrographs generated for each environment show that runoff originates earlier on the vegetated plots than on the unvegetated plots. This early generation of runoff is attributed to soil infiltration rates being overwhelmed by the rapid concentration of water at the base of plants by stemflow. Hydrographs from the degraded grassland and intershrub plots rise continuously throughout the 30 min simulation events indicating that these plots do not achieve equilibrium runoff. This continuously rising form is attributed to the progressive development of raindrop‐induced surface seals. Most grassland and shrub plots level out after the initial early rise indicating equilibrium runoff is achieved. Some shrub plots, however, display a decline in discharge after the early rise. The delayed infiltration of water into macropores beneath shrubs with vegetation in their understories is proposed to explain this declining form. Water yields predicted at the community level indicate that the shrubland sheds 150 per cent more water for a given storm event than the grassland. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Isotope variations in a Sierra Nevada snowpack and their relation to meltwater     

Padinare V. Unnikrishna  Jeffrey J. McDonnell  Carol Kendall   《Journal of Hydrology》2002,260(1-4):38-57

Isotopic variations in melting snow are poorly understood. We made weekly measurements at the Central Sierra Snow Laboratory, California, of snow temperature, density, water equivalent and liquid water volume to examine how physical changes within the snowpack govern meltwater δ¹⁸O. Snowpack samples were extracted at 0.1 m intervals from ground level to the top of the snowpack profile between December 1991 and April 1992. Approximately 800 mm of precipitation fell during the study period with δ¹⁸O values between −21.35 and −4.25‰. Corresponding snowpack δ¹⁸O ranged from −22.25 to −6.25‰. The coefficient of variation of δ¹⁸O in snowpack levels decreased from −0.37 to −0.07 from winter to spring, indicating isotopic snowpack homogenization. Meltwater δ¹⁸O ranged from −15.30 to −8.05‰, with variations of up to 2.95‰ observed within a single snowmelt episode, highlighting the need for frequent sampling. Early snowmelt originated in the lower snowpack with higher δ¹⁸O through ground heat flux and rainfall. After the snowpack became isothermal, infiltrating snowmelt displaced the higher δ¹⁸O liquid in the lower snowpack through a piston flow process. Fractionation analysis using a two-component mixing model on the isothermal snowpack indicated that δ¹⁸O in the initial and final half of major snowmelt was 1.30‰ lower and 1.45‰ higher, respectively, than the value from simple mixing. Mean snowpack δ¹⁸O on individual profiling days showed a steady increase from −15.15 to −12.05‰ due to removal of lower δ¹⁸O snowmelt and addition of higher δ¹⁸O rainfall. Results suggest that direct sampling of snowmelt and snow cores should be undertaken to quantify tracer input compositions adequately. The snowmelt sequence also suggests that regimes of early lower δ¹⁸O and later higher δ¹⁸O melt may be modeled and used in catchment tracing studies.  相似文献   

SIMULATION OF HEAVY RAINFALL IN THE SUMMER OF 1998 OVER CHINA WITH REGIONAL CLIMATE MODEL   总被引：11，自引：0，他引：11  

刘一鸣  丁一汇 《Acta Meteorologica Sinica》2002,(3)

The heavy rainfall in the summer of 1998 over China has been simulated with the NCCRegional Climate Model(RegCM_NCC).It was successful for RegCM_NCC to reproduce thelocation and seasonal shift of the seasonal rain belt in the summer of 1998 over China.The rainyseason in the summer of 1998 over China can be divided into 7 episodes,including the pre-summerrainy season in South China.the Meiyu onset over the Yangtze-Huaihe River Basin,shortappearance of North China rain season and the retreat of seasonal rain belt,the second Meiyuseason over the Yangtze River Valley,the rainy period over the Yellow and Huaihe River Valleyand the seasonal retreat of rain belt over North China.The shortcoming of the RegCM_NCC isover-estimation of precipitation amounts.The regions with large latent heat flux,upper soilmoisture and total runoff are located in the rainy area and move with the simulated rain belt duringthe different episodes.On the contrary,the regions with small sensible heat flux are located in thesimulated rainy area and move with the simulated rain belt during the different episodes.  相似文献   

黄河中游降雨特性对泥沙粒径的影响   总被引：6，自引：3，他引：6  

卢金发  刘爱霞 《地理科学》2002,22(5):552-556

以黄河中游36个有泥沙粒径资料的水文测站流域为样本，在不同自然地理类型流域划分的基础上，建立了流域泥沙粒径特片与降雨特性的关系。结果表明，在不同类型流域，流域泥沙的粗细与降雨季节性变率和年际变率之间存在着相当好的线性正相关关系；而与年降雨量和降雨不均匀系数之间呈明显的非线性关系。流域地面物质、植被和地貌发育程序等下垫面环境因素对泥沙粒径特性与降雨特性之间关系起着十分重要的控制作用。不同类型流域曲线的斜率各不相同，在图中所处的位置也不相同。  相似文献   

青藏高原土壤水热分布特征及冻融过程在季节转换中的作用   总被引：21，自引：0，他引：21  

杨梅学  姚檀栋  何元庆 《山地学报》2002,20(5):553-558

利用GAME-Tibet期间所取得的高分辩率土壤温度和含水量资料，对青藏高原（主要是藏北高原）土壤水热分布特征及冻融过程在季节转换中的作用进行了分析。指出藏北高原4cm学深处土壤在10月份开始冻结，次年4-5月份开始消融，冻结持续时间长达5-7个月。冻结过程有利于土壤维持其水分，因此，在刚刚开始消融时土壤含水量仍然很高。从而为夏季风爆发前土壤通过蒸发向大气提供水分打下了基础。指出土壤冻融过程可能在高原季节转换中起着重要作用。  相似文献   

腾格里沙漠人工固沙植被区生物土壤结皮对降水的拦截作用   总被引：33，自引：16，他引：33  

李守中  肖洪浪  宋耀选  李金贵  刘立超 《中国沙漠》2002,22(6):612-616

在沙坡头人工植被区对人工模拟降水及天然降水后生物土壤结皮层含水率进行了动态定位监测,并分析了生物土壤结皮拦截降水的作用.结果表明:①生物土壤结皮的发育改变了原来沙丘剖面的水分分配格局,10%～40%的年降水量被拦截到结皮层;②随固沙年限的增加,生物土壤结皮的进一步发育和演变,其对降水的拦截能力也进一步提高;③生物土壤结皮对降水的拦截有明显的季节变化,7～10月份平均拦截雨量比4～6月份平均高出12%.  相似文献   

云南省金沙江流域土壤流失方程研究   总被引：17，自引：2，他引：17  

杨子生 《山地学报》2002,(Z1)

云南金沙江流域是长江中上游水土流失最严重的区域。本项研究以“通用土壤流失方程”(USLE)为蓝本,运用小区实验等手段,综合分析了各个侵蚀因子,建立了云南金沙江流域土壤流失方程A=R·K·LS·c·P,并确定了方程中诸因子的求算方法和数值,以及该流域土壤允许流失量,为方程的应用提供了基本的技术数据。同时,还进行了方程的检验,方程计算值与小区实测值的相对误差在6.3％以下,表明该方程在实际应用中是可靠的。该方程的建立,可为云南金沙江流域预测预报土壤侵蚀,制定土地合理利用规划方案、水土保持措施和土地生态安全格局提供了一套可靠的科学方法和依据。  相似文献   

Identification of geomorphic process units in Kärkevagge, northern Sweden, by remote sensing and digital terrain analysis     

Annett Bartsch  Martin Gude  Christer Jonasson  & Dieter Scherer 《Geografiska Annaler: Series A, Physical Geography》2002,84(3-4):171-178

Sediment transport processes in the Kärkevagge are investigated concerning their spatial and temporal characteristics due to long–term monitoring. Within this study remote sensing techniques and GIS modelling in connection with geomorphic mapping are applied for identification and characterization of geomorphic process units. Relationships between geomorphometric parameters and slope processes like solifluction, talus creep and rockfall have been analysed. Multitemporal Landsat–TM5 scenes are used as source for landcover characteristics (Normalized Difference Vegetation Index) after preprocessing involving orthorectification and topographic normalization in order to remove possible terrain–induced effects. Additionally, a digital elevation model with a resolution of 20 m for the Kärkevagge catchment is developed and parameters like slope gradient, slope aspect and profile curvature are extracted as input for the analysis of the sediment transport system. The combination of landcover information, geomorphometrical and topological features allows the definition of areas for single process activities. They show specific sediment displacement characteristics depending on material conditions, topological and geometrical features. Geomorphic process units, which show a homogenous composition, are extracted from these available layers.  相似文献