Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy          下载免费PDF全文

Atsuyuki Ohta  Ran Kubota 《Geostandards and Geoanalytical Research》2016,40(1):117-134

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).  相似文献   

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy          下载免费PDF全文

Jesse D. Ward  Mark Bowden  C. Tom Resch  Steven Smith  Bruce K. McNamara  Edgar C. Buck  Gregory C. Eiden  Andrew M. Duffin 《Geostandards and Geoanalytical Research》2016,40(1):135-148

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.  相似文献   

ASTER mapping of gypsum deposits of Thumrait region of southern Oman     

Sankaran Rajendran  Sobhi Nasir 《Resource Geology》2021,71(1):41-62

This study demonstrates the use of ASTER data for the mapping of gypsum deposits and associated geological formations that occurred in the Thumrait region of southern Oman. The measurement of spectra over samples of gypsum in the 1,300–2,500 nm wavelength using a PIMA spectrometer showed the presence of distinct absorptions at 1400–1600, 1750, 1940, 2,100, and 2,400 nm characteristics to O? H stretching, H₂O combinations, and S? O bending overtones and stretching, respectively. Studying the unique spectral absorption characters of gypsum samples, we developed a false color composite (FCC) and an image by decorrelation stretch using the spectral bands 7, 3, and 2 of ASTER. The results FCC showed the regions of gypsum occurrences, and the decorrelated image discriminated the gypsum occurrences from other geological formations of the area. The study of surface mineralogy of the region using the VNIR‐SWIR bands by the spectral angle mapper method showed the presence of sulfate, carbonate, and clay minerals of the geological formations in the study area. We compared the results of ASTER with the results obtained using spectral bands 12, 8, and 4 of Sentinel‐2A processed by the same methods. The study showed that the spectral bands of ASTER can be used for mapping the gypsum and associated geological formations.  相似文献   

蒙脱石红移、蓝移及水化特征的谱学分析   总被引：3，自引：0，他引：3  

孙红娟  彭同江  刘颖 《矿物岩石》2006,26(3):20-25

对提纯蒙脱石、钠化蒙脱石、有机插层蒙脱石进行紫外-可见光学吸收谱分析、红外光谱分析,发现蒙脱石随着粒度的变化产生红移和蓝移现象。1631插层样品较钠化样品红移20 nm以上,而提纯的胶体粒子样品较1631插层样品SM G-1631红移80 nm;由于提纯蒙脱石样品粒度变细羟基伸缩振动吸收峰向高波数移动了1.69 cm-1,即蓝移了1.69cm-1。蒙脱石水化性能的XRD分析表明,蒙脱石吸水后晶层发生膨胀、剥离,脱水时分散后的晶层发生凝聚作用,即面-面结合作用,形成蒙脱石“定向性层状集合体”衍射峰的d值产生了相应的变化,这种凝聚作用是蒙脱石分散剥离的逆作用,但凝聚后形成的凝聚蒙脱石的衍射谱特征与原始蒙脱石的大不相同。蒙脱石红移、蓝移及水化特征的谱学分析研究丰富了天然纳米蒙脱石矿物材料晶体化学研究的内容,具有重要的理论意义。  相似文献   

Influence analysis of gaseous absorption on “HY-1A” CZI data processing Simulation and correction for Rayleigh scattering     

SUN Ling  ZHANG Jie  GUO Maohua 《海洋学报(英文版)》2008,27(6):102-114

Besides ozone, oxygen and water vapour should be considered for their absorptive effects on ＂HY--1A＂ CZI data processing. First ,gaseous transmittances under various conditions are computed and analyzed for the band settings of this sensor. Second, transmittances under six standard atmospheres are approximated as functions of zenith angle, the water vapour transmittance is approximated as a function of water vapour content and zenith angle, and the ozone transmittance is approximated as a function of ozone content and zenith angle. Finally, taking Rayleigh scattering as an example, the influence of ignoring gaseous absorption when calculating TOA reflectance is analyzed, and the effect of applying the presented transmittance approximations to gaseous absorption correction for Rayleigh scattering in ＂HY--1A＂ CZI data processing is evaluated.  相似文献   

Optical properties of the red tide in Isahaya Bay,southwestern Japan: Influence of chlorophyll a concentration     

Hiroaki Sasaki  Akihiko Tanaka  Mitsunori Iwataki  Yasuharu Touke  Eko Siswanto  Chun Knee Tan  Joji Ishizaka 《Journal of Oceanography》2008,64(4):511-523

Remote sensing reflectance [R _rs(λ)] and absorption coefficients of red tides were measured in Isahaya Bay, southwestern Japan, to investigate differences in the optical properties of red tide and non-red tide waters. We defined colored areas of the sea surface, visualized from shipboard, as “red tides”. Peaks of the R _rs(λ) spectra of non-red tide waters were at 565 nm, while those of red tides shifted to longer wavelengths (589 nm). The spectral shape of R _rs(λ) was close to that of the reciprocal of the total absorption coefficient [1/a(λ)], implying that the R _rs(λ) peak is determined by absorption. Absorption coefficients of phytoplankton [a _ph(λ)], non-pigment particles and colored dissolved organic matter increased with increasing chlorophyll a concentration (Chl a), and those coefficients were correlated with Chl a for both red tide and non-red tide waters. Using these relationships between absorption coefficients and Chl a, variation in the spectrum of 1/a(λ) as a function of Chl a was calculated. The peak of 1/a(λ) shifted to longer wavelengths with increasing Chl a. Furthermore, the relative contribution of a _ph(λ) to the total absorption in red tide water was significantly higher than in non-red tide water in the wavelength range 550–600 nm, including the peak. Our results show that the variation of a _ph(λ) with Chl a dominates the behavior of the R _rs(λ) peak, and utilization of R _rs(λ) peaks at 589 and 565 nm may be useful to discriminate between red tide and non-red tide waters by remote sensing.  相似文献   

Estimation of the <Emphasis Type="Italic">in situ</Emphasis> Ultraviolet-A absorption of seawater by a simple irradiance inversion model     

Takafumi Hirata 《Journal of Oceanography》2008,64(4):561-566

An irradiance inversion model to estimate the in situ absorption coefficient of seawater has been developed for the Ultraviolet-A (UVA) wavelength domain. Input parameters are sun angle and the up-and downward planar irradiances measured for at least two depths. The present method does not require seawater to be sampled, and is a discrete wavelength method which returns the absorption coefficient at a given wavelength from the irradiances measured at that wavelength without assuming a spectral shape of any optical properties a priori. Comparison between the model results and spectrophotometric measurements shows that the model is practically useful when cloud cover in the atmosphere is ≤ 50%. According to the present method, measurements of the irradiances enable simultaneous observation of the in situ underwater UVA radiation level and the absorption capacity of bulk seawater using a radiometer.  相似文献   

机载WIDAS数据的Landsat卫星反照率初步验证   总被引：1，自引：1，他引：0  

何丹丹  焦子锑  董亚冬  张小宁  丁安心  尹思阳  崔磊  常雅轩 《遥感学报》2019,23(1):53-61

随着精细化监测的需求,中高空间分辨率的地表反照率产品逐渐成为气候模型的主要输入。目前,中高空间分辨率反照率产品的验证主要基于地表站点的通量塔观测数据,区域机载飞行数据的验证依然相对较少。因此,本文基于区域机载数据验证Landsat反照率产品。针对内蒙古自治区根河森林试验区所获取的机载红外广角双模式成像仪(WIDAS)多角度反射率数据,应用BRDF原型反演算法估算其反照率,分析了应用机载数据验证中高空间分辨率反照率产品的潜力。2016年内蒙古根河森林试验区机载WIDAS飞行多角度观测的可用多角度范围为25°,以前的研究表明BRDF原型反照率反演算法表现出对小观测角度的反照率反演结果的鲁棒性。因此,机载WIDAS反照率在一定程度可用于星载反照率的验证。首先,基于核驱动模型和各向异性平整指数(AFX)提取了试验区4种MODIS二向性反射分布函数(BRDF)原型;然后,将其作为先验知识应用到根河森林WIDAS机载数据的反照率反演中;最后,用WIDAS反照率和单个地面通量塔观测的反照率对Landsat卫星数据的反照率进行初步验证。验证结果表明Landsat反照率与WIDAS反照率结果较为一致,但略有低估,总体均方根误差(RMSE)约为0.02,偏差为0.0057。在多角度观测范围较小时,BRDF原型的反照率反演算法可为星载地表反照率的验证提供了一种有效的验证手段。  相似文献   

Lymanα forests and the evolution of the universe     

D.-E Liebscher  W. Priester  J. Hoell 《Astronomische Nachrichten》1992,313(5):265-273

The Lyα forest absorption lines in the spectra of quasars are interpreted as caused by the crossings of the light beam with the walls of a bubble structure (expanding with the Hubble flow only). Then, the typical separation between the absorption lines is proportional to the mean size of the bubbles. The variable factor is the expansion rate H[z]. The Friedmann regression analysis of the observed line separations determines the density parameter ω₀ and the normalized cosmological term λ₀ = λc²/3H²₀ of the appropriate cosmological model: ω₀ = 0.014 ± 0.002, λ₀ = 1.080 ± 0.006. Depending on the Hubble parameter this method reveals the values of the present mean matter density pm,0 = 2.6 h² · 10⁻²⁸ kg m⁻³ and of the cosmological constant Λ = 3.77 h² · 10⁻⁵² m⁻² (with h = H₀/(100 km/s·Mpc)). According to our analysis all models with Λ = 0 must be excluded. The curvature of space is positive. The curvature radius R₀ is 3.3 times the Hubble radius (c/H₀). The age t₀ is 2.8 times the Hubble age (H₀⁻¹).  相似文献   

由粒子吸收光谱提取浮游植物吸收光谱的人工神经网络方法     

刘雪锋  张亭禄 《海洋技术学报》2006,25(3):45-50

基于现场实验数据集及人工神经网络技术,论文提出了一种从海中粒子吸收光谱提取浮游植物吸收光谱的方法。这个数据集包含了海中粒子吸收光谱和对应的浮游植物吸收光谱,并被分为三个子集:训练集、印证集和试验集。本研究所利用的人工神经网络系统为多层感知器,训练后的人工神经网络的性能由印证集和试验集来评价。实验结果表明,文中所提出的方法可成功地提取浮游植物的吸收光谱,其提取精度与传统的实验方法相当。  相似文献