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91.
92.
Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope (their δ^18O values range from -0.3‰- -0.1‰) and lighter oxygen isotope (their δ^18O values range from -22.1‰- -19.5‰). Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process. 相似文献
93.
Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong 总被引:1,自引:0,他引:1
QIAN Jianping LI Shuangli and CAO Chao Guilin University of Technology Guilin China 《中国地球化学学报》2008,(1)
Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2 , Mg2 and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K , Na , Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model.. 相似文献
94.
Baode Wang Shuyin Niu Aiqun Sun Huabin Hu Yaming Liu Lijun Guo Shuo Wang 《中国地球化学学报》2008,27(3):235-241
In recent years big strides have been made in the exploration of ores in the central-south segment of the Da Hinggan Ling Range, though some debates still exist on the metallogenesis and sources of ore-forming materials. Pyrite and other sulfides in direct relation to the Pb-Zn-Ag ore deposits were chosen for the He and Ar isotopic analysis of ore-forming fluids, and the first He and Ar isotope data have been obtained from the study region. ^3He/^4He ratios in 14 samples collected from 7 mining districts are 2.17×10^-6-12.52×10^-6, averaging 6.86×10^-6 and their R/Ra ratios are 1.56-9.01 Ra, averaging 4.37 Ra. By projecting the data points onto the ^3He-^4He concentrations diagram, all the points fall near the mantle helium area. The calculated mantle-source helium ratios are within the range of 19.58%-76.96%, with an average of 49.52%. Argon isotopic characteristics are close to those of mantle source, indicating that the ore-forming material was transport upwards via the multi-stage evolution of mantle plume and concentrated as ores in the favorable loci of mantle branch structures. 相似文献
95.
The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin 总被引:2,自引:2,他引:0
Xianqing Li Guoyi Hu Jian Li Dujie Hou Peng Dong Zhihong Song Yunfeng Yang 《中国地球化学学报》2008,27(2):109-120
The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin. 相似文献
96.
Rare-earth elements as source indicators of Pan-African granites from Obudu Plateau,Southeastern Nigeria 总被引:1,自引:1,他引:0
The rare-earth element (REE) concentrations of representative granite samples from the southeast of the Obudu Plateau, Nigeria, were analyzed with an attempt to determine the signatures of their source, evolutionary history and tectonic setting. Results indicated that the granites have high absolute REE concentrations (190×10^-6-1191×10^-6; av.=549×10^-6) with the chondrite-normalized REE patterns characterized by steep negative slopes and prominent to slight or no negative Eu anomalies. All the samples are also characterized by high and variable concentrations of the LREE (151×10^-6-1169×10^-6; av.= 466×10^-6), while the HREE show low abundance (4×10^-6-107×10^-6; av.=28×10^-6). These are consistent with the variable levels of REE fractionation, and differentiation of the granites. This is further supported by the range of REE contents, the chondrite-normalized patterns and the ratios of LaN/YbN (2.30-343.37), CeN/YbN (5.94-716.87), LaN/SmN (3.14-11.68) and TbN/YbN (0.58-1.65). The general parallelism of the REE patterns, suggest that all the granites were comagmatic in origin, while the high Eu/Eu* ratios (0.085-2.807; av.=0.9398) indicate high fo2 at the source. Similarly, irregular variations in LaN/YbN, CeN/YbN and Eu/Eu* ratios and REE abundances among the samples suggest behaviors that are related to mantle and crustal sources. 相似文献
97.
98.
Open source, spatial analysis, and activity-travel behaviour research: capabilities of the aspace package 总被引:2,自引:0,他引:2
This paper reports on recent experience with the development of aspace, an Open Source (OS) library for the geographic visualization and analysis of activity-travel behaviour. The paper begins
with an overview of recent progress with respect to the convergence of Open Source technology, spatial analysis, and travel
behaviour research. The remainder of the paper focuses on aspace; a collection of functions that, when combined with data describing the geographical location of daily activities, can be
used to visualize and describe spatial properties of individual and household activity spaces. These properties include: size,
orientation, shape, and the geographical dispersion of activity locations contained within the activity space. Several planar
geometries are used to transform measurable spatial properties into intuitive objects for visualizing spatial patterns of
activity participation. Experiments are conducted, using data from the first wave of the 2003 Toronto Travel Activity Panel
Survey, to demonstrate the potential application of aspace for basic and applied policy-based research into activity-travel behaviour. The toolkit is distributed as a downloadable
‘package’ from the Open Source R Project for Statistical Computing.
相似文献
99.
长江流域沿江镉异常源追踪与定量评估的方法技术研究:以长江流域安徽段为例 总被引:5,自引:1,他引:4
长江全流域性的Cd异常是被中国正在进行的多目标地球化学调查发现的重大生态环境问题。以长江流域安徽段为研究对象,对沿江镉异常源追踪与定量评估的方法技术进行了系统研究。通过对安徽段长江干流及其主要支流悬浮物中元素含量的测量查明:悬浮物是流域内重金属元素大跨度迁移的主要载体;Cd在悬浮物中的富集程度远远大于其他重金属元素,这或许正是Cd可以形成沿江流域性异常的主要原因;长江干流悬浮物中重金属元素含量的变化明显受到沿江支流的影响。安徽段长江干流及其主要支流重金属元素输出通量定量计算结果表明:秋蒲河是安徽段重金属元素输出通量最大的支流,每年在安徽段长江两岸土壤中沉积下约4.45t的Cd。利用悬浮物加密测量、1∶5万土壤测量和岩石测量对顺安河流域Cd异常源追踪结果显示:内生金属矿床特别是铅锌矿是悬浮物中Cd的最大的供应源。采用河漫滩沉积物分层采样技术和同位素测年技术,初步恢复了研究区Cd等重金属元素沉积和污染的地球化学历史,对研究区Cd等重金属元素异常的未来演变趋势进行了预警预测。 相似文献
100.
青藏高原北部陆相盆地中烃源岩发育层位包括始新统风火山组、渐新统雅西措组和中新统五道梁组。古近系雅西措组烃源岩,特别是灰岩属于中好烃源岩范畴,有机质类型较好,且烃源岩主体处于成熟阶段,是藏北高原新生代陆相盆地主力烃源岩的发育层位。陆相盆地储集岩较发育,储层较丰富,发育层位包括风火山组和雅西措组,其中雅西措组是储层主力分布层位。对测区分析数据表明:通天河盆地具备一定规模的生油岩厚度,而且有机质丰度为沱沱河地区最高,表明其勘探前景较好。 相似文献