Convective stability analysis of the long-term storage of carbon dioxide in deep saline aquifers     

Xiaofeng Xu  Shiyi Chen  Dongxiao Zhang 《Advances in water resources》2006

Deep saline aquifers are one of the most suitable geologic formations for carbon sequestration. The linear and global stability analysis of the time-dependent density-driven convection in deep saline aquifers is presented for long-term storage of carbon dioxide (CO₂). The convective mixing that can greatly accelerate the CO₂ dissolution into saline aquifers arises because the density of brine increases upon the dissolution of CO₂ and such a density difference may induce instability. The effects of anisotropic permeability on the stability criteria, such as the critical time for the appearance of convective phenomena and the critical wavelength of the most unstable perturbation, are investigated with linear and global stability analysis. The linear stability analysis provides a sufficient condition for instability while the global stability analysis yields a sufficient condition for stability. The results obtained from these two approaches are not exactly the same but show a consistent trend, both indicating that the anisotropic system becomes more unstable when either the vertical or horizontal permeability increases.  相似文献   

Theorem of turbulent intensity and macroscopic mechanism of the turbulence development     

Hu YinQiao  Chen JinBei  Zuo HongChao 《中国科学D辑(英文版)》2007,50(5):789-800

Turbulence is one of the most common nature phenomena in everyday experience, but that is not adequately understood yet. This article reviews the history and present state of development of the turbulence theory and indicates the necessity to probe into the turbulent features and mechanism with the different methods at different levels. Therefore this article proves a theorem of turbulent transpor- tation and a theorem of turbulent intensity by using the theory of the nonequilibrium thermodynamics, and that the Reynolds turbulence and the Rayleigh-Bénard turbulence are united in the theorems of the turbulent intensity and the turbulent transportation. The macroscopic cause of the development of fluid turbulence is a result from shearing effect of the velocity together with the temperature, which is also the macroscopic cause of the stretch and fold of trajectory in the phase space of turbulent field. And it is proved by the observed data of atmosphere that the phenomenological coefficient of turbulent in- tensity is not only a function of the velocity shear but also a function of temperature shear, viz the sta- bility of temperature stratification, in the atmosphere. Accordingly, authenticity of the theorem, which is proved by the theory of nonequilibrium thermodynamics, of turbulent intensity is testified by the facts of observational experiment.  相似文献   

钾长石分解反应热力学与过程评价   总被引：2，自引：2，他引：2  

马鸿文  苏双青  王芳  徐锦明  谭丹君  刘浩 《现代地质》2007,21(2):426-434

综述了添加各种助剂分解钾长石的研究进展。对不同体系中钾长石分解反应的G ibbs自由能和能耗计算,综合考虑一次性资源、能源消耗量和烧结过程的环境相容性、产品方案等因素,结果表明:只有以石灰石、碳酸钠为配料的工艺路线具有实际工业应用价值;而唯有以碳酸钠为配料时,钾长石原料烧结过程才具有一次性资源消耗量最少、能耗最低、温室气体CO2排放量最小、且可生产高附加值产品、实现完全清洁生产等优点。因此,选择以碳酸钠为配料分解钾长石的技术路线,具有良好的工业化应用前景。  相似文献   

Best prediction in linear models with mixed integer/real unknowns: theory and application     

P. J. G. Teunissen 《Journal of Geodesy》2007,81(12):759-780

In this contribution, we extend the existing theory of minimum mean squared error prediction (best prediction). This extention is motivated by the desire to be able to deal with models in which the parameter vectors have real-valued and/or integer-valued entries. New classes of predictors are introduced, based on the principle of equivariance. Equivariant prediction is developed for the real-parameter case, the integer-parameter case, and for the mixed integer/real case. The best predictors within these classes are identified, and they are shown to have a better performance than best linear (unbiased) prediction. This holds true for the mean squared error performance, as well as for the error variance performance. We show that, in the context of linear model prediction, best predictors and best estimators come in pairs. We take advantage of this property by also identifying the corresponding best estimators. All of the best equivariant estimators are shown to have a better precision than the best linear unbiased estimator. Although no restrictions are placed on the probability distributions of the random vectors, the Gaussian case is derived separately. The best predictors are also compared with least-squares predictors, in particular with the integer-based least-squares predictor introduced in Teunissen (J Geodesy, in press, 2006).  相似文献   

湿斜压大气中暴雨中尺度系统发展的一种可能机制   总被引：1，自引：0，他引：1  

陈忠明 《高原气象》2007,26(2):233-239

根据暴雨中尺度系统发生时的大气运动特征,在绝热、无摩擦条件下,从湿斜压原始方程出发,考虑大气运动的涡度及散度演化不仅受动力场的制约,而且还受到热力场的约束,采用不同于传统研究涡度及散度方程的分析方法,导出了新形式的涡度及散度方程。在此基础上,分析了湿斜压大气中对流层中低层气流旋转与辐合持续增长的动力特征,初步揭示了湿斜压大气中暴雨中尺度系统发展的动力机制。  相似文献   

C—O—H体系高温高压流体相组成的热力学研究     

白正华  王先彬 《矿物学报》1998,18(3):309-320

本文在C－O－H体系流体相平衡基础上,利用现有的热力学数据和新的p－V－T资料,在pT=∑pi假定下,计算了高温、高压条件下流体相组成。结果表明,该体系主要存在五种流体相,在不同温压条件下各流体相所占比例不同。在相对较低的温、压条件下,CH4是体系中占主要的流体相（约占70％）,且随温、压和氧逸度的升高,它所占比例却明显降低,所获结果为探讨无机成因天然气形成的可能性、存在的量比和稳定存在的物理化学条件提供了充分的理论依据。  相似文献   

地质流体热动力学研究现状与发展趋势     

段振豪 《地质科技情报》1998,(Z1)

流体热动力学性质对理解各种作用过程中的地球化学行为是重要的。有关这方面的知识,通常是从实验资料获得。但实验工作毕竟是有限的,只能反映自然条件中很有限的范围。半经验的模式（如状态方程）或计算机模拟（如分子动力学和ＭｏｎｔｅＣａｒｌｏ模拟）提供了地质流体系统定量研究的主要方法。一个好的状态方程,可以根据实验数据内插或外延,能获得很多物理—化学信息。计算机模拟甚至可以在实验室不能达到的条件下产生“实验数据”,为未来地球化学研究提供了很大的潜在发展可能性。未来研究工作的重点应是：①为Ｈ２Ｏ－ＣａＣｌ２－ＮａＣｌ－ＣＯ２－ＣＨ４－Ｈ２Ｓ－Ｎ２体系提供预测容积、相平衡和焓的状态方程;②有效的计算机程序能够模拟自然界中含水溶液流体混合物的各种特性（包括热动力、结构、迁移性质）;③将这些模式和计算机模拟应用于各种地质系统的研究（如热水溶液矿床和流体—岩石交换反应等）中。  相似文献   

Relationships between rainy days,mean daily intensity and seasonal rainfall in normal,flood and drought years over india     

C. V. Singh 《大气科学进展》1998,15(3):424-432

There are limitations in using the seasonal rainfall total in studies of Monsoon rainfall climatology. A correlation analysis of the individual station seasonal rainfall with all India seasonal mean rainfall has been made. After taking the significance test (strictly up to 5% level) the stations which are significantly correlated have been considered in this study in normal, flood and drought years respectively. Analysis of seasonal rainfall data of 50 stations spread over a period of 41 years suggests that a linear relationship fits better than the logarithmic relationship when seasonal rain-fall versus number of rainy days is studied. The linear relationship is also found to be better in the case of seasonal rainfall versus mean daily intensity.  相似文献   

渤海的海冰数值预报   总被引：33，自引：0，他引：33  

白珊  吴辉碇 《气象学报》1998,56(2):139-153

根据渤海气候和冰情特点,在已有海冰模式研究基础上,提出模拟海冰增长、消融和漂移的动力－热力学模式。模式冰厚分布由开阔水、平整冰和堆积冰三要素表示。该模式已与数值天气预报模式、大气边界层模式、潮流模式联结,并于１９９０年到１９９６年在国家海洋环境预报中心进行渤海和北黄海冰情预报。其数值预报产品包括冰厚、密度集、冰速、冰外缘线、冰脊参数、局地冰厚以及接近石油平台的冰漂移轨迹等,传送到国家海洋预报台和渤海石油公司等有关用户。为了客观评价模式和检验预报结果,在逐日预报后进行统计检验。本文概述渤海冰情、卫星遥感应用、冰模式及其预报结果和检验。  相似文献   

中尺度对流复合体的热力学特征分析   总被引：1，自引：0，他引：1  

康凤琴 《干旱气象》1998,(4)

用合成分析方法探讨ＭＣＣ热力学结构的演变规律,结果表明：ＭＣＣ整个生命史里,对流层中下部为正涡度区,２００ｈＰａ以上为负涡度区;发展时刻辐合区突然抬升;ＭＣＣ前期的垂直上升速度最大中心高度低于后期的;ＭＣＣ的高低空的冷心、中层暖心的温度结构在成熟期以后不明显  相似文献