Measurement of Particle-Bound Reactive Oxygen Species in Rubidoux Aerosols   总被引：1，自引：0，他引：1  

Prasanna?Venkatachari  Philip?K.?HopkeEmail author  Brett?D.?Grover  Delbert?J.?Eatough 《Journal of Atmospheric Chemistry》2005,50(1):49-58

The diurnal variations in the concentrations of reactive oxygen species (ROS) in various size fractions were determined for ambient particles in Rubidoux, CA. Sampling of particles was conducted at 3 h intervals using a cascade impactor. The collected particles were reacted with dichlorofluorescin (DCFH), a non-fluorescent probe that fluoresces when oxidized. The factors affecting the diurnal variation in ROS concentration were also investigated with special emphasis on the relation between ROS concentration and the intensity of photochemical reactions where the ozone concentration was taken as an index. The intensity of photochemical reactions was found to be a moderate factor affecting the daytime ROS concentration. The concentration of ROS was found to be higher on the smaller particles of the ambient aerosol. An erratum to this article is available .  相似文献   

Distinguishing climatic from direct anthropogenic influences during the past 400 years in varved sediments from Lake Holzmaar (Eifel,Germany)   总被引：3，自引：0，他引：3  

Ulrike?KienelEmail author  Markus?J.?Schwab  Georg?Schettler 《Journal of Paleolimnology》2005,33(3):327-347

A 336-year floating varve chronology from Lake Holzmaar (Eifel, Western-Germany) covering the recent period has been established by microfacies analysis of thin sections. This sequence terminates 23 cm below the core top. In the top 23 cm, the varves are disturbed. By means of linear regression, the varve sequence was dated to the period AD 1607–1942. The influences of climatic variability and anthropogenic activities in the lakes catchment (e.g., forestry, agriculture) on lithology, fabric, and microfossil content of the varve sublaminae could be discriminated by applying statistical analyses (ordination and clustering) to the combination of the sublaminae in the varves and their thickness. Four clusters are obtained. Cluster 1 indicates cold springs, and shorter, cooler summers reflected primarily in below-average varve thickness (VT) for two stable phases: from AD 1650–1700 (during the Maunder Minimum) and from AD 1750–1785. Cluster 2 indicates years with conditions transitional to that indicated by cluster 1, characterized by vigorous and prolonged spring circulation with massive blooms of the nordic-alpine Aulacoseira subarctica. The samples assigned to Cluster 3 and Cluster 4 show the imprint of anthropogenic influences. Cluster 3 (AD 1795–1815 and AD 1825–1885) is characterized by above-average VT due to high detritus input throughout the year. The increased soil erosion can be linked to anthropogenic deforestation as a consequence of the production increase of the Eifelian iron industry at the end of the 18th century. This input dampens the climatic signal of a colder Dalton Minimum, which is reflected in a short drop in VT centered around AD 1810. At about AD 1885, Cluster 4 conditions, characterized by increased nutrient concentrations, low detritus input, and longer periods of stable summer stratification, become the stable state in Lake Holzmaar. They indicate the response of the lake to natural reforestation and the use of artificial fertilizers in the catchment, which began, according to historical records, in the 1850s in the Eifel region. The prolonged, stable summer stratification periods may be the first indication of the modern warming trend. A drop in VT centered around AD 1890 and recurring cluster-1 conditions may indicate the Damon Minimum.  相似文献   

Probing the magnetic topology of coronal mass ejections by means of Ulysses/HI-SCALE energetic particle observations     

O. Malandraki  E. T. Sarris  P. Trochoutsos 《Annales Geophysicae》2000,18(2):129-140

In this work, solar flare energetic particle fluxes (E_e 42 keV) observed by the HI-SCALE instrument onboard Ulysses, a spacecraft that is probing the heliosphere in 3-D, are utilized as diagnostics of the large-scale structure and topology of the interplanetary magnetic field (IMF) embedded within two well-identified interplanetary coronal mass ejection (ICME) structures. On the basis of the energetic solar flare particle observations firm conclusions are drawn on whether the detected ICMEs have been detached from the solar corona or are still magnetically anchored to it when they arrive at 2.5 AU. From the development of the angular distributions of the particle intensities, we have inferred that portions of the ICMEs studied consisted of both open and closed magnetic field lines. Both ICMEs present a filamentary structure comprising magnetic filaments with distinct electron anisotropy characteristics. Subsequently, we studied the evolution of the anisotropies of the energetic electrons along the magnetic field loop-like structure of one ICME and computed the characteristic decay time of the anisotropy which is a measure of the amount of scattering that the trapped electron population underwent after injection at the Sun.  相似文献   

Charge state behaviour of projectiles under an acceleration mechanism in a hot plasma     

L. del Peral  M. D. Rodríguez-Frías  R. Gmez-Herrero  J. Rodríguez-Pacheco  J. Gutirrez 《Astroparticle Physics》2002,17(4):215-420

We have studied the ionization states of most ions in solar flares when a stochastic acceleration mechanism is present. Calculations using a computer code (ESCAPE) designed to find the charge states of heavy and light ions under stochastic acceleration have shown an energy dependence on the ionization states, stronger for heavy ions. Moreover the charge states depend on source parameters as density or temperature, but if an acceleration mechanism is taken into account in impulsive solar energetic particles events, the same source temperature may not be inferred for all the ions.  相似文献   

Nongravitational forces and meteoroid streams     

Jozef Klačka 《Earth, Moon, and Planets》1994,65(2):191-196

The action of the solar electromagnetic radiation on the moving interplanetary dust particles in its more complete form than the special case known as the Poynting-Robertson effect is theoretically discussed in application to meteoroid stream of comet Encke.Normal and transversal components of the perturbing nongravitational force are used due to the action of the solar electromagnetic radiation. It is shown that the normal component of the force is negligible. However, transversal component is very important: it can probably completely explain all the observed meteoroid streams situated along the orbit of comet Encke (and, possibly, some asteroids) as the product of the comet Encke alone. Much shorter time is required for producing such a meteoroid stream than is a general conception.If the idea about the significance of the transversal component of the nongravitational force (may be, not produced by electromagnetic radiation) is correct, it may have important consequences for our understanding of ageing of comets, global evolution of the cometary (and, partially, asteroidal) system, and, of course, for a long-term evolution of small interplanetary particles.  相似文献   

大气退化图像的处理研究   总被引：2，自引：0，他引：2  

周旋  周树道  黄峰  朱福萌 《武汉大学学报(信息科学版)》2005,30(8):720-722

大气退化图像最主要的特征是退化造成的影响和景物与相机的之间的距离相关。针对这种相关性,并结合大气退化图像的特点,提出了一种有效的处理方法,该方法对大气退化图像的处理不需要任何辅助信息。实验表明,该方法具有较好的处理效果。  相似文献   

The last 1300?years of environmental history recorded in the sediments of Lake Sils (Engadine, Switzerland)   总被引：2，自引：0，他引：2  

Alex Blass  Flavio S. Anselmetti  Martin Grosjean  Michael Sturm 《Eclogae Geologicae Helvetiae》2005,98(3):319-332

  相似文献   

Sr and Nd isotopes as tracers of clastic sources in Lake Le Bourget sediment (NW Alps, France) during the Little Ice Age: Palaeohydrology implications     

Marie Revel-Rolland  Fabien Arnaud  Marc Desmet  Chantal Alibert 《Chemical Geology》2005,224(4):183-200

Geochemical methods (major elements and Sr, Nd isotopes) have been used to (1) characterize Lake Le Bourget sediments in the French Alps, (2) identify the current sources of the clastic sediments and estimate the source variability over the last 600 years. Major element results indicate that Lake Le Bourget sediments consist of 45% clastic component and 55% endogenic calcite. In addition, several individual flood levels have been identified during the Little Ice Age (LIA) on the basis of their higher clastic content (> 70%).Potential sources of Lake Le Bourget clastic sediments have been investigated from Sr and Nd isotope compositions. The sediments from the Sierroz River and Leysse River which are mainly derived from the Mesozoic Calcareous Massifs are characterised by lower ⁸⁷Sr/⁸⁶Sr ratios and slightly lower ?_Nd(0) ratios than the Arve River sediments which are derived from the Palaeozoic Mont-Blanc External Crystalline Massifs. The Rhône River appears to have been the main source of clastic sediments into the lake for the last 600 years, as evidenced by a similar Sr and Nd isotopic compositions analyzed in core B16 sediments (⁸⁷Sr/⁸⁶Sr = 0.719, ?_Nd(0) = − 10) and in the sediments of the Rhône River (⁸⁷Sr/⁸⁶Sr = 0.719, ?_Nd(0) = − 9.6).The isotopic signatures of flood events and background samples from core B16 in Lake Le Bourget are also similar. This indicates that prior to ∼ 1800, the inputs into the lake have remained relatively homogeneous with the proportion of clastic component mainly being a function of the palaeohydrology of the Rhone River. Early human modification (deforestation and agriculture) of the lake catchment before the 1800s appears to have had little influence on the source of clastic sediments.  相似文献   

Climate change on the Yucatan Peninsula during the Little Ice Age   总被引：1，自引：0，他引：1  

David A. Hodell  Mark Brenner  Roger Medina-González  Alma Albornaz-Pat 《Quaternary Research》2005,63(2):109-121

We studied a 5.1-m sediment core from Aguada X'caamal (20° 36.6′N, 89° 42.9′W), a small sinkhole lake in northwest Yucatan, Mexico. Between 1400 and 1500 A.D., oxygen isotope ratios of ostracod and gastropod carbonate increased by an average of 2.2‰ and the benthic foraminifer Ammonia beccarii parkinsoniana appeared in the sediment profile, indicating a hydrologic change that included increased lake water salinity. Pollen from a core in nearby Cenote San José Chulchacá showed a decrease in mesic forest taxa during the same period. Oxygen isotopes of shell carbonate in sediment cores from Lakes Chichancanab (19° 53.0′N, 88° 46.0′W) and Salpeten (16° 58.6′N, 89° 40.5′W) to the south also increased in the mid-15th century, but less so than in Aguada X'caamal. Climate change in the 15th century is also supported by historical accounts of cold and famine described in Maya and Aztec chronicles. We conclude that climate became drier on the Yucatan Peninsula in the 15th century A.D. near the onset of the Little Ice Age (LIA). Comparison of results from the Yucatan Peninsula with other circum-Caribbean paleoclimate records indicates a coherent climate response for this region at the beginning of the LIA. At that time, sea surface temperatures cooled and aridity in the circum-Caribbean region increased.  相似文献   

Temporal evolution of sediment supply in Lago Puyehue (Southern Chile) during the last 600 yr and its climatic significance     

Sébastien Bertrand  Xavier Boës  François Charlet  Cristian Espinoza  Bernard Charlier 《Quaternary Research》2005,64(2):163-175

Short-term climate changes in Southern Chile are investigated by a multi-proxy analysis of a 53-cm-long sedimentary sequence selected among eight short cores retrieved in Lago Puyehue (Chile, 40°S). This core contains a 600-yr-long undisturbed record of paleo-precipitation changes. Two measurement methods for sediment density, organic matter and biogenic silica contents are compared and the most appropriate techniques are selected. Together with aluminium and titanium concentrations, grain size and geochemical properties of the organic matter, these proxies are used to demonstrate paleo-precipitation changes around 40°S. Increase of terrigenous particle supply between A.D. 1490 and A.D. 1700 suggests a humid period. Contemporaneously, δ¹³C data show increasing lake productivity, in response to the high nutrient supply. The A.D. 1700-1900 interval is characterized by a decreasing terrigenous supply and increasing δ¹³C values, interpreted as a drying period. The magnetic susceptibility signal, reflecting the terrigenous/biogenic ratio, demonstrates that similar variations occur in all the undisturbed sedimentary environments of Lago Puyehue. The A.D. 1490-1700 wet period is associated with the onset of the European Little Ice Age (LIA) and interpreted as its local signature. This work supports the fact that the LIA was a global event, not only restricted to the Northern Hemisphere.  相似文献