Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile   总被引：1，自引：0，他引：1  

Santiago Andrade  James Moffett  Juan A. Correa   《Marine Chemistry》2006,101(3-4):203-212

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.  相似文献   

Study of macroaggregate composition using FT-IR and H-NMR spectroscopy     

N. Kovac  O. Bajt  J. Faganeli  B. Sket  B. Orel 《Marine Chemistry》2002,78(4)

Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and ¹H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to ¹H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides.  相似文献   

Identification of constitutive androstane receptor cDNA in northern fur seal (Callorhinus ursinus)     

Hiroki Sakai  Hisato Iwata  Eun-Young Kim  Shinsuke Tanabe  Norihisa Baba 《Marine environmental research》2004,58(2-5):107

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新疆北部石炭纪地层、岩相古地理与烃源岩   总被引：8，自引：1，他引：7  

吴晓智  齐雪峰  唐勇  卫延召  侯连华 《现代地质》2008,22(4)

依据近几年新疆区域地质调查结果,结合新疆油田与吐哈油田最新勘探成果,通过区域构造背景和沉积充填演化特征推断石炭系沉积建造样式,理顺了新疆北疆地区石炭纪地层层序,目的是推断石炭纪烃源岩发育层段与主力生烃区范围。下石炭统有效烃源岩分布较广,主要发育于北疆西准噶尔达尔布特山前、博格达山前、准噶尔东部陆东—五彩湾地区早石炭世被动陆缘海相和海陆过渡相沉积盆地;上石炭统有效烃源岩分布相对局限,主要发育于东准噶尔克拉美丽山前石钱滩区、布尔津—吉木乃区及库普—三塘湖区海陆过渡相沉积盆地内。石炭系油气成藏严格遵循"源控论",有效生烃区决定其有效成藏范围,所伴随发育的火山岩体决定其富集程度。优选西准噶尔、东准噶尔、库普—三塘湖区、博格达山前区、布尔津—吉木乃区石炭系烃源岩发育区及其相邻构造带,作为今后石炭系油气勘探战略选区的重要领域和区带。  相似文献   

Application of Spectral Decomposition to Detection of Fracture-Cavity Carbonate Reservoir Beds in the Tahe Oiifieid, Tarim Basin, NW China     

Liu Xiaoping  Yang Xiaolan  Zhang Yazhong  Han Long 《《地质学报》英文版》2008,82(3):530-536

Ordovician fracture-cavity carbonate reservoir beds are the major type of producing formations in the Tahe oilfield, Tarim Basin. The seismic responses of these beds clearly changes depending on the different distance of the fracture-cavity reservoir bed from the top of the section. The seismic reflection becomes weak or is absent when the fracture-cavity reservoir beds are less than 20 ms below the top Ordovician. The effect on top Ordovician reflection became weaker with deeper burial of fracture-cavity reservoir beds but the developed deep fracture-cavity reservoir beds caused stronger reflection in the interior of the Ordovician. This interior reflection can be divided into strong long-axis, irregular and bead string reflections, and was present 80 ms below the top Ordovician. Aimed at understanding reflection characteristics, the spectral decomposition technique, which uses frequency to ＂tune-in＂ bed thickness, was used to predict Ordovician fracture-cavity carbonate formations in the Tahe oilfield. Through finely adjusting the processing parameters of spectral decomposition, it was found that the slice at 30 Hz of the tuned data cube can best represent reservoir bed development. Two large N-S-trending strong reflection belts in the mid-western part of the study area along wells TK440- TK427-TK417B and in the eastern part along wells TK404-TK409 were observed distinctly on the 30 Hz slice and 4-D time-frequency data cube carving. A small N-S trending reflection belt in the southern part along wells T403-TK446B was also clearly identified. The predicted reservoir bed development area coincides with the fracture-cavities connection area confirmed by drilling pressure testing results. Deep karst cavities occur basically in three reservoir bed-development belts identified by the Ordovician interior strong reflection. Spectral decomposition proved to be a useful technique in identifying fracture-cavity reservoir beds.  相似文献   

南海北部深水盆地沉积-构造的差异性及其油气意义   总被引：5，自引：3，他引：2  

吕宝凤  袁亚娟 《大地构造与成矿学》2008,32(4)

南海北部深水区自西向东依次分布着琼东南盆地、珠江口盆地、台西南盆地等新生代被动陆缘盆地,这些盆地经历了大致相当的从裂陷到坳陷的构造演化史,但在张裂活动过程中存在着明显的沉积-构造的差异性。构造沉降特征分析显示:在同一构造带上自西向东有盆地主要构造沉降发生的时段逐步变晚的趋势;在不同构造带上自北向南有盆地主要构造沉降发生的时段逐步变晚的趋势。这种沉积-构造的差异性对烃源岩的发育类型、分布及生储盖组合等方面有明显的控制作用,表现为:裂谷期构造沉降幅度大的盆地,陆相烃源岩发育,以陆生陆储陆盖型成藏组合为主;裂后期构造沉降幅度大的盆地,海相烃源岩发育规模较大,海生海储海盖型成藏组合及混生海储海盖型生储盖组合所占分量逐渐增多。推测渐新统湖相-湖沼相及海陆过渡相源岩和中新统海相烃源岩应是南海北部深水区油气的主要来源,陆生海储海盖型、海生海储海盖型及混生海储海盖型生储盖组合应是深水区基本生储盖组合类型。  相似文献   

新疆伊犁南岸干渠黄土渠段湿陷性分析     

汪海涛  刘晓丽  王思敬 《工程地质学报》2008,16(2):222-228

新疆伊犁南岸干渠工程明渠段沿线风积黄土广布,黄土的湿陷性对工程具重要影响。本文依据规范并考虑工程实际,对区内黄土的湿陷性等级、起始湿陷压力、湿陷性黄土厚度进行了综合分析,分析了挖方渠道黄土的湿陷性程度;并在考虑降雨土体非饱和过程的条件下,对填方渠道土地基的湿陷变形量进行了详细深入的研究。通过分析认为,工程区黄土渠段为非自重湿陷性场地,湿陷等级为Ⅰ～Ⅱ级;压实后的黄土不具湿陷性;无论是挖方渠道还是填方渠道,经过换填处理和设置排水措施后,即可消除湿陷性,无需要再做专门处理措施。  相似文献   

1983～2006年新疆及邻区地震活动的时空格局分析     

朱创鑫  肖清华  马双飞  张旺生 《地质灾害与环境保护》2008,19(2):38-42

利用中国地震台网（CSN）地震目录整理了1983年以来发生在新疆及邻区ML≥3．0的浅源地震,并在MapGIS平台下,运用数字地图技术,制作了分震级、分年份、分月份系列地震图谱,分析地震发生的时空特征,表明：新疆及邻区地震呈带状分布,自北往南可分为阿尔泰地震带、天山地震带、西昆仑地震带和阿尔金地震带;各地震带活动水平不同,前3条地震带在2003年出现地震次数最高值,具有近10年的活动周期,阿尔金地震带地震次数最高值出现在1993年,有约5年的活动周期;各地震带带内活动水平也有一定差异,帕米尔地区地震最为频繁;年内地震主要集中在2、5、8、10月4个月份。  相似文献   

塔里木盆地巴楚地区中奥陶统一间房组露头礁滩复合体储层地质建模及其对塔中地区油气勘探的启示   总被引：2，自引：0，他引：2  

沈安江  郑剑锋  顾乔元 《地质通报》2008,27(1):137-148

通过1：5万礁滩复合体地质填图,在巴楚地区共发现大小不等的礁滩复合体90余个,层位为中奥陶统一间房组二段．台缘为礁滩复合体密集发育区,礁滩体规模大,台内为礁滩复合体零星发育区,礁滩体规模小。通过对6个典型礁滩复合体的解剖,研究了礁滩复合体的微相类型、组合和各微相的岩石特征、生物群落,并对其生长发育阶段进行了分析。根据6个典型礁滩复合体及礁间的大量铸体薄片鉴定和物性资料,分析了储层的特征、成因和非均质性,建立了台缘礁及礁间、台内礁及礁间2种背景条件下的储层地质模型。巴楚地区露头礁滩复合体储层地质模型对塔中地区上奥陶统良里塔格组礁滩复合体的勘探具有重要的指导意义,并为勘探实践所证实。  相似文献   

新疆天山公路沿线地质灾害危险性评价     

刘昌容  何政伟  黄爽兵 《四川地质学报》2008,28(1):44-47

新疆天山公路（国道217线）是连接南、北疆的一条重要交通干线。通过调查研究沿线的地质条件,采用多元线性回归分析方法,选取地层岩性、地面坡度、相对高差、构造密度、多年平均降雨量、冻融作用、地震强度、植被覆盖率、开挖深度、灾害的分布密度和规模大小等11个评价因子,建立了地质灾害危险性级别的评价模型,得出了公路沿线的危险性级别图。  相似文献