Comparison of techniques for pre-concentrating radium from seawater     

M. Bourquin  P. van Beek  J.-L. Reyss  M. Souhaut  M.A. Charette  C. Jeandel 《Marine Chemistry》2008,109(3-4):226

In the framework of the KEOPS project (KErguelen: compared study of the Ocean and the Plateau in Surface water), we aimed to provide information on the water mass pathways and vertical mixing on the Kerguelen Plateau, Southern Ocean, based on ²²⁸Ra profiles. Because ²²⁸Ra activities are extremely low in this area (~ 0.1 dpm/100 kg or ~ 2.10^− 18 g kg^− 1), the filtration of large volumes of seawater was required in order to be able to detect it with minimal uncertainty. This challenging study was an opportunity for us to test and compare methods aimed at removing efficiently radium isotopes from seawater. We used Mn-fiber that retains radium and that allows the measurement of all four radium isotopes (²²⁶Ra, ²²⁸Ra, ²²³Ra, ²²⁴Ra). First, we used Niskin bottles or the ship's seawater intake to collect large volumes of seawater that were passed onto Mn-fiber in the laboratory. Second, we filled cartridges with Mn-fiber that we placed in tandem on in situ pumps. Finally, we fixed nylon nets filled with Mn-fiber on the frame of in situ pumps to allow the passive filtration of seawater during the pump deployment.Yields of radium fixation on the cartridges filled with Mn-fiber and placed on in situ pumps are ca. 30% when combining the two cartridges. Because large volumes of seawater can be filtered with these pumps, this yields to effective volumes of 177–280 kg (that is, higher than that recovered from fourteen 12-l Niskin bottles). Finally, the effective volume of seawater that passed through Mn-fiber placed in nylon nets and deployed during 4 h ranged between 125 and 364 kg. Consequently, the two techniques that separate Ra isotopes in situ are good alternatives for pre-concentrating radium from seawater. They can save ship-time by avoiding repeated CTD casts to obtain the large volumes of seawater. This is especially true when in situ pumps are deployed to collect suspended particles. However, both methods only provide ²²⁸Ra/²²⁶Ra ratios. The determination of the ²²⁸Ra specific activity is obtained by multiplying this ratio by the ²²⁶Ra activity measured in a discrete sample collected at the same water depth.  相似文献   

The release of dissolved actinium to the ocean: A global comparison of different end-members   总被引：1，自引：1，他引：0  

Walter Geibert  Matt Charette  Guebuem Kim  Willard S. Moore  Joseph Street  Megan Young  Adina Paytan   《Marine Chemistry》2008,109(3-4):409

The measurement of short-lived ²²³Ra often involves a second measurement for supported activities, which represents ²²⁷Ac in the sample. Here we exploit this fact, presenting a set of 284 values on the oceanic distribution of ²²⁷Ac, which was collected when analyzing water samples for short-lived radium isotopes by the radium delayed coincidence counting system. The present work compiles ²²⁷Ac data from coastal regions all over the northern hemisphere, including values from ground water, from estuaries and lagoons, and from marine end-members. Deep-sea samples from a continental slope off Puerto Rico and from an active vent site near Hawaii complete the overview of ²²⁷Ac near its potential sources.The average ²²⁷Ac activities of nearshore marine end-members range from 0.4 dpm m^− 3 at the Gulf of Mexico to 3.0 dpm m^− 3 in the coastal waters of the Korean Strait. In analogy to ²²⁸Ra, we find the extension of adjacent shelf regions to play a substantial role for ²²⁷Ac activities, although less pronounced than for radium, due to its weaker shelf source. Based on previously published values, we calculate an open ocean ²²⁷Ac inventory of 1.35 * 10¹⁸ dpm ²²⁷Ac_ex in the ocean, which corresponds to 37 moles, or 8.4 kg. This implies a flux of 127 dpm m⁻² y^− 1 from the deep-sea floor. For the shelf regions, we obtain a global inventory of ²²⁷Ac of 4.5 * 10¹⁵ dpm, which cannot be converted directly into a flux value, as the regional loss term of ²²⁷Ac to the open ocean would have to be included.Ac has so far been considered to behave similarly to Ra in the marine environment, with the exception of a strong Ac source in the deep-sea due to ²³¹Pa_ex. Here, we present evidence of geochemical differences between Ac, which is retained in a warm vent system, and Ra, which is readily released [Moore, W.S., Ussler, W. and Paull, C.K., 2008-this issue. Short-lived radium isotopes in the Hawaiian margin: Evidence for large fluid fluxes through the Puna Ridge. Marine Chemistry]. Another potential mechanism of producing deviations in ²²⁷Ac/²²⁸Ra and daughter isotope ratios from the expected production value of lithogenic material is observed at reducing environments, where enrichment in uranium may occur. The presented data here may serve as a reference for including ²²⁷Ac in circulation models, and the overview provides values for some end-members that contribute to the global Ac distribution.  相似文献   

A seasonal carbon budget for the sub-Antarctic Ocean, South of Australia     

B.I. McNeil  B. Tilbrook 《Marine Chemistry》2009,115(3-4):196-210

Changes from winter (July) to summer (February) in mixed layer carbon tracers and nutrients measured in the sub-Antarctic zone (SAZ), south of Australia, were used to derive a seasonal carbon budget. The region showed a strong winter to summer decrease in dissolved inorganic carbon (DIC;  45 µmol/kg) and fugacity of carbon dioxide (fCO₂;  25 µatm), and an increase in stable carbon isotopic composition of DIC (δ¹³C_DIC;  0.5‰), based on data collected between November 1997 and July 1999.The observed mixed layer changes are due to a combination of ocean mixing, air–sea exchange of CO₂, and biological carbon production and export. After correction for mixing, we find that DIC decreases by up to 42 ± 3 µmol/kg from winter (July) to summer (February), with δ¹³C_DIC enriched by up to 0.45 ± 0.05‰ for the same period. The enrichment of δ¹³C_DIC between winter and summer is due to the preferential uptake of ¹²CO₂ by marine phytoplankton during photosynthesis. Biological processes dominate the seasonal carbon budget (≈ 80%), while air–sea exchange of CO₂ (≈ 10%) and mixing (≈ 10%) have smaller effects. We found the seasonal amplitude of fCO₂ to be about half that of a study undertaken during 1991–1995 [Metzl, N., Tilbrook, B. and Poisson, A., 1999. The annual fCO₂ cycle and the air–sea CO₂ flux in the sub-Antarctic Ocean. Tellus Series B—Chemical and Physical Meteorology, 51(4): 849–861.] for the same region, indicating that SAZ may undergo significant inter-annual variations in surface fCO₂. The seasonal DIC depletion implies a minimum biological carbon export of 3400 mmol C/ m² from July to February. A comparison with nutrient changes indicates that organic carbon export occurs close to Redfield values (ΔP:ΔN:ΔC = 1:16:119). Extrapolating our estimates to the circumpolar sub-Antarctic Ocean implies a minimum organic carbon export of 0.65 GtC from the July to February period, about 5–7% of estimates of global export flux. Our estimate for biological carbon export is an order of magnitude greater than anthropogenic CO₂ uptake in the same region and suggests that changes in biological export in the region may have large implications for future CO₂ uptake by the ocean.  相似文献   

大尺度环流系统对西北太平洋变性TC频数影响的气候诊断分析     

钟颖旻  徐明 《成都信息工程学院学报》2007,22(3):374-378

基于中国热带气旋年鉴资料,从气候学角度出发,对西北太平洋TC(热带气旋)发生温带变性的频数与大尺度环流系统间的关系进行了诊断和分析.研究发现变性TC多发生于夏、秋两季,通过对NCEP月平均再分析资料的500hPa高度场进行EOF分解,发现西北太平洋TC变性的频数与65°N附近强冷高压系统在夏、秋两季都存在着正相关关系,且相关性在秋季高于夏季;与30°N附近强副热带高压系统存在负相关关系,夏季副热带高压系统的作用更大;与30°N以南西北太平洋多台风活动区域的弱低压存在显著的负相关,低压越弱,对流越弱,则TC的生成数越少,其中发生变性的TC数也会减少.500hPa高度场EOF分解的第一特征向量所对应的时间函数分布在20世纪70年代中期前后出现了反号,较好地对应了变性TC年频数的年际变化趋势,70年代中期之前变性TC呈总体偏多,之后变性TC的频数总体偏少,呈明显下降趋势.  相似文献   

Combining 2D-basin and structural modelling to constrain heat transport along the Muroto Transect,Nankai Trough,Japan     

Robert Ondrak  Christoph Gaedicke  Brian Horsfield 《Marine and Petroleum Geology》2009

The Nankai Trough located southeast of Shikoku Island, Japan, exhibits a zone of exceptionally high heat flow. In the central part of the Nankai Trough the fossil spreading centre of the Shikoku Basin is subducted beneath the southwest Japan arc. We have modelled the temperature and maturation history along the Muroto Transect reaching from the tip of the thrust zone out into nearly undeformed Quaternary and Tertiary sediments seawards of Nankai Trough. We used two balanced cross-sections defining the sections before and after overthrusting as input for 2D-basin modelling. We can show that rapid burial and overthrusting during the Quaternary in combination with a heat flow history following the cooling curve of a 15 Ma old oceanic plate is not sufficient to explain the measured maturity of organic material in the sediments. Several heat flow scenarios derived from theoretical concepts [Yamano, M., Kinoshita, M., Goto, S., Matsubayashi, O., 2003. Extremely high heat flow anomaly in the middle part of the Nankai Trough. Physics and Chemistry of the Earth, Parts A/B/C 28, 487–497.] and previous modelling approaches [e.g. Brown, K.M., Saffer, D.M., Bekins, B.A., 2001. Smectite diagenesis, pore water freshening, and fluid flow at the toe of the Nankai wedge. Earth and Planetary Science Letters 194, 97–109; Spinelli, G.A., Underwood, M.B., 2005. Modeling thermal history of subducting crust in Nankai Trough: constraints from in situ sediment temperature and diagenetic reaction progress. Geophysical Research Letters 32(L09301): doi:10.1029/2005GL022793; Steurer, J., Underwood, M.B., 2003. Clay mineralogy of mudstones from the Nankai Trough reference sites 1173 and 1177 and frontal accretionary prism site 1174. In: H. Mikada et al. (Eds.), pp. 1–37. Available from: <http://www-odp.tamu.edu/publications/190196SR/VOLUME/CHAPTERS/211.PDF>] were tested. The best match between observed maturity levels, temperature and heat flow measurements is reached for a heat flow history which initially assumes the cooling of a 15 Ma old oceanic lithosphere but is reheated to 170–180 mW/m² during the phase of rapid burial in the Quaternary. This can be achieved either by assuming the onset of hydrothermal circulation in the cooling crust or by reheating caused by off-axis volcanism at about 6 Ma [Yamano, M., Kinoshita, M., Goto, S., Matsubayashi, O., 2003. Extremely high heat flow anomaly in the middle part of the Nankai Trough. Physics and Chemistry of the Earth, Parts A/B/C 28, 487–497.].  相似文献   

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于胜杰  柳林涛 《大地测量与地球动力学》2008,28(5):34-38

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Role of unusual moisture transport across Equatorial Indian Ocean on the extreme rainfall event during Kerala flood 2018     

《Dynamics of Atmospheres and Oceans》2021

Southwestern Indian state, Kerala experienced extreme devastating statewide flood event of the century during 2018 monsoon season. In this study, an attempt has been made to bring out the salient dynamical factors contributed to the Kerala flood. There were 3 active spells over Kerala during 2018 Monsoon season. All the three spells were accustomed with the intrinsic factors of low frequency components of the active spells such as strength of monsoon Low Level Jet (LLJ), Monsoon depressions in the Bay of Bengal, favorable Madden-Julian oscillation (MJO) phases and Western Pacific systems. Though all the common ingredients remain same, the third spell is distinct with the less evaporation flux over Western and Central Arabian Sea and unusual moisture transport from maritime continent through South Equatorial Indian ocean (SEIO) towards the Kerala coast across Equator. Strong meridional pressure gradient force created by the combined effect of high pressure anomaly oriented Northwest-Southeast direction across tropical Indian ocean and anomalous low pressure along monsoon trough might have contributed to this unusual moisture transport across SEIO originating from west of Australia. The anomalous high pressure in South Indian ocean was greatly influenced by the position of the Mascarene high. Subtropical Indian ocean dipole (SIOD) also exhibits an influential role by altering tropical Southern Indian ocean dynamics in favor of the unusual moisture transport. The position of the monsoon depression and presence of typhoons in Western Pacific might have aided to this moisture transport. However, the normal moisture transport from Central Arabian sea towards Kerala coast by virtue of the strong LLJ along with additional moisture transport directly from South of maritime continent through SEIO across the Equator towards Kerala coast might have played a dominant role in the historical flood event over entire Kerala state.  相似文献   

末次间冰期以来门捷列夫洋脊南部冰盖对细颗粒沉积的控制作用   总被引：1，自引：1，他引：0  

叶黎明  于晓果  章伟艳  王嵘 《海洋学报(英文版)》2020,39(9):86-95

门捷列夫洋脊南部的粘土矿物沉积具有明确的物源，为追踪该区沉积环境的演变提供了良好的条件。末次间冰期以来，ARC7-E23孔中的粘土矿物记录表现出了非常显著的变化。结合沉积物粒度的端元组份和冰阀碎屑沉积，粘土矿物的变化模式表明，东西伯利亚冰盖(ESIS)的规模可能是控制细颗粒沉积的主要因素。在氧同位素2期(MIS2)和4期(MIS4)，门捷列夫洋脊南部可能被ESIS所覆盖，几乎阻挡了所有来自加拿大和拉夫贴夫海陆架的沉积物，但允许大量来自东西伯利亚海陆架的细粒沉积物输入。只有当ESIS消融后，波弗特环流和越极流的相对强度以及搬运作用才成为了控制远源沉积物输入的主要因素。MIS3期的气候条件似乎最适合远源沉积物的输入，不仅提高了表层环流的流通性，也提供了足够多的搬运介质。  相似文献   

孟加拉湾障碍层年际变化及其与印度洋偶极子事件的联系   总被引：1，自引：1，他引：0  

郭文仪  邱云  林新宇 《海洋学报》2020,42(9):38-49

利用1980?2015年SODA温盐资料，结合Argo数据分析了印度洋偶极子(IOD)事件年份孟加拉湾障碍层的变化特征及其形成机制。结果表明，IOD事件年份孟加拉湾障碍层变化显著。纯的正IOD(纯pIOD)年份及伴随型pIOD年份盛期(9?11月)，除孟加拉湾内西南海域障碍层厚度略变厚约5 m外，赤道海域、安达曼海至孟加拉湾北部障碍层厚度均变薄5～15 m，此障碍层距平盛期形态在纯pIOD年份随pIOD消亡迅速消退，但在伴随型pIOD年份维持至翌年3?5月才开始弱化。纯的负IOD (纯nIOD)年份障碍层厚度变化特征与pIOD年份大体相反。进一步分析表明，IOD事件年份赤道风场距平的远地强迫造成等温层深度的变化是湾内障碍层变化的主因。在伴随型IOD年份，受ENSO事件的影响，赤道风场距平在IOD消亡后仍得以维持3个月以上，使得湾内障碍层距平形态持续更久。除赤道远地强迫外，湾内局地风场的Ekman抽吸作用以及混合盐度变化对障碍层厚度年际变化也有一定影响。  相似文献   

The Kings River Experimental Watersheds: Infrastructure and data     

Joseph W. Wagenbrenner  David N. Dralle  Mohammad Safeeq  Carolyn T. Hunsaker 《水文研究》2021,35(5):e14142

The Kings River Experimental Watersheds (KREW) were established in 2002 to expand our knowledge of catchment physical, chemical, and biological processes in Sierra Nevada headwater forests, and to better understand the impacts of prescribed burning and forest thinning on these processes. Two elevation strata (high and low) were selected for the KREW sites, with four independent catchments and one nested catchment within each stratum. Both high and low elevation study areas were instrumented for continuous measurements of meteorology, streamflow, and turbidity. Atmospheric and stream chemistry, suspended sediment concentration, and bedload sediment delivery were measured on a regular schedule. Soil chemical and physical properties and vegetation were systematically sampled before and after the initial thinning and prescribed burning treatments, which were implemented between 2012 and 2016. Post-treatment data collection continues today as we explore opportunities for the second round of possible treatments. The critical research infrastructure and long-term baseline data collection has been instrumental in building partnerships with downstream managers, end users, non-governmental organizations, academic researchers, and national research programmes. Contributions to date include fundamental understanding of magnitude and variability of nutrient deposition; carbon, nutrient, and major ion dynamics in headwater streams; aquatic algae and macroinvertebrate populations; vegetation composition and structure; and streamflow responses to precipitation in the two elevation strata. Data from the experimental watersheds also support calibration and validation of diverse hydrologic models used for water resources planning.  相似文献