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ZAHEER Iqbal CUI Guang Bai Ph D candidate College of Water Resources Environment Hohai University Nanjing China E-mail: zaheeriqbal@hotmail.com Prof. College of Water Resources Environment Hohai University Nanjing China 《国际泥沙研究》2002,17(2)
1 INTRODUCTION Numerical computation provides an easily extended and user-friendly environment with computer aided programming for the simulation of pollutants in river systems. In the most of water quality assessment and monitoring problems during water pollution control and environmental impact assessment studies of river systems, mathematical modeling has been playing a key role for the last two decades. The majority of existing water quality models are the mechanistic and are based o… 相似文献
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A manual SPME method is presented for the analysis of organic compounds in industrial wastewater. 24 compounds commonly found in the wastewater of a chemical plant in northern Germany have been selected as reference compounds. Precision, linearity, and detection limits have been determined. Moreover, the effect of methanol content, pH value, salt content, and an excess of compounds on the extraction process have been studied. Several compounds have been investigated for their applicability as internal standards to quantify the compounds of interest. Since the method will later be transferred to a fully automated SPME-GC system, which will be operated directly on-site at an industrial wastewater purification plant, special attention has been paid to the analysis of real wastewater samples. In this context, the fibre stability has been studied by performing 53 extraction/desorption cycles from one wastewater sample. Neither a decrease in fibre performance nor in precision has been observed indicating that the proposed method is suitable for the analysis of real wastewater. 相似文献
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为改善油气田开采过程中的环境,本文结合主成分分析法(Principal Component Analysis)与污染物迁移模型,对研究区的油气田开采过程中的污染物进行了分析,主要研究其在土壤中的迁移程度。本研究首先介绍了油气田开采产生污染物的研究背景与污染物种类,其次结合主成分分析法对污染物中的主要成分进行了筛选,最后构建污染物迁移模型,对污染物在土壤以及水体中的迁移进行了研究。结果表明,本文中的主要污染物为石油类、酸、氟离子、氯离子和COD(Chemical Oxygen Demand)、BOD(Biochemical oxygen demand),石油类所占比重最大,为23.63%;石油类污染物在黑钙土中的迁移最广,直至土层厚度为35cm,污染物浓度从18365 mg/kg降到0;石油类污染物在黑钙土中的迁移符合负指数规律;当酸液浓度在1%、2%、3%、4%时,氢离子在土壤中随深度的变化一致,土层厚度为20cm时,11%的酸液酸值高于低浓度土壤酸值,11%的酸液在快速淋滤状态下比缓慢淋滤快一步到达定值;氯离子和氟离子的迁移深度变化基本符合负指数变化规律;低浓度的污染物比高浓度的污染物更早达到定值;石油类污染物在土壤中的迁移能力较弱;本次研究实验值与模拟值基本一致,研究成果良好。石油类污染物在土壤中的迁移能力较弱,酸性污染物对土壤有一定影响。 相似文献
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Petroleum pollution has become an important factor to threaten the groundwater environment, and the classification of its typical characteristics will contribute to pollution assessment and environmental management. Under the same hydrogeological features con?dition, the reaction of typical petroleum pollutants in groundwater depends on the charac?teristics. This paper takes the typical toxicity, oil pollutant migration, degradation, water-soluble etc. as evaluation indexes, and with AHP method the typical petroleum pollut?ants in groundwater are divided into four classifications according to comprehensive calculated values: comprehensive value≥2.5, Class I hazardous pollutant; 2.0≤comprehensive value<2.5, Class II hazardous pollutant; 1.5≤comprehensive value<2.0, Class III hazardous po?llutant; comprehensive value<1.5, Class IV hazardous pollutant. The pollutant group shall be managed according to the classification, and obtained classification list will provide technical support for priority monitoring and priority repair of groundwater environmental management. 相似文献
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苏州灰霾特征分析 总被引:10,自引:5,他引:5
利用苏州市2009年6月-2010年5月逐时的能见度、相对湿度、污染物(PM1o、PM2.5、黑碳)浓度和散射系数等资料进行灰霾的判识与统计分析,结果表明:苏州市灰霾日占全年天数的46.6%,雨日和“蓝天”分别占33.2%和21.9%.在苏州所有灰霾日中以轻微灰霾为主,占灰霾曰总数的70.6%,发生中度和重度灰霾的频率较小.灰霾出现频率的日变化规律表明白天出现灰霾的频率比夜间低,在5-8时灰霾出现的频率达到峰值,14-16时灰霾出现的频率最低.灰霾日的污染物浓度远大于非灰霾日,随着灰霾等级增大,黑碳浓度明显增大;除重度灰霾外,PM10和PM2.5浓度也明显增大;散射系数增大. 相似文献
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2010年太原空气污染物特征及环流形势 总被引:1,自引:0,他引:1
利用太原市2010年6个环境监测站SO2、NO2、PM10的逐日监测资料和MICAPS、自动站逐日资料,应用统计方法分析了太原市污染物的时空分布特征,并分析了污染严重时期的大气环流形势特点。结果表明:随着城市工业结构变化、集中供暖布局改变、以及住宅小区建设,PM10。已不再是首要污染物,3种污染物的时空分布特征均发生了明显变化;大气结构对污染物扩散的影响也呈现复杂化的特点。 相似文献
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An environmental capacity model for the petroleum hydrocarbon pollutions (PHs) in Jiaozhou Bay is constructed based on field surveys, mesocosm, and parallel laboratory experiments. Simulated results of PHs seasonal successions in 2003 match the field surveys of Jiaozhou Bay resaonably well with a highest value in July. The Monte Carlo analysis confirms that the variation of PHs concentration significantly correlates with the river input. The water body in the bay is reasonably subjected to self-purification processes, such as volatilization to the atmosphere, biodegradation by microorganism, and transport to the Yellow Sea by water exchange. The environmental capacity of PHs in Jiaozhou Bay is 1500 tons per year IF the seawater quality criterion (Grade Ⅰ/Ⅱ, 0.05 mgL-1) in the region is to be satisfied. The contribution to self-purification by volatilization, biodegradation, and transport to the Yellow Sea accounts for 48%, 28%, and 23%, respectively, which make these three processes the main ways of PHs purification in Jiaozhou Bay. 相似文献
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It was previously observed that sodium dodecylbenzenesulfonate (SDBS) is degraded in the presence of chrysotile fibres. A higher catalytic efficiency was obtained than the reported values for TiO2 under the same conditions. Chrysotile, a clay mineral fibre of low cost and relatively abundant, probably acts as a catalyst through an Advanced Oxidative Process (AOP) involving free radical formation. In this work, experiments with non‐ionic – Triton X‐45 (octil‐phenoxy polyethoxy ethanol) – and cationic – Herquat 3500 (alkyl dimethyl benzyl ammonium chloride) – surfactants were carried out. Diluted aqueous solutions (50 ppm) of these surfactants were kept in contact with chrysotile (4.0 g) in the dark at room temperature. The aromatic ring disappearance was followed through the absorbance peaks at 224 nm (Triton X‐45) and 208 nm (Herquat 3500) in the UV spectra. After 4 h, reductions in the surfactant solution concentration of 65.0% and 35.0% were observed for the Triton X‐45 and the Herquat 3500 surfactants, respectively. In both cases, reactions carried out without aeration showed a lower reduction of the aromatic ring concentration (30.0% less) when compared to the values obtained for the systems with airflow. The system containing the non‐ionic surfactant seems to achieve equilibrium after 2 h, what is not observed for the cationic surfactant system. 相似文献
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Impact of a sea breeze on the boundary-layer dynamics and the atmospheric stratification in a coastal area of the North Sea 总被引:1,自引:0,他引:1
Charles Talbot Patrick Augustin Céline Leroy Véronique Willart Hervé Delbarre Georgui Khomenko 《Boundary-Layer Meteorology》2007,125(1):133-154
In-situ sodar and lidar measurements were coupled with numerical simulations for studying a sea-breeze event in a flat coastal
area of the North Sea. The study’s aims included the recognition of the dynamics of a sea-breeze structure, and its effects
on the lower troposphere stratification and the three-dimensional (3D) pollutant distribution. A sea breeze was observed with
ground-based remote sensing instruments and analysed by means of numerical simulations using the 3D non-hydrostatic atmospheric
model Meso-NH. The vertical structure of the lower troposphere was experimentally determined from the lidar and sodar measurements,
while numerical simulations focused on the propagation of the sea breeze inland. The sea-breeze front, the headwind, the thermal
internal boundary layer, the gravity current and the sea-breeze circulation were observed and analysed. The development of
a late stratification was also observed by the lidar and simulated by the model, suggesting the formation of a stable multilayered
structure. The transport of passive tracers inside the sea breeze and their redistribution above the gravity current was simulated
too. Numerical modelling showed that local pollutants may travel backward to the sea above the gravity current at relatively
low speed due to the shearing between the landward gravity current and the seaward synoptic wind. Such dynamic conditions
may enhance an accumulation of pollutants above coastal industrial areas. 相似文献