Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer     

Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   

Double–double radio galaxies: remnants of merged supermassive binary black holes     

F. K. Liu  Xue-Bing Wu  S. L. Cao 《Monthly notices of the Royal Astronomical Society》2003,340(2):411-416

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用双三次样条函数和GPS资料反演现今中国大陆构造形变场   总被引：38，自引：20，他引：18  

杨少敏  游新兆  杜瑞林  乔学军  王琪 《大地测量与地球动力学》2002,22(1):68-75

将中国大陆现今构造变动视为一种连续的地壳变形,利用双三次样条函数模拟了近期GPS测定的大陆内部及周边地区412个测站速率,反演大陆地区自洽的构造变动速度场和应变率场.模拟结果显示:印度板块与欧亚板块的碰撞、挤压是构成中国大陆内部岩石层水平形变的主要驱动力.印度板块在东喜马拉雅构造结深深插入青藏高原,造成地壳大规模的缩短和抬升.青藏高原东南部的喜马拉雅带、拉萨和羌塘地块以及青藏高原东南边的川滇地区,内部构造活动强烈,其内部的构造变形包含地壳碎片的冲断、褶皱和侧向逃逸.大陆地壳(或岩石圈)的增厚,尤其是喜马拉雅山脉南北向的快速缩短和青藏高原东西向的缓慢拉张,大约吸收了印欧板块会聚量的85%,西藏中东地区东西向的拉张速率达到了(16±2.0)mm/a,且顺时针方向扭转明显.印度板块相对欧亚板块运动的欧拉极为(29.7°N, 19.3°E, 0.392°/Ma);华南地块相对于欧亚大陆向东(102°±7.4°)南的运动速率是(11±1.54)mm/a,华南块体相对欧亚板块运动的欧拉极为(62.25°N, 126.56°E, 0.141°/Ma);塔里木地块相对较稳定,其西部运动速度高于东部运动速度,作顺时针方向旋转.总体上讲,中国大陆运动方向为北偏东呈辐射状,从西部近南北方向的运动转向东部地区东南方向的运动,绕东喜马拉雅构造结有一顺时针方向的旋转.横穿喜马拉雅构造带及青藏内部的南北向压缩速率为(19±2.0)mm/a,横穿西天山构造带的南北向压缩平均速率为(13±1.5)mm/a,横穿东天山构造带的南北向压缩平均速率为(6.0±1.4)mm/a.阿尔金断裂带的左旋走滑速率为(6±1.2)mm/a.  相似文献   

THE POSITION AND ROLES OF PORTS AND RAILWAYS IN THE EURASIA LAND BRIDGE TRANSPORTATION IN NORTHEAST CHINA     

叶宝明  李文杰 《中国地理科学(英文版)》1992,2(3):235-244

This paper systematically analyzes and proves the favorable factors of utilizing the ports and the railways in Northeast China for the Asia-Europe land bridge transportation. It will be more beneficial to Dalian Port and HaDa (Harbin-Dalian) and Binzhou (Harbin-Manzhouli) railways in Northeast China to the Siberia railway in Russia than 1) to other ports and the corresponding railways in China, 2) to the Nakhodka Port in Russia and the corresponding railways and 3) to the Chongjin Port in North Korea and the corresponding railways. This paper also puts forward the reform measures to adopt the ports and the railways in the northeast region in China for the land bridge transportation and the problems in transportation policies and management systems.  相似文献   

Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

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Revised masses of dust and gas of SCUBA Local Universe Survey far-infrared bright galaxies based on a recent CO survey     

Ernest Seaquist  Lihong Yao  Loretta Dunne  Heather Cameron 《Monthly notices of the Royal Astronomical Society》2004,349(4):1428-1434

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Geochemical survey of thermal system in Northeast China and their geothermometric characters     

MohammedHazaea HUKe MohammedMattash CHENBing M.O.AI-JabaliAref MohammedAbdussalam 《东北亚地学研究》2004,7(2):181-184

The chemical composition of several thermal springs around Changbaishan area has been investigated. Cenozoic basaltic rocks are widely distributed in Northeast China and geothermal characteristics have been described. About one hundred hot springs exist around Changhaishan Volcano at the border between China and D.P.R.Korea with high temperature about 82~C. The pH values of the spring water range from 6.9 to 7.1 and the total flow rate is about 4.8 L/sec. The chemical composition of the thermal springs is sodium carbonate; the high-mineral contents of thermal water are believed to have medicinal properties. Bathhouses are already built along the hot springs to take the advantage of the supposed healing properties. The high quality of those hot springs is believed to be utilitized for mineral water. The chemical equilibrium temperatures were estimated at about 160℃ based on the Na-K-Ca geochemical thermometer.  相似文献   

地壳对海洋潮汐的响应   总被引：2，自引：2，他引：0  

郑文衡  王乘  何振  牛安福 《大地测量与地球动力学》2002,22(2):41-46

应用三维动态有限元方法研究了中国北部地区的地壳对邻近的渤海与黄海海平面变化的响应。虽然此应力场过于微弱不足以引发地震，但发现应力集中的位置及应力场变化较大的位置恰好与某些现代地震的震中一致。这一结果表明研究地壳对广泛分布的载荷的响应对研究区域地震构造是有帮助的。  相似文献   

基于SAR干涉点目标分析技术的城市地表形变监测   总被引：1，自引：0，他引：1  

张永红  张继贤  龚文瑜  LU Z 《测绘学报》2009,38(6)

通过深入研究干涉点目标的相位模型,提出基于空间搜索的邻近点目标干涉相位差解缠方法,用以计算点目标的地形残差和线性形变,以及分离点目标大气延迟相位和非线性形变相位的时空域滤波方法,解决干涉点目标分析中的关键问题.最后,以苏州地区地表沉降监测为应用试验,利用形成的SAR干涉点目标形变信息提取技术,获取苏州市区1992-2002年间的地表沉降信息.研究结果与已有文献记录保持比较好的一致性,证明SAR干涉点目标技术完全可以发展成为应用于城市地表形变监测的实用化技术.

Abstract：

Interferometric point target analysis (IPTA) is one of the latest developments in radar interferometric processing. It is achieved by analysis of the interferometric phases of some individual point targets, which are discrete and present temporarily stable backscattering characteristics, in long temporal series of interferometric SAR images. This paper analyzes the interferometric phase model of point targets, and then addresses two key issues within IPTA process. Firstly, a spatial searching method is proposed to unwrap the interferometric phase difference between two neighboring point targets. The height residual error and linear deformation rate of each point target can then be calculated, when a global reference point with known height correction and deformation history is chosen. Secondly, a spatial-temporal filtering scheme is proposed to further separate the atmosphere phase and nonlinear deformation phase from the residual interferometric phase. Finally, an experiment of the developed IPTA methodology is conducted over Suzhou urban area. Totally 38 ERS-1/2 SAR scenes are analyzed, and the deformation information over 3 546 point targets in the time span of 1992-2002 are generated. The IPTA-derivecl deformation shows very good agreement with the published result, which demonstrates that the IPTA technique can be developed into an operational tool to map the ground subsidence over urban area.  相似文献