Analysis of rock drainage and cooling experiments for underground cryogenic LNG storage     

Sung-Soo Cha  Kang-Kun Lee  Gwang-Ok Bae  Dae-Hyuck Lee  Nicolas Gatelier 《Engineering Geology》2007,93(3-4):117-129

Hydrogeological monitoring was conducted around a pilot cavern for underground cryogenic LNG (Liquefied Natural Gas) storage. The monitoring was mainly focused on the operation of a drainage and recharge system. After the operation of the drainage system commenced, the drainage rate decreased rapidly in the initial stages and then decreased gradually. Hydrogeological monitoring revealed that the rock drainage system operated effectively. During drainage, the water table was maintained below the cavern roof. The recharge for ice-ring formation was performed in two phases. The first phase involved the cessation of pumping in downward-drainage holes and the second involved the closure of upward boreholes. Since the water table was maintained below the cavern roof, artificial recharge was planned at first. However, it was not implemented due to heavy rainfall in the recharge stage. On the basis of hydrogeological monitoring and hydraulic tests, it was found that the fractures above the roof and on the right wall of the pilot cavern mainly affected seepage into the cavern and thermal variation due to the storage of liquid nitrogen. Thermal variation was examined by the thermometers installed around the pilot cavern. The cooling and thawing processes reveal the characteristics of thermal distribution in the rock and the 0 °C isotherm. The cooling phase lasted for six months, and the 0 °C isotherm progressed in time after the injection of liquid nitrogen into the cavern. The isotherm propagated up to about 4 m from the floor and the sidewall of the cavern and about 3 m from the cavern roof. The cooling rate of the rock mass above the cavern roof was lower than that of the other cavern sides due to the gaseous space in the upper part of the containment. The fractures were analyzed and considered for thermal modeling. A two-dimensional finite element analysis was performed to compare the field monitoring at the pilot cavern. The numerical modeling shows the distance between the ice ring and heat transfer pattern of the fractures around the pilot cavern. The propagation of the measured and calculated 0 °C isotherm reveals that the water-conveying joint on the right wall might affect thermal propagation through a thermal pipe.  相似文献   

The Kuwae (Vanuatu) eruption of<Emphasis Type="SmallCaps"> AD</Emphasis> 1452: potential magnitude and volatile release     

J. B. Witter  S. Self 《Bulletin of Volcanology》2007,69(3):301-318

Sometime during AD 1452, according to new evidence, a large-magnitude, initially phreatomagmatic eruption, destroyed the island of Kuwae (16.83°S, 168.54°E), located in the present-day Republic of Vanuatu. It created a 12×6-km submarine caldera composed of two adjacent basins. Based on estimates of caldera volume, between 30 and 60 km³ DRE of dacite magma was ejected as pyroclastic flow and fall deposits during this event. Annual layers of ice dating from the period AD 1450–1460 contain acidity peaks representing fallout of sulfuric acid onto both the Greenland and Antarctic ice caps. These acidity peaks have been attributed by others to the sedimentation of H₂SO₄ aerosols that originated from sulfur degassing during the Kuwae eruption. Improved dating techniques and new data from nineteen ice cores reveal a single acidity peak attributed to Kuwae lasting from 1453 to 1457. In this study, we present new electron microprobe analyses of the S, Cl, and F contents of matrix glasses and glass inclusions in phenocrysts from tephra ejected during the Kuwae eruption. We establish that the Kuwae event did indeed yield a large release of sulfur gases. From our glass inclusion data and analysis, we calculate that the total atmospheric aerosol loading from the 1452 Kuwae eruption was ≫100 Tg H₂SO₄. Much of the volatile mass released during the eruption was probably contained in a separate, volatile-rich, fluid phase within the pre-eruptive Kuwae magma body. Comparing the volatile release of the Kuwae eruption with other large-magnitude eruptions, places Kuwae as the greatest sulfuric acid aerosol producer in the last seven centuries, larger even than sulfur emissions from the eruption of Tambora (Indonesia) in 1815, and possibly Laki (Iceland) in 1783. The severe and unusual climatic effects reported in the mid- to late-1450s were likely caused by the Kuwae eruption.  相似文献   

Peatland development at the arctic tree line (Québec, Canada) influenced by flooding and permafrost     

Najat Bhiry  Serge Payette  lisabeth C. Robert 《Quaternary Research》2007,67(3):426-437

In this study, we documented the Holocene history of a peat plateau at the arctic tree line in northern Québec using stratigraphic and macrofossil analyses to highlight the effects of geomorphic setting in peatland development. Paludification of the site began about 6800 cal yr BP. From 6390 to 4120 cal yr BP, the peatland experienced a series of flooding events. The location of the peatland in a depression bounded by two small lakes likely explains its sensitivity to runoff. The proximity of a large hill bordering the peatland to the south possibly favored the inflow of mineral-laden water. The onset of permafrost aggradation in several parts of the peatland occurred after 3670 cal yr BP. Uplifting of the peatland surface caused by permafrost stopped the flooding. According to radiocarbon dating of the uppermost peat layers, permafrost distribution progressed from the east to the west of the peatland, indicating differential timing for the initiation of permafrost throughout the peatland. Most of the peatland was affected by permafrost growth during the Little Ice Age. Picea mariana macroremains at 6450 cal yr BP indicate that the species was present during the early stages of peatland development, which occurred soon after the sea regression.  相似文献   

中国小冰期的气候   总被引：37，自引：2，他引：35       下载免费PDF全文

王绍武  叶瑾琳  龚道溢 《第四纪研究》1998,18(1):54-64

在建立了近百年中国10个区的年平均气温序列的基础上,利用史料、冰芯δ18O及树木年轮,重建了各区近400～1000年的10年平均气温序列。分析表明,近千年来中国可能有5次冷期分别出现于1100’s～1150’s,1300’s～1390’s,1450’s～1510’s,1560’s～1690’s及1790’S～1890’S。第4次冷期主要在中国大陆中部最明显,而第5次冷期在中国南部较强。新疆、东北及闽台气温变化与中国其它部分特别是南部及西南有一定差异。如果把最后两次冷期作为中国小冰期的两次主要寒冷阶段,其30年平均气温可能比20世纪中期中国最暖的30年(1920’S～1940’S)低0．6～0．11℃。  相似文献   

可可西里苟仁错湖泊沉积物元素地球化学特征及其环境意义   总被引：18，自引：4，他引：14  

吴艳宏  李世杰  夏威岚 《地球科学与环境学报》2004,26(3):64-68

湖泊沉积物元素地球化学特征及其比值，有效地揭示了湖泊沉积物物源区的化学风化程度．已成为反映古气候波动的有效指标。根据可可西里苟仁错湖泊沉积物的元素地球化学特征，通过CIA，ICV等元素比值的结果，揭示该地区1400AD以来化学风化作用十分微弱，因此湖泊沉积物元素组成，对气候变化非常敏感。研究表明1400AD以来该地区气候经历多次冷暖波动，且呈干旱化的趋势，1420AD左右进入小冰期，其中1480～1520AD最为寒冷，1900AD后干旱化加剧。  相似文献   

Sea level induced variations in clay mineral composition in the southwestern South China Sea over the past 17,000 yr     

Stephan Steinke  Till J.J. Hanebuth  Christoph Vogt  Karl Stattegger 《Marine Geology》2008,250(3-4):199-210

Variations in clay mineral composition of sediment cores from the margin and continental slope of the Sunda Shelf (southern South China Sea, SE Asia) covering the past 17,000 yr reflect changing influences of sediment sources together with clay mineral partitioning processes in shallow waters. We identify the deglacial sea level rise as the principal factor driving these changes. During the late glacial, high values of kaolinite are interpreted to reflect a higher contribution of clays from soils that have formed on the exposed Sunda Shelf and in the southern archipelagos of Indonesia. At this time core sites were located in close proximity to the mouths of the Sunda Shelf palaeo-drainage systems on the emerged shelf (“Sundaland”). The progressive landward displacement of the coastline and breakdown of these vast drainage systems during deglaciation led to a decrease in influence of the kaolinite-rich southern sources. When the coastline had retreated closely to its present-day position in mid-Holocene times, the former dominance of southern sources was replaced by a stronger influence of illite-rich sources (e.g. Borneo). The overriding control of sea level changes on the clay mineral distribution patterns precludes a definite climatic interpretation of clay mineral data in terms of climatic/monsoonal changes in such highly dynamic sedimentary environment.  相似文献   

Geometry and architectural associations of co-genetic debrite–turbidite beds in basin-margin strata, Carboniferous Ross Sandstone (Ireland): Applications to reservoirs located on the margins of structurally confined submarine fans     

David R. Pyles  D.C. Jennette 《Marine and Petroleum Geology》2009,26(10):1974-1996

Co-genetic debrite–turbidite beds are most commonly found in distal basin-plain settings and basin margins. This study documents the geometry, architectural association and paleogeographic occurrence of co-genetic debrite–turbidite beds in the Carboniferous Ross Sandstone with the goal of reducing uncertainty in the interpretation of subsurface data in similarly shaped basins where oil and gas is produced.The Ross Sandstone of western Ireland was deposited in a structurally confined submarine basin. Two outcrops contain co-genetic debrite–turbidite beds: Ballybunnion and Inishcorker. Both of the exposures contain strata deposited on the margin of the basin. An integrated dataset was used to characterize the stratigraphy of the Ballybunnion exposure. The exposure is divided into lower, middle, and upper units. The lower unit contains laminated shale with phosphate nodules, structureless siltstone, convolute bedding/slumps, locally contorted shale, and siltstone turbidites. The middle unit contains co-genetic debrite–turbidite beds, siltstone turbidites, and structureless siltstone. Each co-genetic debrite–turbidite bed contains evidence that fluid turbulence and matrix strength operated alternately and possibly simultaneously during deposition by a single sediment-gravity-flow event. The upper unit contains thin-bedded sandy turbidites, amalgamated sandy turbidites, siltstone turbidites, structureless siltstone, and laminated shale. A similar vertical facies pattern is found at Inishcorker.Co-genetic debrite–turbidite beds are only found at the basin-margin. We interpret these distinct beds to have originated as sand-rich, fully turbulent flows that eroded muddy strata on the slope as well as interbedded sandstone and mudstone in axial positions of the basin floor forming channels and associated megaflute erosional surfaces. This erosion caused the axially dispersing flows to laterally evolve to silt- and clay-rich flows suspended by both fluid turbulence and matrix strength due to a relative increase in clay proportions and associated turbulence suppression. The flows were efficient enough to bypass the basin center/floor, physically disconnecting their deposits from coeval lobes, resulting in deposition of co-genetic debrite–turbidite beds on the basin margin. The record of these bypassing flows in axial positions of the basin is erosional surfaces draped by thin siltstone beds with organic debris.A detailed cross-section through the Ross Sandstone reveals a wedge of low net-to-gross, poor reservoir-quality strata that physically separates sandy, basin-floor strata from the basin margin. The wedge of strata is referred to as the transition zone. The transition zone is composed of co-genetic debrite–turbidite beds, structureless siltstone, slumps, locally contorted shale, and laminated shale. Using data from the Ross Sandstone, two equations are defined that predict the size and shape of the transition zone. The equations use three variables (thickness of basin-margin strata, thickness of coeval strata on the basin floor, and angle of the basin margin) to solve for width (w) and trajectory of the basinward side of the low net-to-gross wedge (β). Beta is not a time line, but a facies boundary that separates sandy basin floor strata from silty basin-margin strata. The transition zone is interpreted to exist on lateral and distal margins of the structurally confined basin.Seismic examples from Gulf of Mexico minibasins reveal a wedge of low continuity, low amplitude seismic facies adjacent to the basin margin. Strata in this wedge are interpreted as transition-zone sediments, similar to those in the Ross Sandstone. Besides defining the size and shape of the transition zone, the variables “w” and “β” define two important drilling parameters. The variable “w” corresponds to the minimum distance a well bore should be positioned from the lateral basin margin to intersect sandy strata, and “β” corresponds to the deviation (from horizontal) of the well bore to follow the interface between sandy and low net-to-gross strata. Calculations reveal that “w” and “β” are related to the relative amount of draping, condensed strata on the margin and the angle of the basin margin. Basins with shallowly dipping margins and relatively high proportions of draping, clay-rich strata have wider transition zones compared to basins with steeply dipping margins with little draping strata. These concepts can reduce uncertainty when interpreting subsurface data in other structurally confined basins including those in Gulf of Mexico, offshore West Africa, and Brunei.  相似文献   

Long-term bottom water warming in the north Ross Sea     

Hirokazu Ozaki  Hajime Obata  Mikio Naganobu  Toshitaka Gamo 《Journal of Oceanography》2009,65(2):235-244

We measured potential temperature, salinity, and dissolved oxygen profiles from the surface to the bottom at two locations in the north Ross Sea (65.2°S, 174.2°E and 67.2°S, 172.7°W) in December 2004. Comparison of our data with previous results from the same region reveals an increase in potential temperature and decreases in salinity and dissolved oxygen concentration in the bottom layer (deeper than 3000 m) over the past four decades. The changes were significantly different from the analytical precisions. Detailed investigation of the temperature, salinity, dissolved oxygen and σ ₃ value distributions and the bottom water flow in the north Ross Sea suggests a long-term change in water mass mixing balance. That is to say, it is speculated that the influence of cool, saline, high-oxygen bottom water (high-salinity Ross Sea Bottom Water) formed in the southwestern Ross Sea has possibly been decreased, while the influences of relatively warmer and fresher bottom water (low-salinity Ross Sea Bottom Water) and the Adélie Land Bottom Water coming from the Australia-Antarctic Basin have increased. The possible impact of global warming on ocean circulation needs much more investigation.  相似文献   

东海内陆架表层沉积物粒度及其净输运模式   总被引：2，自引：0，他引：2  

刘升发  刘焱光  朱爱美  李朝新  石学法 《海洋地质与第四纪地质》2009,(1)

根据对东海内陆架海底沉积物的粒度测试,运用Gao-Collins"粒度趋势分析"方法,探讨了东海内陆架海底表层沉积物的粒度分布特征和净输运趋势。结果表明,研究区表层沉积物可以分为两类:细颗粒(>5Φ)和粗颗粒(<5Φ);细颗粒分布于研究区的大部分区域,而粗颗粒主要分布在闽江、瓯江等入海河流口门以及马祖等海岛附近;表层沉积物的平均粒径、分选系数、偏态等粒度参数对应性较好,总体特征为粒径越粗,分选越差,偏态更正偏,而粒径越细,分选越好,偏态也较低;粒径趋势分析显示东海陆架表层沉积物的运移模式总体为NE—WS方向运移,而研究区边缘在运移过程中发生向左右两侧的偏移,南部闽江河口区沉积物由近岸向海方向辐射运移,研究区表层沉积物的净输运模式主要受控于流系和地形等多种因素。  相似文献   

Quantitative assessment of dissolved radiotracers in the English Channel: Sources, average impact of la Hague reprocessing plant and conservative behaviour (1983, 1986, 1988, 1994)     

P. Bailly du Bois  P. Guguniat 《Continental Shelf Research》1999,19(15-16)

Knowledge of long-term movements of water-masses in the English Channel has been substantially improved using hydrodynamic modelling coupled with radio-tracers studies; nevertheless, the precision of results so obtained is still largely dependent on measurement precision. New tools are now available to make more accurate determinations of radio-tracer distribution: (1) Repositioning of station locations at the same tide reference-time, giving a homogeneous spatial data set, coupled with the possibility of interpolating and quantifying the amounts of dissolved radioactivity flowing through the English Channel; (2) the first measurements of tritium (³H) in seawater on a large scale in the English Channel demonstrate that this fully conservative radionuclide is a clearly identifiable marker of industrial releases; (3) recent campaigns carried out during the FLUXMANCHE II CCE (1994) programme show the general distribution of dissolved radionuclides ¹³⁷Cs, ¹³⁴Cs, ⁶⁰Co, ¹²⁵Sb, ¹⁰⁶Ru and ³H in the English Channel and the Irish Sea; and (4) the re-utilisation of data from previous campaigns (1983, 1986, 1988) provides indications, at any given location in the English Channel, about the average dilution and distribution of releases derived from the La Hague reprocessing plant. Excesses and losses of radionuclides are now quantified with respect to known source terms; estimates of losses are provided for non-conservative radionuclides, while an excess of ¹³⁷Cs was observed in the English Channel during the period 1983–1994. This excess, which has the same order of magnitude as the quantities released from La Hague plant in the English Channel, could be explained by about 1% of the Sellafield reprocessing plant releases entering the Channel. These results confirm and give a more detailed picture of the previously known distribution of water masses in the English Channel. They lead to clear information about transit times and dilution at this scale, and provide directly comparable data for the validation of hydrodynamic models.  相似文献