Estimate of heavy metals in soil and streams using combined geochemistry and field spectroscopy in Wan-sheng mining area,Chongqing, China     

《International Journal of Applied Earth Observation and Geoinformation》2015

Heavy metals contaminated soils and water will become a major environmental issue in the mining areas. This paper intends to use field hyper-spectra to estimate the heavy metals in the soil and water in Wan-sheng mining area in Chongqing. With analyzing the spectra of soil and water, the spectral features deriving from the spectral of the soils and water can be found to build the models between these features and the contents of Al, Cu and Cr in the soil and water by using the Stepwise Multiple Linear Regression (SMLR). The spectral features of Al are: 480 nm, 500 nm, 565 nm, 610 nm, 680 nm, 750 nm, 1000 nm, 1430 nm, 1755 nm, 1887 nm, 1920 nm, 1950 nm, 2210 nm, 2260 nm; The spectral features of Cu are: 480 nm, 500 nm, 610 nm, 750 nm, 860 nm, 1300 nm, 1430 nm, 1920 nm, 2150 nm, 2260 nm; And the spectral features of Cr are: 480 nm, 500 nm, 610 nm, 715 nm, 750 nm, 860 nm, 1300 nm, 1430 nm, 1755 nm, 1920 nm, 1950 nm. With these features, the best models to estimate the heavy metals in the study area were built according to the maximal R². The R² of the models of estimating Al, Cu and Cr in the soil and water are 0.813, 0.638, 0.604 and 0.742, 0.584, 0.513 respectively. And the gradient maps of these three types of heavy metals’ concentrations can be created by using the Inverse distance weighted (IDW).The gradient maps indicate that the heavy metals in the soil have similar patterns, but in the North-west of the streams in the study area, the contents are of great differences. These results show that it is feasible to predict contaminated heavy metals in the soils and streams due to mining activities by using the rapid and cost-effective field spectroscopy.  相似文献   

红外高光谱资料近地面通道应用     

金大智  李刚  张华  朱文刚 《气象》2013,39(6):675-680

由于下垫面的复杂性,卫星近地面通道的辐射率资料没有得到充分开发和利用。就我国自主研发的GRAPES 3DVar而言,红外高光谱近地面通道资料还没有应用于陆地,即使在下垫面相对简单的海洋,由于背景场海表温度估计不够准确,红外高光谱资料的使用效果也不甚理想。针对GRAPES模式的背景场海表温度估计不够准确这一问题,本文利用大气红外探测仪器AIRS(The Atmospheric Infrared Sounder)辐射率观测资料通过一维变分（1DVar）方法对其晴空视场点内的背景场海表温度进行调整,再运用GRAPES全球分析预报系统进行同化分析,研究了海表温度调整后对分析场的影响。结果表明,利用一维变分调整后的海表温度不仅使得低层通道的模拟亮温与观测亮温更加匹配,而且有效地改进了分析场,对位势高度场高、中、低层均有不错的改进,对低层湿度场以及风场的改进也较为明显。  相似文献   

FR－Ⅰ和FR－Ⅱ型射电源的关系—谱特征     

张有宏  谢光中  刘江 《天文研究与技术》1995,(1)

本文比较了两类射电源ＦＲ－Ⅰ和ＦＲ－Ⅱ型的射电－光学—Ｘ－ｒａｙ的谱特征。ＦＲ－Ⅰ射电源的射电－光学谱比ＦＲ－Ⅱ射电源平得多（△αｒｏ≈０．１９）；但对于光学－Ｘ－ｒａｙ和射电－Ｘ－ｒａｙ谱，ＦＲ－Ⅰ却比ＦＲ－Ⅱ陡得多（△αｏｘ≈０．４０；△αｒｘ≈０．１０）。初步结果表明，ＦＲ－Ⅱ（Ｇ）可能是ＦＲ－Ⅱ（Ｑ）向ＦＲ－Ⅰ过渡的中间状态。  相似文献   

Spectral Characteristics and Correction of Long-Term Eddy-Covariance Measurements Over Two Mixed Hardwood Forests in Non-Flat Terrain   总被引：1，自引：1，他引：0  

Hong-Bing Su  Hans Peter Schmid  C. S. B. Grimmond  Christoph S. Vogel  Andrew J. Oliphant 《Boundary-Layer Meteorology》2004,110(2):213-253

We present turbulence spectra and cospectra derived from long-term eddy-covariancemeasurements (nearly 40,000 hourly data over three to four years) and the transferfunctions of closed-path infrared gas analyzers over two mixed hardwood forests inthe mid-western U.S.A. The measurement heights ranged from 1.3 to 2.1 times themean tree height, and peak vegetation area index (VAI) was 3.5 to 4.7; the topographyat both sites deviates from ideal flat terrain. The analysis follows the approach ofKaimal et al. (Quart. J. Roy. Meteorol. Soc. 98, 563–589, 1972) whose results were based upon 15 hours of measurements atthree heights in the Kansas experiment over flatter and smoother terrain. Both thespectral and cospectral constants and stability functions for normalizing and collapsingspectra and cospectra in the inertial subrange were found to be different from those ofKaimal et al. In unstable conditions, we found that an appropriate stabilityfunction for the non-dimensional dissipation of turbulent kinetic energy is of the form ₍₎ = (1 - b^-)^-1/4 - c^-, where representsthe non-dimensional stability parameter. In stable conditions, a non-linear functionG_xy() = 1 + b_xy^c _xy (c_xy < 1) was found to benecessary to collapse cospectra in the inertial subrange. The empirical cospectralmodels of Kaimal et al. were modified to fit the somewhat more (neutraland unstable) or less (stable) sharply peaked scalar cospectra observed over forestsusing the appropriate cospectral constants and non-linear stability functions. Theempirical coefficients in the stability functions and in the cospectral models varywith measurement height and seasonal changes in VAI. The seasonal differencesare generally larger at the Morgan Monroe State Forest site (greater peak VAI) andcloser to the canopy.The characteristics of transfer functions of the closed-path infrared gas analysersthrough long-tubes for CO₂ and water vapour fluxes were studied empirically. This was done by fitting the ratio between normalized cospectra of CO₂ or watervapour fluxes and those of sensible heat to the transfer function of a first-order sensor.The characteristic time constant for CO₂ is much smaller than that for water vapour. The time constant for water vapour increases greatly with aging tubes. Three methods were used to estimate the flux attenuations and corrections; from June through August, the attenuations of CO₂ fluxes are about 3–4% during the daytime and 6–10% at night on average. For the daytime latent heat flux (Q_E), the attenuations are foundto vary from less than 10% for newer tubes to over 20% for aged tubes. Correctionsto Q_E led to increases in the ratio (Q_H + Q_E)/(Q^* - Q_G) by about 0.05 to0.19 (Q_H is sensible heat flux, Q^* is net radiation and Q_G is soil heat flux),and thus are expected to have an important impact on the assessment of energy balanceclosure.  相似文献   

用卫星高光谱数据提取德兴铜矿区植被污染信息   总被引：24，自引：7，他引：17  

刘圣伟  甘甫平  王润生 《国土资源遥感》2004,15(1):6-10,31

在深入分析研究德兴铜矿矿区植被光谱特征的基础上,利用美国EO-1卫星Hyperion高光谱数据,通过反演表征植物生理状态的光谱特征参数(红边位置和最大吸收深度)变异,提取与污染相关的信息,获取了矿山植被污染生态效应概况,为矿山污染的诊断和监测提供新技术和知识支撑。  相似文献   

A modeling of the structure and favorable H-docking sites and defects for the high-pressure silica polymorph stishovite     

G. V.?GibbsEmail author  D. F.?Cox  N. L.?Ross 《Physics and Chemistry of Minerals》2004,31(4):232-239

Employing first-principles methods, the docking sites for H were determined and H, Al, and vacancy defects were modeled with an infinite periodic array of super unit cells each consisting of 27 contiguous symmetry nonequivalent unit cells of the crystal structure of stishovite. A geometry optimization of the super-cell structure reproduces the observed bulk structure within the experimental error when P1 translational symmetry was assumed and an array of infinite extent was generated. A mapping of the valence electrons for the structure displays mushroom-shaped isosurfaces on the O atom, one on each side of the plane of the OSi₃ triangle in the nonbonded region. An H atom, placed in a cell near the center of the super cell, was found to dock upon geometry optimization at a distance of 1.69 Å from the O atom with the OH vector oriented nearly perpendicular to the plane of the triangle such that the OH vector makes a angle of 91° with respect to [001]. However, an optimization of a super cell with an Al atom replacing Si and an H atom placed nearby in a centrally located cell resulted in an OH distance of 1.02 Å with the OH vector oriented perpendicular to [001] as observed in infrared studies. The geometry-optimized position of the H atom was found to be in close agreement with that (0.44, 0.12, 0.0) determined in an earlier study of the theoretical electron density distribution. The docking of the H atom at this site was found to be 330 kJ mol^–1 more stable than a docking of the atom just off the shared OO edge of the octahedra as determined for rutile. A geometry optimization of a super cell with a missing Si generated a vacant octahedra that is 20% larger than that of the SiO₆ octahedra. The valence electron density distribution displayed by the two-coordinate O atoms that coordinate the vacant octahedral site is very similar to those displayed by the bent SiOSi angles in coesite. The internal distortions induced by the defect were found to diminish rather rapidly with distance, with the structure annealing to that observed in the bulk crystal to within about three coordination spheres.  相似文献   

基于高光谱资料对FY-1C/1D气象卫星进行交叉定标     

漆成莉  胡秀清  张里阳  董超华 《气象学报》2012,70(4):892-901

介绍了利用AQUA卫星高光谱AIRS资料对FY-1C、FY-1D气象卫星热红外通道进行交叉定标的方法及定标结果。首先利用卫星轨道预报软件预报出AQUA与FY-1C以及AQUA与FY-1D卫星交叉点,再对交叉区域卫星资料进行像元投影和像元匹配,像元匹配包括时间、观测角度、环境均匀性等检验。以AIRS探测结果作为辐射基准,利用其观测值和FY-1卫星热红外通道光谱响应函数进行光谱匹配,最终得到FY-1卫星热红外通道的准真值并与FY-1卫星的业务产品进行比较分析。对FY-1C、FY-1D两年多卫星资料进行多次交叉比对,结果表明FY-1C通道4比AIRS观测亮温低1.3K左右,通道5低3.6K左右;而FY-1D通道4比AIRS观测亮温低0.3K左右,通道5低3.6K左右。这个准真值与FY-1观测的计数值进行再定标得到新的定标系数。  相似文献   

利用不同地表比辐射率对ETM＋数据地表温度反演对比研究     

苏建云 《北京测绘》2012,(6):28-33

地表温度作为研究环境生态影响的一个重要指标之一,以Landsat ETM+的热红外波段作为数据源,辅助大气透过率、大气平均气温等参数,利用单窗算法基于混合像元、NDVI、植被和裸露地三种不同地表比辐射率反演泉州市地表温度,对比分析结果表明采用这三种地表比辐射率反演地表温度的方法均是可行的,对于具体采用哪一种地表比辐射率应需要结合实际的研究区域地表地物的实际监测地表温度进行对比后,方可选择合适的地表比辐射率进行地表温度反演,会更具实际意义。反演结果可为城市热岛效应等研究提供支持数据源。  相似文献   

基于光谱分类的太湖水体后向散射研究     

陆超平  吕恒  李云梅 《遥感学报》2012,16(2):417-434

由于时空变化而产生的水体后向散射系数参数化差异一直是影响水质参数遥感定量反演精度的一个重要因素。在对太湖遥感反射率光谱进行分类的基础上,针对影响太湖水体水色的不同主导因子,把太湖水体分为3种类型,分别利用半分析方法和光学闭合原理对后向散射系数进行模拟,在此基础上研究其光学特性及其与水体组分浓度的关系,最后针对3种不同主导类型的水体分别建立了后向散射系数参数化模型。将后向散射特性在不同时间和空间上的差异转化为水体不同主导因子在生物-光学上的差异,从而得到适用于太湖不同湖区及不同季节的后向散射系数参数化模型,为利用分析方法对太湖水质参数进行更为精确的遥感反演提供了基础。  相似文献   

中巴地球资源卫星数据反演地表温度产品设计   总被引：1，自引：0，他引：1  

石玉立 《河南气象》2009,(1):5-8

利用CBERS IRMSS/IRS传感器红外通道数据,基于MODTRAN4和查找表算法,根据地表数字高程和全球/区域一体化数值预报模式,建立相应高度和气象条件下温度反演配套系数,利用CBERS可见/近红外通道和地表比辐射率数据库最终生成地表温度/地表发射率产品。最后介绍了温度产品的验证工作,并对温度反演中存在的参数敏感性和不确定性问题进行了分析。  相似文献