Stabilization of swelling clays by Mg(OH)₂. Changes in clay properties after addition of Mg-hydroxide     

G. S. Xeidakis 《Engineering Geology》1996,44(1-4):107-120

Stabilization of the swelling clay structure is attempted by intercalation of Mg(OH)₂ and the development of a brucite interlayer between the clay layers. The properties of the product obtained by applying the technique, formulated as described in a previous work, are considered here. The materials used were Wyoming bentonite (USA), Fuller's Earth (UK), kaolinite, illite, lignite, and silica gels. The Mg(OH)₂-clay products were examined by the methylene blue dye test, X-ray diffraction analysis (XRD), differential thermal analysis (DTA), and derivative thermogravimetry analysis (DTGA). From the results obtained it is concluded that: the Mg-hydroxide is adsorbed by swelling clays both on their external and internal surface, whereas it is adsorbed on the external surface by non-swelling clays. The internally adsorbed phase of Mg-hydroxide forms an ill-defined interlayer of brucite, retarding swelling, whereas the external phase covers the particles modifying drastically their surface properties, like the adsorption of the MB dye. The material produced after precipitation of Mg-hydroxide on swelling clays (smectites) did not re-expand on wetting or after glycolation. The adsorption of MB dye was also reduced by some 80–90%, due to coating effect, preventing the measurements of the external surface area of the clay by polar molecules. The principal forces involved in the process are believed to be physical adsorption on the external surface, along with chemisorption and some chemical bonding, mostly in the internal surface. Cementation due to crystallization and, in the long term, some pozzolanic reactions take also place. Internal adsorption of the Mg-hydroxide is postulated to be in the form of positively charged mono- and/or small polymers and it is, chiefly, diffusion controlled. Since Mg-hydroxide is internally adsorbed by swelling clays, whereas Ca-hydroxide(lime) is not, and the (Mg, Ca)-clay aggregates are more stable than the Ca-clay or the Mg-one, the combination of the two hydroxides could give better results in soil stabilization than each hydroxide alone.  相似文献   

华北地区煤的显微组分结焦性热台试验   总被引：1，自引：0，他引：1       下载免费PDF全文

康西栋  潘银苗 《地球科学》1997,22(2):181-184

为探讨煤的显微组分的结焦性，对不同变质程度煤的镜质组、壳质组和惰性组分别进行了显微镜热台加热试验．在加热过程中，活性组分经历了３个明显不同的变化阶段，即变形阶段、胶质体形成阶段以及固化阶段．随煤变质程度的增加，镜质组的初变温度和胶质体形成时的温度逐渐增大，而固结温度变化规律不明显；壳质组在低变质阶段因受热而挥发掉，但随煤级增高其变形程度减弱；半镜质组在受热过程中也有变形和少量胶质体形成，而惰性组只发生微弱变化．在低变质阶段，活性显微组分形成的焦炭显微结构以各向同性为主；随变质程度的增高，焦炭显微结构中各向异性成分比例增大  相似文献   

煤层倾角与覆岩变形破裂分带   总被引：7，自引：0，他引：7  

杜时贵  翁欣海 《工程地质学报》1997,5(3):211-217

地下采煤中三带(冒落带、裂隙带、弯曲带)高度的判断是预测采空引起地表变形破坏程度的依据。在诸多的影响因素中, 煤层倾角是控制三带高度的最主要因素。建立在实测统计基础上的经验范围值用于三带高度的判断带有一定的人为性。急倾斜煤层中冒落带和裂隙带高度随煤层倾角变化的规律已被褐示[7].通过弹塑性岩石材料的非线性有限元模拟, 本文提出了利用应力重分布图判断中、缓倾角煤层采空区覆岩三带高度的方法, 并应用于实际工程。  相似文献   

旋喷固结体的物理力学性状研究     

周勇  徐进 《地质灾害与环境保护》1997,(3)

通过单轴抗压试验、剪切试验、变形试验及渗透性试验等方法，对旋喷固结体的物理力学性状和渗透性进行了研究。结果表明：旋喷固结体具有良好的物理力学性质和较低的渗透性，可完全改变天然土的性质。  相似文献   

塔里木盆地油气资源的基本特征   总被引：3，自引：0，他引：3  

陈正辅 《海相油气地质》1997,2(1):15-20

塔里木盆地成油气地质历史条件复杂，盆地内海陆相油气、不同成藏期油气、不同成熟度以及不同保存条件的油气并存。具海相古生界及陆相中－新生界两大烃源岩系，前者以奥陶系和石炭系为最好源岩，后者以三叠系和侏罗系最佳。烃源对比结果比较全面地反映了这一特点。石炭系、三叠系、白垩系和中新统均为重要的储油层系，其储集岩类古生界主要为白云岩，次为石灰岩，中－新生界主要为砂岩。成藏类型可分为六种：古生古储、后生古储、后  相似文献   

Comparison of Aircraft and Ground-Based FluxMeasurements during OASIS95     

P. R. Isaac  J. Mcaneney  R. Leuning  J. M. Hacker 《Boundary-Layer Meteorology》2004,110(1):39-67

Aircraft and ground-based measurements made during the1995 Australian OASIS field campaign are compared. The aircraft data were recorded during low-level flightsat 6 m above ground level and grid flights at altitudes of between 15 and 65 m, allin unstable atmospheric conditions. The low-level flights revealed an inadequate temperaturesensor response time, a correction for which was determined from subsequent work ina wind tunnel. Aircraft and ground-based measurements of mean wind speed, wind directionand air temperature agree to within 0.2 m s^-1, 4° and 0.9 °C respectively.Comparisons between aircraft and ground-based observations of the standarddeviations of vertical velocity, horizontal wind speed, air temperature and specifichumidity have slopes of 0.96, 0.97, 0.92 and 0.99 respectively but the observed scatter isroughly twice the random error expected due to the averaging length of the aircraft data andthe averaging period of the ground-based data. For the low-level flights, the ground-basedand aircraft measurements of sensible and latent heat flux show mean differences of 27 and-25 W m^-2 respectively, which reduce to 11 and -4 W m^-2 respectivelywhen analysis of aircraft data is limited to areas immediately adjacent to the fluxtowers. For the flights at 15 to 65 m above ground level, the mean differences between theground-based and aircraft measurements of sensible and latent heat flux are -22 and-1 W m^-2 respectively and these change to -1 and -7 W m^-2 respectively oncethe effect of surface heterogeneity is included. Aircraft and ground-based measurementsof net radiation agree to within 6% at one ground-based site but differ by 20% at a second.Aircraft measurements of friction velocity at 6 m above the ground agree well withground-based data, but those from flights between 15 and 65 m above ground level do not.This is because at these heights the aircraft measurements provide the local shear stress,not the surface shear stress. Overall, the level of agreement allows confidence in the aircraftdata provided due care is taken of instrument response times and differences in thesurfaces sampled by aircraft and ground-based systems.  相似文献   

Radiative Exchange in an Urban Street Canyon   总被引：1，自引：4，他引：1  

Ian N. Harman  Martin J. Best  Stephen E. Belcher 《Boundary-Layer Meteorology》2004,110(2):301-316

The influence of building geometry on the radiation terms ofthe surface energy balance is a principal reason for surfacetemperature differences between rural and urban areas.Methods exist to calculate the radiation balance in an urban area,but their validity across the range of urban geometries andmaterials has not been carefully considered.Here the exchange of diffuse radiation in an urban street canyon isinvestigated using a method incorporating all reflections of radiation.This exact solution is compared to two commonly used approximationsthat retain either no reflections, or just one reflection of radiation.The area-averaged net radiative flux density from the facets of the canyondecreases in magnitude monotonically as the canyon aspect ratio increases.The two approximate solutions possess unphysical differences from thismonotonic decrease for high canyon aspect ratios or low materialemissivities/high material albedos.The errors of the two approximate solutions are small for near blackbodymaterials and small canyon aspect ratios but can be an order ofmagnitude for intermediate material properties and deep street canyons.Urban street canyon models need to consider at least one reflectionof radiation and multiple reflections are desirable for full applicability.  相似文献   

Estimation of Regional Evapotranspiration by Combining Aircraftand Ground-Based Measurements     

P. R. Isaac  R. Leuning  J. M. Hacker  H. A. Cleugh  P. A. Coppin  O. T. Denmead  M. R. Raupach 《Boundary-Layer Meteorology》2004,110(1):69-98

Two methods are examined for combining measurements from instrumented aircraftand towers to estimate regional scale evapotranspiration. Aircraft data provided spatially averaged values of properties of the surface, the evaporative fraction and maximum stomatal conductance. These quantities are less sensitive to meteorological conditions than the turbulent fluxes of heat and water vapour themselves. The methods allowed aircraft data collected over several days to be averaged and thus to reduce the random error associated with the temporal under-sampling inherent in aircraft measurements. Evaporative fraction is estimated directly from the aircraft data, while maximum stomatal conductance is estimated by coupling the Penman–Monteith equation to a simple model relating surface conductance to the incoming shortwave radiation and specific humidity saturation deficit. The spatial averages of evaporative fraction and maximum stomatal conductance can then be used with routine tower data to estimate the regional scale evapotranspiration. Data from aircraft flights and six ground based sites during the OASIS field campaign in south–east New South Wales in 1995 have been used to check the methods. Both the evaporative fraction and the maximum stomatal conductance derived from the aircraft data give information on the spatial variability of the surface energy budget at scales from 10 to 100 km. Daily averaged latent heat fluxes estimated using these methods for the OASIS study region agree with the available observations in quasi-stationary conditions or in weakly non-stationary conditions when the data from several aircraft flights are averaged to reduce the impact of short term imbalances in the surface energy budget.  相似文献   

程海断裂带断层泥中石英碎砾表面SEM特征及断层活动状态的分析   总被引：4，自引：0，他引：4  

俞维贤  王彬  毛燕  杨继武 《中国地震》2004,20(4):347-352

根据断层泥中石英碎砾表面SEM特征的鉴定研究，可将程海断裂中、北段断层泥中石英碎砾表面SEM形貌特征分为6类，这表明该段断裂经历了长期多期次活动，强烈活动时间在中晚更新世；5件样品中均未见破裂类(Io)的石英颗粒，表明程海断裂全新世以来强烈活动的频度相对较低。石英碎砾表面机械作用特征的分类统计研究显示：程海断裂中、北段晚更新世以来，断层所经历的活动方式以粘滑活动为主。  相似文献   

Parameters of Land-Surface Processes for Gobi in North-West China   总被引：1，自引：0，他引：1  

Zhang Qiang  Huang Ronghui 《Boundary-Layer Meteorology》2004,110(3):471-478

Using data from the intensive observation period (May–June 2000) of the NWC-ALIEX (The Field Experiment on Interaction between Land and Atmosphere in Arid Region of North-west China), the characteristics and mechanisms of some key land-surface process over Gobi in a typical arid region of north-west China are analyzed and several parameters of land-surface processes are calculated. The weighted mean of the surface albedo over a typical arid region of the Dunhuang Gobi is calculated using the relative reflection as a weighting factor, and its value is 0.255 ± 0.021. After removing the influence of precipitation, the mean soil heat capacity over a typical arid region of the Dunhuang Gobi is 1.12 × 10⁶ J m^-3 K^-1,which is smaller than that observed in the Heihe (China) River basin Field Experiment (HEIFE). The mean soil heat diffusivity and conductivity are about half of those observed in HEIFE.  相似文献