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We present results from a new simulation code that accounts for the evolution of the reservoirs of carbon dioxide on Mars, from its early years to the present. We establish a baseline model parameter set that produces results compatible with the present (i.e., Patm?6.5 mbar with permanent CO2 ice cap) for a wide range of initial inventories. We find that the initial inventory of CO2 broadly determines the evolutionary course of the reservoirs of CO2. The reservoirs include the atmosphere, ice cap, adsorbed CO2 in the regolith, and carbonate rocks. We track the evolution of the free inventory: the atmosphere, ice cap and regolith. Simulations begin at 4.53 Gyr before present with a rapid loss of free inventory to space in the early Noachian. Models that assume a relatively small initial inventory (?5 bar) have pronounced minima in the free inventory of CO2 toward the end of the Noachian. Under baseline parameters, initial inventories below ∼4.5 bar result in a catastrophic loss of the free inventory to space. The current free inventory would be then determined by the balance between outgassing, sputtering losses and chemical weathering following the end of the late bombardment. We call these “thin” models. They generically predict small current free inventories in line with expectations of a small present CO2 ice cap. For “thick” models, with initial inventories ?5 bar, a surplus of 300-700 mbar of free CO2 remains during the late-Noachian. The histories of free inventory in time for thick models tend to converge within the last 3.5 Gyr toward a present with an ice cap plus atmospheric inventory of about 100 mbar. For thick models, the convergence is largely due to the effects of chemical weathering, which draws down higher free inventories more rapidly than the low. Thus, thick models have ?450 mbar carbonate reservoirs, while thin models have ?200 mbar. Though both thick and thin scenarios can reproduce the current atmospheric pressure, the thick models imply a relatively large current CO2 ice cap and thin models, little or none. While the sublimation of a massive cap at a high obliquity would create a climate swing of greenhouse warming for thick models, under the thin model, mean temperatures and pressures would be essentially unaffected by increases in obliquity.  相似文献   
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In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K2O, Ca/(Ca + Na)rock and FeOtot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H2O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.  相似文献   
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Man Hoi Lee  S.J. Peale 《Icarus》2006,184(2):573-583
Two small satellites of Pluto, S/2005 P1 (hereafter P1) and S/2005 P2 (hereafter P2), have recently been discovered outside the orbit of Charon, and their orbits are nearly circular and nearly coplanar with that of Charon. Because the mass ratio of Charon-Pluto is ∼0.1, the orbits of P2 and P1 are significantly non-Keplerian even if P2 and P1 have negligible masses. We present an analytic theory, with P2 and P1 treated as test particles, which shows that the motion can be represented by the superposition of the circular motion of a guiding center, the forced oscillations due to the non-axisymmetric components of the potential rotating at the mean motion of Pluto-Charon, the epicyclic motion, and the vertical motion. The analytic theory shows that the azimuthal periods of P2 and P1 are shorter than the Keplerian orbital periods, and this deviation from Kepler's third law is already detected in the unperturbed Keplerian fit of Buie and coworkers. In this analytic theory, the periapse and ascending node of each of the small satellites precess at nearly equal rates in opposite directions. From direct numerical orbit integrations, we show the increasing influence of the proximity of P2 and P1 to the 3:2 mean-motion commensurability on their orbital motion as their masses increase within the ranges allowed by the albedo uncertainties. If the geometric albedos of P2 and P1 are high and of order of that of Charon, the masses of P2 and P1 are sufficiently low that their orbits are well described by the analytic theory. The variation in the orbital radius of P2 due to the forced oscillations is comparable in magnitude to that due to the best-fit Keplerian eccentricity, and there is at present no evidence that P2 has any significant epicyclic eccentricity. However, the orbit of P1 has a significant epicyclic eccentricity, and the prograde precession of its longitude of periapse with a period of 5300 days should be easily detectable. If the albedos of P2 and P1 are as low as that of comets, the large inferred masses induce significant short-term variations in the epicyclic eccentricities and/or periapse longitudes on the 400-500-day timescales due to the proximity to the 3:2 commensurability. In fact, for the maximum inferred masses, P2 and P1 may be in the 3:2 mean-motion resonance, with the resonance variable involving the periapse longitude of P1 librating. Observations that sample the orbits of P2 and P1 well on the 400-500-day timescales should provide strong constraints on the masses of P2 and P1 in the near future.  相似文献   
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Measurements of 18O concentrations in precipitation, soil solution, spring and runoff are used to determine water transit time in the small granitic Strengbach catchment (0·8 km2; 883–1146 m above sea level) located in the Vosges Mountains of northeastern France. Water transit times were calculated by applying the exponential, exponential piston and dispersion models of the FlowPC program to isotopic input (rainfall) and output (spring and stream water) data sets during the period 1989–95. The input function of the model was modified compared with the former version of the model and estimated by a deterministic approach based on a simplified hydrological balance. The fit between observed and calculated output data showed marked improvements compared with results obtained using the initial version of the model. An exponential piston version of the model applied to spring water indicates a 38·5 month mean transit time, which suggests that the volume in the aquifer, expressed in water depth, is 2·4 m. A considerable thickness (>45 m) of fractured bedrock may be involved for such a volume of water to be stored in the aquifer. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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