硫化物矿物溶解度与溶液pH值的关系   总被引：2，自引：0，他引：2  

贾建业  兰斌明  谢先德  吴大清  汤艳杰  王燕  王建成 《吉林大学学报(地球科学版)》2001,31(3):241-246

硫化物作为自然界常见的一大类矿物 ,由于溶解度很小 ,硫化物对水pH值的影响以及水对它的溶解度影响往往被人们所忽视。通过计算常见硫化物矿物的自由能ΔG0f、溶度积Ksp和溶解度S、绘制logS—pH曲线 ,得出硫化物矿物在不同 pH值条件下的溶解规律 ,水溶液的pH值受硫化物矿物的控制 ;反过来 ,水溶液的pH值也影响着矿物溶解度的大小。此外 ,对硫化物矿物饱和溶液的缓冲范围、缓冲容量和硫化物与溶液pH值相互作用的机理进行了探讨  相似文献   

非饱和土壤水力参数预测的分形模型   总被引：12，自引：3，他引：12       下载免费PDF全文

刘建国  聂永丰 《水科学进展》2001,12(1):99-106

综述了利用分形几何理论,可在土壤水力性质,包括土壤水分特征曲线及水力传导系数与土壤结构分维之间建立起一定的函数关系式.这些函数关系式大多与Campbell定律具有相同或相似的幂定律形式,一方面揭示了Campbell定律的物理实质,另一方面可用于土壤持水量及水力传导系数的预测.  相似文献   

下庄铀成矿古水热系统排泄区（减压区）铀成矿作用研究     

刘金辉  李学礼 《矿床地质》2001,20(3):259-264

形成于古水热系统排泄区（减压区）的下庄花岗岩型铀矿床是地下热水与岩石相互作用的产物。矿物流体包裹体水文地球化学分析表明，成矿期铀成矿古热水溶液气体成分主要为CO2，水化学类型为HCO3－Ca.Na型，F－Ca型和HCO3.F－K型。地球化学模式和热力学计算证明，热水溶液中铀的存在形式为UO2（CO3）2^2-,UO2F3^-和UO2F4^2-。热水溶液深循环过程中CO2的加入可使溶液铀沉淀临界电位值（EhC,U)明显降低，从而保持水－铀比电位值（ΔEhW,U)为正值（ΔEhW,U=EhW-EhC,U)使铀在深部相对还原的条件下仍能稳定迁移。当富铀成矿热液进入减压排泄区时，由于溶液物理－化学条件的改变，发生CO2脱气作用和中和还原作用，导致ΔEhW,U小于零，使铀沉淀、富集，最终形成花岗岩型铀矿床。  相似文献   

酸性土壤中20种元素有效态浸提体系浅析   总被引：8，自引：4，他引：8  

李锡坤  李鉴伦  洪翊  冯超  何平 《岩矿测试》2001,20(3):167-173

通过对酸性土壤中Cu、Pb、Zn、Co、Ni、Fe、Mn、Cd、K、Na、Ca、Mg、Si、P、S、Mo、F、Se、As、Hg20种元素有效态的浸提与测定，拟定了一个操作条件宽松、质量稳定，能满足区域调查需要的浸提体系和分析方案。该分析配套方案对20种元素的检出限在（0.0001～4.9）×10  相似文献   

长沙—澧陵—浏阳—带冷家溪群及板溪群的甚低级变质作用   总被引：13，自引：5，他引：13  

朱明新  王河锦 《岩石学报》2001,17(2):291-300

湘东长沙-澧陵-浏阳一带中晚元古宇的冷家溪群及板溪群遭受了区域甚低级变质作用.在本地区所采的＜2μm的样品中,冷家溪群伊利石结晶度的Kübler指数为0.18～0.26°△2θ,板溪群为0.21～0.28°△2θ(Kisch国际标样校正).从而可把本地区冷家溪群的区域变质划归浅变质带和近变质带上部,温度大约为280～400℃.板溪群划归近变质带上部,温度大约为250～300℃.并未普遍达到目前人们认为的绿片岩相或者是低绿片岩相.样品中冷家溪群伊利石(白云母)b0值的范围在0.8999～0.9042 nm,板溪群为0.9018～0.9042nm.由冷家溪群b0频率累积曲线图,得出本区冷家溪群处于较典型的中压区.  相似文献   

Delineation of sulphide ore-zones by borehole radar tomography at Hellyer Mine, Australia     

Binzhong Zhou  Peter K. Fullagar   《Journal of Applied Geophysics》2001,47(3-4)

Velocity and absorption tomograms are the two most common forms of presentation of radar tomographic data. However, mining personnel, geophysicists included, are often unfamiliar with radar velocity and absorption. In this paper, general formulae are introduced, relating velocity and attenuation coefficient to conductivity and dielectric constant. The formulae are valid for lossy media as well as high-resistivity materials. The transformation of velocity and absorption to conductivity and dielectric constant is illustrated via application of the formulae to radar tomograms from the Hellyer zinc–lead–silver mine, Tasmania, Australia. The resulting conductivity and dielectric constant tomograms constructed at Hellyer demonstrated the potential of radar tomography to delineate sulphide ore zones.  相似文献   

Variations in chemical compositions of the eolian dust in Chinese Loess Plateau over the past 2.5 Ma and chemical weathering in the Asian inland   总被引：5，自引：0，他引：5  

CHEN Jun  LIU Lianwen  JI Junfeng  YANG Jiedong  CHEN Yang 《中国科学D辑(英文版)》2001,44(5):403-413

Major and trace elements as well as strontium isotopic composition have been analyzed on the acid-insoluble (AI) phase of the loess-paleosol sequence from Luochuan, Shaanxi Province, China. Results show that the chemical composition of AI phase of loess and paleosols is distinctive to the average composition of upper continental crust (UCC), characterized by depletion of mobile elements Na, Ca and Sr. The distribution pattern of elements in AI phase reveals that initial dust, derived from a vast area of Asian inland, has suffered from Na- and Ca-removed chemical weathering compared to UCC. Some geochemical parameters (such as CIA values, Na/K, Rb/Sr and⁸⁷Sr/⁸⁶Sr ratios) display a regular variation and evolution, reflecting that the chemical weathering in the source region of loess deposits has decreased gradually since 2.5 Ma with the general increase of global ice volume. This coincidence reflects that the aridity of Asian inland since the Quaternary is a possible regional response to the global climate change.  相似文献   

Seismic interaction in linearly connected electrical substation equipment     

A. Der Kiureghian  J. L. Sackman  K‐J. Hong 《地震工程与结构动力学》2001,30(3):327-347

An electrical substation consists of a complex set of equipment items that are interconnected through conductor buses or cables. If the connections are not sufficiently flexible, significant dynamic interaction may occur between the connected equipment items during a seismic excitation. This interaction is believed to be responsible for some of the observed substation equipment damage in recent earthquakes. This paper investigates the interaction between two equipment items connected by a linear spring‐dashpot or spring‐dashpot‐mass element representing a conductor bus. It is found that the interaction between the two equipment items may significantly amplify the response of the higher‐frequency equipment item. The influences of various key parameters on the interaction effect are quantified. Means for reducing the adverse interaction effect are described. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Dynamical problem of micropolar viscoelasticity     

Rajneesh Kumar  Suman Choudhary 《Journal of Earth System Science》2001,110(3):215-223

The dynamic problem in micropolar viscoelastic medium has been investigated by employing eigen value approach after applying Laplace and Fourier transformations. An example of infinite space with concentrated force at the origin has been presented to illustrate the application of the approach. The integral transforms have been inverted by using a numerical technique to obtain the displacement components, force stresses, couple stress and microrotation in the physical domain. The results for these quantities are given and illustrated graphically.  相似文献   

Yearly changes in the seasonal frequency and duration of short-term acid pulses in some Nova Scotia, Canada streams   总被引：1，自引：0，他引：1  

T. A. Clair  A. Ghosh Bobba  Krista Miller 《Environmental Geology》2001,40(4-5):582-591

 The seasonal frequency and duration of low pH events at three sites located in southwestern Nova Scotia were analyzed using measured and synthetic daily pH data. The basins varied in size from 0.3 to 300 km² and were subject to frequent snowmelt events in winter and spring, as well as occasional runoff events during summer and fall. Results showed that, in order to fill in missing data from periods where collection was interrupted, statistical approximations using discharge were not totally acceptable, as generated data consistently missed the extreme values measured. Despite a lack of totally accurate event pH estimates for periods where daily data were missing, analysis showed that in this region, low pH episodes can occur year-round including summer. The highest probabilities of low pH episodes nevertheless occurred in the winter and spring when snowmelts were frequent. Received: 12 November 1999 · Accepted: 18 July 2000  相似文献