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101.
This paper presents a quantitative reconstruction of the European late Pleistocene paleoclimate based on 72 rodent assemblages of five sequences from France, Germany and Bulgaria, covering the last interglacial-glacial cycle. They show a pattern of severe changes in temperature, with reduced precipitation during the coldest periods. A tentative correlation between the isotopic and palynological records and the paleotemperature changes is shown. These changes are consistent with variations in atmospheric circulation patterns in response to an expanding-retracting Fennoscandian ice-sheet. They can be attributed to the enhancement-weakening of the Scandinavian-Polar anticyclone and its associated dry winds, the south-north shifting of the North Atlantic Polar Front, and the varying supply of moist air from the Atlantic. Qualitative paleoenvironmental analysis shows broadleaved-deciduous forests in France and Bulgaria during most of the studied period. Taiga and tundra appeared in eastern France during the lower Würm. The German sequence indicates the presence of coniferous forests. These results are broadly consistent with other paleobiological records (mammalian, avian and insect faunas, isotopic record in dental tissue, palynology). The main discrepancies with the paleoclimate inferred from the palynological record are found during the coldest periods and are probably due to the interaction between vegetation, climate, and atmospheric CO2 levels.  相似文献   
102.
In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献   
103.
This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.  相似文献   
104.
This review of the literature from 2004 and 2005 concerning secondary ion mass spectrometry (SIMS) highlights the contribution the technique has made in the fields of petrology, geochronology, cosmochemistry and material sciences. In petrology, much research was devoted to the measurement of stable isotopes and trace elements by developments in multicollection acquisition, with emphasis on low atomic mass number elements. Elements studied in particular were S (in sulfides), O (in garnets), C (in sedimentary organic matter), Cl (in glasses) and Si. Novel applications of SIMS to geochronology have included the measurement of young zircon grains by the U-Pb and U-Th decay methods. An increasing number of studies have combined U-Pb geochronology with the measurement of trace elements or stable isotopes in zircon.  相似文献   
105.
林草复合经营模式养分动态关系   总被引:2,自引:0,他引:2  
林草复合经营模式在目前的退耕还林工程中起着重要的作用,研究林草复合模式的林与草之间的营养元素关系,通过对不同林草养分的研究得出林木、草、土壤之间的养分动态关系,对矿质养分相互关系的研究为合理搭配林草提供重要依据,为退化山地生态系统的恢复和重建提供重要的模式。模式Ⅰ在退耕还林初期,土壤养分供给氮素虽未亏缺,但从三者问的消长关系看出:氮磷素供应并不富足,特别是水解性氮。土壤交换性钙供应不足,引起杉木与黑麦草对钙质竞争。而土壤全钙含量很高,钙质向交换性钙转化的速度缓慢。模式Ⅱ与模式Ⅰ得到相似结果,所以在这两种模式中应加强人为管理,在退耕初期应适当增施氮磷钙肥,辅以土壤结构改良,加速土壤养分向植物可利用态转化。模式Ⅲ牛鞭草的生物量极高,磷、钙索相对缺乏。由于牛鞭草被不断的采割用于牲畜的饲料,对该模式中必须进行一定养分的输入,以保持杂交竹与牛鞭草这一林草生态系统的养分平衡。  相似文献   
106.
长白山锦北雨养泥炭剖面元素富集规律分析   总被引:3,自引:2,他引:3  
贾琳  王国平  刘景双 《湿地科学》2006,4(3):187-192
为了揭示长白山锦北泥炭沼泽区泥炭沉积环境和重金属元素的历史变化及其对环境的指示意义,利用荷兰W ardenaar泥炭采样器采取泥炭样品并对样品进行高分辨率切割。用原子吸收分光光度计和等离子体发射光谱仪测定不同深度剖面Ca,Mg,Na,K,A l,Ti,Cu,Zn,Fe,Mn,Pb,Cr,N i和Co的浓度。研究分析了Ca,Mg,Na,K,A l,Ti,Mn,Zn,Cu,Pb,Cr,N i和Co在泥炭剖面的分布趋势并对其进行了相关分析和富集分析,得出Mn,Zn,Cu,Pb,Cr,N i和Co呈显著相关且在泥炭表层明显累积,揭示出泥炭表层重金属元素的大气沉降来源,表明近年来人类重金属消耗量及排放量的增加是大气沉降重金属元素的主要释放源,而且环境中重金属污染有加重的趋势。  相似文献   
107.
Geochemical analyses and geobarometric determinations have been combined to create a depth vs. radiogenic heat production database for the Sierra Nevada batholith, California. This database shows that mean heat production values first increase, then decrease, with increasing depth. Heat production is 2 μW/m3 within the 3-km-thick volcanic pile at the top of the batholith, below which it increases to an average value of 3.5 μW/m3 at 5.5 km depth, then decreases to 0.5–1 μW/m3 at 15 km depth and remains at these values through the entire crust below 15 km. Below the crust, from depths of 40–125 km, the batholith's root and mantle wedge that coevolved beneath the batholith appears to have an average radiogenic heat production rate of 0.14 μW/m3. This is higher than the rates from most published xenolith studies, but reasonable given the presence of crustal components in the arc root assemblages. The pattern of radiogenic heat production interpreted from the depth vs. heat production database is not consistent with the downward-decreasing exponential distribution predicted from modeling of surface heat flow data. The interpreted distribution predicts a reasonable range of geothermal gradients and shows that essentially all of the present day surface heat flow from the Sierra Nevada could be generated within the 35 km thick crust. This requires a very low heat flux from the mantle, which is consistent with a model of cessation of Sierran magmatism during Laramide flat-slab subduction, followed by conductive cooling of the upper mantle for 70 m.y. The heat production variation with depth is principally due to large variations in uranium and thorium concentration; potassium is less variable in concentration within the Sierran crust, and produces relatively little of the heat in high heat production rocks. Because silica content is relatively constant through the upper 30 km of the Sierran batholith, while U, Th, and K concentrations are highly variable, radiogenic heat production does not vary directly with silica content.  相似文献   
108.
Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages.  相似文献   
109.
大气CO2浓度升高对土壤中不同粒级碳的影响   总被引:4,自引:0,他引:4  
不同粒级土壤中的碳有着不同的周转规律,在高CO2浓度条件下,它们含量的变化将在一定程度上反映土壤碳是累积还是减少,对明确土壤碳的变化趋势有重要意义.采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布.结果表明,加入秸秆培养1年,由于CO2浓度升高的原因导致在低氮(LN)、常规氮(NN)和高氮(HN)水平下土壤中碳分别增加0.01、1.10、1.22g/kg,表现为粒级〈53μm土壤颗粒中碳分别增加1.53、2.19、2.70g/kg.粒级〈53μmm土壤颗粒碳量的增加,主要是由于其重量分配百分数显著增加36.2%,碳浓度增加5.4%;粒级〉250μm和250~53μm土壤颗粒部分虽然其碳浓度分别增加20.8%和17.3%(P〈0.05),怛由于重量分配百分数分别显著降低22.8%和36.1%,结果碳量降低.试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化;高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势.  相似文献   
110.
Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS 14C and 210Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO4 addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the 210Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.  相似文献   
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