Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate     

Gerhard Kramm  Ralph Dlugi 《Journal of Atmospheric Chemistry》1994,18(4):319-357

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.  相似文献   

苯和甲苯在盐水溶液中活度系数及其盐效应的研究          下载免费PDF全文

王卫东  张建银 《盐湖研究》2006,14(2):52-55

采用紫外分光光度法测定了24.0℃时苯和甲苯在CH3COONa,(NH4)2SO4,MgSO4,Na2SO4和Na2CO3水溶液中的活度系数(f),它们的lgf-Cs关系符合Setschenow盐效应公式,计算了苯和甲苯在上述5种盐水溶液中的盐析系数。  相似文献   

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China     

Aierken Sidike  X.-M. Wang  Alifu Sawuti  H.-J. Zhu  I. Kusachi  N. Yamashita 《Physics and Chemistry of Minerals》2006,33(8-9):559-566

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.  相似文献   

VTI介质多波速度与各向异性系数求取及应用   总被引：1，自引：0，他引：1  

罗省贤  李录明  陈春继 《物探化探计算技术》2005,27(3):214-218

针对具有垂直对称轴的横向各向同性(VTI)介质,研究了多波速度与地层各向异性系数之间的关系。采用适应大偏移距以及强各向异性介质的双平方根方程,进行速度和各向异性系数分析,并将批量计算与交互解释相结合,实现了高精度各向异性介质多波速度与各向异性系数提取,并形成了一套利用多波地震资料求取地震波纵、横波速度及各向异性系数的方法和软件。所求取的参数可用于多波地震资料处理,提高多波资料的成像质量,也可为地层地质解释提供参考。实际资料的应用效果证明了该方法和软件的正确性及有效性。  相似文献   

引黄水在北大港水库蓄存期水质咸化的研究   总被引：10，自引：0，他引：10       下载免费PDF全文

赵文玉  王启山  吴国平  吴立波  孙增峰  郑力燕 《水科学进展》2005,16(6):763-766

依据引黄水在北大港水库蓄存期水质咸化的事实以及传质理论,定性地分析了引黄水水质咸化的主要原因,包括盐碱土传质作用、蒸发浓缩作用以及风的扰动加速传质作用等.在北大港水库旁修建了一个模拟试验水池,进行了现场模拟试验研究.依据水量平衡和氯离子总量平衡的原理,分别定量地计算了传质作用和蒸发浓缩作用对水质咸化影响的比重.结果表明,在模拟水池蓄水后的30 d内,传质作用对水质咸化影响的比重有随时间增加而增长的趋势;30 d后,传质作用对水质咸化影响的比重稳定在80%,蒸发浓缩作用对水质咸化影响的比重稳定在20%,说明导致水质咸化的最主要因素是盐碱土传质作用.  相似文献   

不同辐射传输方案对中尺度降水影响的对比分析   总被引：5，自引：3，他引：5       下载免费PDF全文

周广强赵春生  丁守国秦瑜 《应用气象学报》2005,16(2):148-158

在MM5非静力稳定中尺度气象模式中引进了建立在δ-4流近似和相关-k分布基础上的对云水、雨水、冰晶和霰的辐射特性进行详细描述的辐射传输方案。新建立的辐射传输方案和MM5中原有的辐射传输方案在华南暴雨中的模拟结果相互比较，并与天气实况的对比表明:辐射在中尺度暴雨中起着重要的作用；辐射传输方案对云辐射特性描述的准确程度对于地面降水影响是明显的；不同的辐射传输方案对地面降水的影响存在较大的差异，并且这些差异在白天比在夜间明显；辐射传输过程对地面降水影响的差异主要表现在降水中心上，而对降水的地理分布改变很小；相对而言，不同的辐射传输方案之间对短波描述的差异对地面降水的影响明显，而对长波描述差异的影响不大；新辐射传输方案能够在一定程度上改进MM5对中尺度降水的模拟能力。  相似文献   

紫外线模式预报方法的研究和试验   总被引：8，自引：2，他引：8  

沈元芳  况石 《应用气象学报》2002,13(Z1):223-231

文章介绍了在T106全球谱模式中应用大气辐射传输模式预报紫外线辐射(UVR)的方法,给出了试验运行的结果.UVR强度的划分考虑了到达地表的UVR通量.参考国内、外紫外线(UV)预报服务的经验,制定了5个日光暴露的级别、相应的紫外线指数(UVI)及防护措施.1999年9月起,国家气象中心已在NOTES网上每月不定期地展示UVR预报的一些结果,2000年9月起,在Cray-C92业务操作系统上实施了连续的试验运行.  相似文献   

Probability Density Functions as Botanical-Climatological Transfer Functions for Climate Reconstruction     

Norbert Kühl  Christoph Gebhardt  Thomas Litt  Andreas Hense 《Quaternary Research》2002,58(3):381

We present a new procedure, the pdf method (pdf=probability density function), for reconstructing Quaternary climate utilizing botanical data. The procedure includes the advantages of the indicator species method by considering the fossil and modern presence and absence of taxa rather than their frequencies, thus avoiding the need for modern analog plant communities. Overcoming the problematic use of absolute limits to describe climate response ranges is the main progress of the pdf method in comparison to the indicator species method. This advantage results from estimating probability density functions (pdfs) for monthly mean January and July temperature conditional on the present day occurrence of single taxa. Gaussian distributions sufficiently approximate pdfs of many, although not all, studied taxa. On the assumption of statistical independence, the procedure calculates a joint pdf as the product of the pdfs of the individual taxa. This algorithm weights each taxon according to the extent of its climate response range expressed by its covariance structure. We interpret the maximum of the resulting pdf as the most likely climate and its confidence interval as the uncertainty range. To avoid an artificial reduction of uncertainty arising from the use of numerous similar pdfs, a preselection method is proposed based on the Mahalanobis distance between pdfs. The pdf method was applied to the Carpinus phase of a profile from Gröbern, Germany, that spans the last interglaciation (Eemian). The reconstructed most probable January and July temperatures of about 0.0°C and 18.4°C barely differ from the modern values of −0.5°C and 18.3°C.  相似文献   

Determining Q of near-surface materials from Rayleigh waves     

Jianghai Xia  Richard D. Miller  Choon B. Park  Gang Tian 《Journal of Applied Geophysics》2002,51(2-4)

High-frequency (≥2 Hz) Rayleigh wave phase velocities can be inverted to shear (S)-wave velocities for a layered earth model up to 30 m below the ground surface in many settings. Given S-wave velocity (V_S), compressional (P)-wave velocity (V_P), and Rayleigh wave phase velocities, it is feasible to solve for P-wave quality factor Q_P and S-wave quality factor Q_S in a layered earth model by inverting Rayleigh wave attenuation coefficients. Model results demonstrate the plausibility of inverting Q_S from Rayleigh wave attenuation coefficients. Contributions to the Rayleigh wave attenuation coefficients from Q_P cannot be ignored when Vs/V_P reaches 0.45, which is not uncommon in near-surface settings. It is possible to invert Q_P from Rayleigh wave attenuation coefficients in some geological setting, a concept that differs from the common perception that Rayleigh wave attenuation coefficients are always far less sensitive to Q_P than to Q_S. Sixty-channel surface wave data were acquired in an Arizona desert. For a 10-layer model with a thickness of over 20 m, the data were first inverted to obtain S-wave velocities by the multichannel analysis of surface waves (MASW) method and then quality factors were determined by inverting attenuation coefficients.  相似文献   

南向行星际磁场事件与磁暴关系的研究   总被引：5，自引：5，他引：5       下载免费PDF全文

刘绍亮  李立文 《地球物理学报》2002,45(3):297-305

利用172-182年IMP-8飞船的太阳风观测资料和相应地磁活动性指数Dst和AE,研究了43个南向行星际磁场事件期间太阳风和磁层的耦合问题. 与这43个事件对应的地磁暴是中等的和强的磁暴(Dst＜-50nT). 结果表明:(1) 在43个事件中有11个(约占25.6髎)紧随激波之后,18个处于激波下游流场中(占42髎),其余14个(占33髎)和激波没有关连. 绝大多数事件都伴有太阳风动压和总磁场强度的增加;(2) 当行星际晨昏向电场强度EI＞-4mV/m时,只引起磁亚暴,对Dst指数没有明显影响. 仅当EI＜-5mV/m时,磁亚暴和磁暴才会同时出现;(3) 太阳风动压的增加会增强能量向环电流的输入,但不是密度和速度单独起作用,而是以PK=ρV2的组合形式影响能量的输入;(4) 虽然行星际磁场(IMF)南向分量BZ对太阳风和磁层的耦合起着关键作用,但IMF的BX和BY分量相对于BZ的大小对太阳风向磁层的能量传输也有一定影响. 当BX、BY相对BZ较大时能量耦合加强.  相似文献