Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Solution for a plane strain rough‐walled hydraulic fracture driven by turbulent fluid through impermeable rock          下载免费PDF全文

N. Zolfaghari  E. Dontsov  A. P. Bunger 《国际地质力学数值与分析法杂志》2018,42(4):587-617

The impact of turbulent flow on plane strain fluid‐driven crack propagation is an important but still poorly understood consideration in hydraulic fracture modeling. The changes that hydraulic fracturing has experienced over the past decade, especially in the area of fracturing fluids, have played a major role in the transition of the typical fluid regime from laminar to turbulent flow. Motivated by the increasing preponderance of high‐rate, water‐driven hydraulic fractures with high Reynolds number, we present a semianalytical solution for the propagation of a plane strain hydraulic fracture driven by a turbulent fluid in an impermeable formation. The formulation uses a power law relationship between the Darcy‐Weisbach friction factor and the scale of the fracture roughness, where one specific manifestation of this generalized friction factor is the classical Gauckler‐Manning‐Strickler approximation for turbulent flow in a rough‐walled channel. Conservation of mass, elasticity, and crack propagation are also solved simultaneously. We obtain a semianalytical solution using an orthogonal polynomial series. An approximate closed‐form solution is enabled by a choice of orthogonal polynomials embedding the near‐tip asymptotic behavior and thus giving very rapid convergence; a precise solution is obtained with 2 terms of the series. By comparison with numerical simulations, we show that the transition region between the laminar and turbulent regimes can be relatively small so that full solutions can often be well approximated by either a fully laminar or fully turbulent solution.  相似文献   

Overview of In - Situ Biodegradation and Enhancement     

DONG Jun  Anthony Adzomani  Zhao Yongsheng 《世界地质(英文版)》2002,5(1)

Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation.  相似文献   

Stochastic modelling of groundwater flow and solute transport in aquifers     

T.-C. Jim Yeh 《水文研究》1992,6(4):369-395

This paper presents an introductory overview of recently developed stochastic theories for tackling spatial variability problems in predicting groundwater flow and solute transport. Advantages and limitations of the theories are discussed. Lastly, strategies based on the stochastic approaches to predict solute transport in aquifers are recommended.  相似文献   

Boundary Conditions and Efficient Solution Algorithms For the Potential Function Formulation of the 3-D Viscous Flow Equations     

G. A. Houseman 《Geophysical Journal International》1990,100(1):33-38

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Discovery of 13 New Variable Stars in the Field of the Open Cluster NGC 2168 （M35）     

Juei-Hwa Hu  Wing-Huen Ip 《中国天文和天体物理学报》2005,5(4):356-362

A wide-field time-series CCD photometric survey of variable stars in the field of the open cluster NGC 2168 was carried out using the BATC Schmidt telescope. In total 13 new variable stars are discovered with three W UMa systems, one EA type and two EB type eclipsing binaries (one of them could be a W UMa system), and seven pulsating stars including three candidates of δScuti stars.  相似文献   

Geochemical survey of thermal system in Northeast China and their geothermometric characters     

MohammedHazaea HUKe MohammedMattash CHENBing M.O.AI-JabaliAref MohammedAbdussalam 《东北亚地学研究》2004,7(2):181-184

The chemical composition of several thermal springs around Changbaishan area has been investigated. Cenozoic basaltic rocks are widely distributed in Northeast China and geothermal characteristics have been described. About one hundred hot springs exist around Changhaishan Volcano at the border between China and D.P.R.Korea with high temperature about 82~C. The pH values of the spring water range from 6.9 to 7.1 and the total flow rate is about 4.8 L/sec. The chemical composition of the thermal springs is sodium carbonate; the high-mineral contents of thermal water are believed to have medicinal properties. Bathhouses are already built along the hot springs to take the advantage of the supposed healing properties. The high quality of those hot springs is believed to be utilitized for mineral water. The chemical equilibrium temperatures were estimated at about 160℃ based on the Na-K-Ca geochemical thermometer.  相似文献   

Three dimensional simulation of fluid flow in X‐ray CT images of porous media     

A. Al‐Omari  E. Masad 《国际地质力学数值与分析法杂志》2004,28(13):1327-1360

A numerical scheme is developed in order to simulate fluid flow in three dimensional (3‐D) microstructures. The governing equations for steady incompressible flow are solved using the semi‐implicit method for pressure‐linked equations (SIMPLE) finite difference scheme within a non‐staggered grid system that represents the 3‐D microstructure. This system allows solving the governing equations using only one computational cell. The numerical scheme is verified through simulating fluid flow in idealized 3‐D microstructures with known closed form solutions for permeability. The numerical factors affecting the solution in terms of convergence and accuracy are also discussed. These factors include the resolution of the analysed microstructure and the truncation criterion. Fluid flow in 2‐D X‐ray computed tomography (CT) images of real porous media microstructure is also simulated using this numerical model. These real microstructures include field cores of asphalt mixes, laboratory linear kneading compactor (LKC) specimens, and laboratory Superpave gyratory compactor (SGC) specimens. The numerical results for the permeability of the real microstructures are compared with the results from closed form solutions. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

MATLAB在运用系统建模处理南海气象数据过程中应用     

董言治  周晓东  娄树理  陈永刚  沈同圣 《成都信息工程学院学报》2004,19(1):76-81

介绍了MATLAB语言特点和系统建模方法的基本理论.根据南海气象数据的实际建模处理过程,给出了建模的详细步骤及其MATLAB实现过程以及MATLABTM的主要实现程序.试验讨论和结果表明利用MATLAB语言可以方便地对南海气象数据用系统建模方法进行建模和处理,MATLAB在运用系统建模法处理南海气象数据方面具有明显的优越性.  相似文献   

Metamorphic phase relations in orthopyroxene-bearing granitoids: implication for high-pressure metamorphism and prograde melting in the continental crust     

S. K. BHOWMIK  L. SAHA  S. DASGUPTA  M. FUKUOKA 《Journal of Metamorphic Geology》2009,27(4):295-315

In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K₂O, Ca/(Ca + Na)_rock and FeO_tot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H₂O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.  相似文献