Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

利用超快速精密星历约束的北斗卫星实时精密定轨     

范磊  施闯  李敏 《大地测量与地球动力学》2018,38(9):937-942

以广播星历为起算轨道的北斗卫星实时滤波精密定轨往往需要较长收敛时间，针对此，提出利用超快速精密星历约束的实时精密定轨方法。通过MGEX跟踪网全球分布的51个测站连续7 d的实测数据，利用平方根信息滤波对北斗卫星实时精密轨道进行确定，并以3 d解事后轨道作为参考，评估北斗卫星实时滤波轨道精度。结果表明，利用广播星历作起算轨道时，北斗实时滤波轨道平均需要经过15 h收敛才能达到稳定，而新方法在这段时间内轨道变化较为平稳，未出现明显的收敛现象，并且7 d时间内GEO卫星在切向、法向和径向上RMS分别优于2.5 m、20 cm和30 cm，IGSO和MEO卫星在3个方向上分别优于30 cm、15 cm和10 cm。
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基于高斯两步移动搜寻法的村镇避难场所可达性研究     

但文羽  肖映辉  胡周灵  詹庆明 《地球信息科学学报》2018,20(10):1412-1421

避难场所可达性是指避难场所与受灾居民之间的通达性,即灾害发生时,避难人员通过避难疏散通道到达避难场所的难易程度,是评价避难场所布局合理性的重要指标。本研究结合高斯两步移动搜寻法和网络分析法,从供需双向出发对村镇地区避难场所进行可达性分析。2种方法的结合,既充分考虑了需求点与设施点的相互作用,又充分考虑了设施点的吸引力随距离的衰减关系,并基于实际道路,以步行疏散时间作为搜索半径,降低了传统研究中因忽略供需间相互作用及实际距离而引起的可达性结果的误差。最后,以神农架松柏镇区为例,验证该方法的实际应用价值。结果表明,该方法能够有效测定村镇地区避难场所的空间可达性,同时,基于GIS软件可以直观地揭示研究区域内避难场所可达性空间分布差异。该方法可为制定科学的村镇防灾减灾规划提供方法支持。  相似文献   

基于GIS的石家庄市雾霾分析     

苏亚聪  史娟  徐爽 《北京测绘》2020,(2):233-237

为了得出雾霾气象成因机制、影响因素和时空分布特征,以石家庄市区与郊县为研究区域,将2013年9月至2016年12月石家庄市各市区、郊县的PM2.5历史监测数据中的有效数据进行了数据分析处理得到雾霾浓度数据,还有温度、降水、风速、地形和人口密度等数据,运用GIS分析的方法,模拟绘制石家庄雾霾的时空分布图、雾霾与各影响因子的专题对比图,得到雾霾形成机制的因子、雾霾的时空分布规律、雾霾季节变化特征、雾霾与地形间的关系等;运用数据分析软件OriginPro8.SR3分析雾霾浓度与风速数据、降雨数据、温度数据间的相关性。  相似文献   

基于概率积分法的采动坡体稳定性预测与分析          下载免费PDF全文

王猛  孙丽丽  薄怀志 《山东国土资源》2018,34(12)

地下采煤会引起地表沉降、变形,甚至引发山体、河堤滑坡等地质灾害。采动坡体的稳定性研究一直是采矿工程中实际关心的问题。该文首先介绍分析了概率积分法移动变形稳态、动态预测模型以及基于极限平衡理论的单滑面采动坡体稳定性预测模型,提出了使用概率积分法结合Knothe时间函数对采动坡体稳定性进行预测分析的方法,并使用C#及XML Schema语言编制了相关的计算程序。最后,结合一个工程实例对采动坡体稳定性和动态变化过程进行了预测与分析,通过实测数据验证了提出方法的可行性,得出了采动引起的坡体下沉是影响坡体稳定性的主要因素,并提出了在坡体拉伸阶段进行注浆加固的方法。  相似文献   

Wave tank and bench-top control testing of a wave energy converter     

《Applied Ocean Research》2019

An increasing number of experiments are being conducted to study the design and performance of wave energy converters. Often in these tests, a real-time realization of prospective control algorithms is applied in order to assess and optimize energy absorption as well as other factors. This paper details the design and execution of an experiment for evaluating the capability of a model-scale WEC to execute basic control algorithms. Model-scale hardware, system, and experimental design are considered, with a focus on providing an experimental setup capable of meeting the dynamic requirements of a control system. To more efficiently execute such tests, a dry bench testing method is proposed and utilized to allow for controller tuning and to give an initial assessment of controller performance; this is followed by wave tank testing. The trends from the dry bench test and wave tank test results show good agreement with theory and confirm the ability of a relatively simple feedback controller to substantially improve energy absorption. Additionally, the dry bench testing approach is shown to be an effective and efficient means of designing and testing both controllers and actuator systems for wave energy converters.  相似文献   

基于SPEI的渭河流域干旱时空变化特征分析          下载免费PDF全文

邹磊  余江游  夏军  王飞宇 《干旱区地理》2020,43(2):329-338

以标准化降水蒸散指数（SPEI）作为评估指标，基于渭河流域28个气象站点1961—2017年实测降水量和气温数据，采用Mann-Kendall（M-K）趋势检验、经验正交函数以及小波变换等方法分析渭河流域干旱时空变化特征，并研究渭河流域干旱与6种大尺度气候因子之间的相关关系，进一步探讨主要气候因子对流域干旱时空分布特征的潜在影响。研究表明：渭河流域在1961—2017年间整体呈现出变旱的趋势。通过经验正交函数分解，渭河流域干旱分布场主要有3种典型模态类型，分别为全局型、西北—东南反向分布型以及东—西反向分布型；同时，大尺度气候因子南方涛动指数SOI与流域干旱分布场具有更好的相关关系，对该区域内干旱变化有较强的影响。  相似文献   

A land-use mix allocation model considering adjacency,intensity, and proximity     

Sunyong Eom  Tsutomu Suzuki  Myeong-Hun Lee 《International journal of geographical information science》2020,34(5):899-923

ABSTRACT

Land-Use Mix (LUM) refers to the strategy of integrating complementary functions within a building or area. While LUM has become a dominant approach in urban planning, its actual benefits and vision for spatial planning remain unclear. To clarify this issue, this study discerns the spatial features of land-use patterns depending on the compatibilities among land-use categories. Accordingly, this study introduces three LUM measures – adjacency, intensity, and proximity – to identify differences in the spatial distribution of land-use categories. Based on these measures, a land-use allocation model is developed to specify spatial patterns satisfying the given compatibilities. This model is tested by applying the concept of the neighborhood unit on a case study of normative land-use patterns subject to specified compatibilities. The results describe spatial features of four compatibility sets, including a set exhibiting a compatibility conflict between the same land-use pair and LUM measures when, for example, a given land-use pair is compatible in terms of intensity but incompatible in terms of proximity. Understanding the spatial features of a normative land-use pattern that satisfies various possible compatibilities will facilitate the incorporation of the LUM approach into local planning guidance and zoning ordinances.  相似文献   

Overview of In - Situ Biodegradation and Enhancement     

DONG Jun  Anthony Adzomani  Zhao Yongsheng 《世界地质(英文版)》2002,5(1)

Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation.  相似文献   

用双三次样条函数和GPS资料反演现今中国大陆构造形变场   总被引：38，自引：20，他引：18  

杨少敏  游新兆  杜瑞林  乔学军  王琪 《大地测量与地球动力学》2002,22(1):68-75

将中国大陆现今构造变动视为一种连续的地壳变形,利用双三次样条函数模拟了近期GPS测定的大陆内部及周边地区412个测站速率,反演大陆地区自洽的构造变动速度场和应变率场.模拟结果显示:印度板块与欧亚板块的碰撞、挤压是构成中国大陆内部岩石层水平形变的主要驱动力.印度板块在东喜马拉雅构造结深深插入青藏高原,造成地壳大规模的缩短和抬升.青藏高原东南部的喜马拉雅带、拉萨和羌塘地块以及青藏高原东南边的川滇地区,内部构造活动强烈,其内部的构造变形包含地壳碎片的冲断、褶皱和侧向逃逸.大陆地壳(或岩石圈)的增厚,尤其是喜马拉雅山脉南北向的快速缩短和青藏高原东西向的缓慢拉张,大约吸收了印欧板块会聚量的85%,西藏中东地区东西向的拉张速率达到了(16±2.0)mm/a,且顺时针方向扭转明显.印度板块相对欧亚板块运动的欧拉极为(29.7°N, 19.3°E, 0.392°/Ma);华南地块相对于欧亚大陆向东(102°±7.4°)南的运动速率是(11±1.54)mm/a,华南块体相对欧亚板块运动的欧拉极为(62.25°N, 126.56°E, 0.141°/Ma);塔里木地块相对较稳定,其西部运动速度高于东部运动速度,作顺时针方向旋转.总体上讲,中国大陆运动方向为北偏东呈辐射状,从西部近南北方向的运动转向东部地区东南方向的运动,绕东喜马拉雅构造结有一顺时针方向的旋转.横穿喜马拉雅构造带及青藏内部的南北向压缩速率为(19±2.0)mm/a,横穿西天山构造带的南北向压缩平均速率为(13±1.5)mm/a,横穿东天山构造带的南北向压缩平均速率为(6.0±1.4)mm/a.阿尔金断裂带的左旋走滑速率为(6±1.2)mm/a.  相似文献