粮食中痕量氟的离子选择电极法测定     

许国琳  邬家祥 《矿物岩石》1991,11(1):107-110

本文采用0.1mol/L HClO_4 80℃恒温水浴浸取粮食中的氟,并用氟离子选择电极于pH=1.0下直接测定其电位值。该方法浸取率高,检测限为0.016μg/ml。在0.14—1.0μg/ml之间有较好地能斯特响应。并对氟含量小于0.14μg/ml的样品提出了空白浓度校正的数字处理方法,经过空白校正能斯特响应线性范围变为0.01—1.00μg/ml。该方法适于固态生物样品中氟的测定。变异系数小于5％。  相似文献   

喀喇昆仑山克勒青河谷冰川冰岩界面特征的初步研究   总被引：2，自引：0，他引：2  

唐建成  何元庆 《冰川冻土》1991,13(4):331-336

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Nonequilibrium thermodynamics of pressure solution     

F. K. Lehner  J. Bataille 《Pure and Applied Geophysics》1984,122(1):53-85

This paper is concerned with the thermodynamic theory of solution and precipitation processes in wet crustal rocks and with the mechanism of steady pressure-solution slip in contact zones, such as grain-to-grain contacts, fracture surfaces, and permeable gouge layers, that are infiltrated by a mobile aqueous solution phase. A local dissipation jump condition at the phase boundary is fundamental to identifying the thermodynamic force driving the solution and precipitation process and is used here in setting up linear phenomenological relations to model near-equilibrium phase transformation kinetics. The local thermodynamic equilibrium of a stressed pure solid in contact with its melt or solution phase is governed by Gibbs's relation, which is rederived here, in a manner emphasizing its independence of constitutive assumptions for the solid while neglecting surface tension and diffusion in the solid. Fluid-infiltrated contact zones, such as those formed by rough surfaces, cannot generally be in thermodynamic equilibrium, especially during an ongoing process of pressure-solution slip, and the existing equilibrium formulations are incorrect in overlooking dissipative processes tending to eliminate fluctuations in superficial free energies due to stress concentrations near asperities, defects, or impurities. Steady pressure-solution slip is likely to exhibit a nonlinear dependence of slip rate on shear stress and effective normal stress, due to a dependence of the contact-zone state on the latter. Given that this dependence is negligible within some range, linear relations for pressure-solution slip can be derived for the limiting cases of diffusion-controlled and interface-reaction-controlled rates. A criterion for rate control by one of these mechanisms is set by the magnitude of the dimensionless quantityk/2C _pD, wherek is the interfacial transfer coefficient, is the mean diffusion path length,C _p is the solubility at pressurep, andD is the mass diffusivity.  相似文献   

近年来我国冰流动研究进展     

黄茂桓 《冰川冻土》1995,17(4):366-370

本简要介绍我国学１９８７年以来在国内外冰流动理论和试验研究中取得的进展，包括晶粒长大规律、异向性冰的第三蠕变、压剪联合作用下冰的流动以及全新世冰和冰期冰流动性质的差别等，并加以评论。  相似文献   

菌藻对碳酸盐颗粒的泥晶化作用研究─以滇西保山地区下石炭统研究为例   总被引：1，自引：1，他引：1  

韦龙明 《沉积学报》1995,(3)

碳酸盐颗粒泥晶化由真菌类和藻类的穿孔所引起，颗粒泥晶化可划分为四个阶段６种类型，泥晶套和泥晶铸型分别代表泥晶化的成长、成熟阶段。丰富的泥晶化颗粒为浅滩标志；泥晶化的深度与沉积速度成反比；泥晶化均匀程度与颗粒翻转次数成正比；颗粒泥晶化类型组合与风暴沉积有关；暴露环境出现溶蚀孔洞或负鲕。菌藻的泥晶化作用可加速海水及成岩压实作用对颗粒的破碎和细化并产生内碎屑和灰泥；鲕粒泥晶化后转变为辐射鲕和假鲕。  相似文献   

长城系团山子组火山岩颗粒锆石U－Pb年龄及其地质意义   总被引：46，自引：1，他引：46  

李怀坤  李惠民  陆松年 《地球化学》1995,(1)

蓟县中－上元古界典型剖面之邻区平谷县境内，长城系团山子组连续发育两层厚度各为１ｍ左右的富钾粗面安山岩，发育气孔构造和绳状构造。其中存在三种不同成因类型锆石，应用颗粒锆石Ｕ－Ｐｂ测定年龄技术，得到：（１）自生锆石，其Ｕ－Ｐｂ不一致上交点年龄为１６８３±６７Ｍａ，代表该火山岩形成年龄；（２）捕获锆石，多为原碎屑锆石，较年轻的一种捕获锆石的２０７Ｐｂ／２０６Ｐｂ表面年龄为１８２３±６８Ｍａ，这限定了长城系底界年龄应新于１８２３Ｍａ；（３）后生热液锆石，其Ｕ－Ｐｂ年龄为４６０Ｍａ左右，反映后期热液事件发生的时代。  相似文献   

环境空气中的气溶胶污染的影响分析     

常凤池 《矿产与地质》2005,19(6):728-729,731

环境空气中气溶胶粒子是由极性气体凝聚而成,呈三峰型分布.对其空气中溶胶粒子,特别是可吸入粒子的成分,气溶胶态、粒径大小、浓度等对人体健康危害进行了分析研究.  相似文献   

Cenozoic uplift of West Qinling, northeast margin of Tibetan plateau-a detrital apatite fission track record from the Tianshui basin     

Wang Xiuxi  Li Jijun  Song Chunhui  Zhang Jun  Zhao Zhijun  Gao Junping  Pan Meihui 《Frontiers of Earth Science》2007,1(3):304-308

The Cenozoic sedimentation in the Tianshui basin, which is located at the junction of the liupanshan and West Qinling, northeast margin of the Tibetan plateau, provides a record for the regional tectonism and exhumation history of the surrounding mountains. Thermochronologic study on the detrital apatite grains from sandstones at Yaodian, near Tianshui, has revealed two rapid tectonic uplift-exhumation events of the source area, which happened at 23.7 and 14.1 Ma, respectively. The fast exhumation (0.34 mm/a) at 23.7 Ma, which recorded the tectonic uplift of West Qinling, led to the formation of the Neogene Tianshui basin and initiated the reception of alluvial deposits. This event is most likely in response to the synchronous tectonism of the Tibetan plateau. The source region experienced another rapid exhumation (1.05 mm/a) at 14.1 Ma, when the Tianshui basin began to depress broadly and fluvial-lacustrine sediments dominated the Late Miocene. Translated from Acta Sedimentologica Sinica, 2006, 24(6): 783–789 [译自: 沉积学报]  相似文献   

Experimental study of surface texture and resonance mechanism of booming sand     

Qu JianJun  Zhang KeCun  Sun Bo  Jiang ShengXiang  Dong GuangRong  Zu RuiPing  Fang HaiYan 《中国科学D辑(英文版)》2007,50(9):1351-1358

The sound-producing mechanism of booming sand has long been a pending problem in the blown sand physics. Based on the earlier researches, the authors collected some silent sand samples from Teng- ger Desert, Australian Desert, Kuwait Desert, beaches of Hainan Island and Japanese coast as well as the soundless booming sand samples from the Mingsha Mountain in Dunhuang to make washing ex- periments. In the meantime the chemical corrosion experiment of glass micro-spheres, surface coating experiment and SEM examination were also conducted. The experimental results show that the sound production of booming sand seems to have nothing to do with the presence of SiO2 gel on the surface of sand grains and unrelated to the surface chemical composition of sand grains but is related to the resonance cavities formed by porous (pit-like) physical structure resulting from a number of factors such as wind erosion, water erosion, chemical corrosion and SiO2 gel deposition, etc. Its resonance mechanism is similar to that of Hemholz resonance cavity. Under the action of external forces, nu- merous spherical and sand grains with smooth surface and porous surface are set in motion and rub with each other to produce extremely weak vibration sound and then become audible sound by human ears through the magnification of surface cavity resonance. However the booming sands may lose their resonance mechanism and become silent sand due to the damping action caused by the invasion of finer particles such as dust and clay into surface holes of sand grains. Therefore, clearing away fine pollutants on the quartz grain surface is an effective way to make silent sand emit audible sound.  相似文献   

Development of algebra algorithms for automated generation of grain‐size distribution maps     

Alessandro Sarretta  Mauro Masiol  Emanuela Molinaroli 《地球表面变化过程与地形》2007,32(7):1116-1127

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