Researches on the Internal Molecular Weight Uniformity of Chitosan Biomaterials     

LANG Xuqian  LI Yang  SUN Guohui  ZHOU Zhongzheng  LI Jing  FENG Chao  KONG Ming  LIU Ya  CHENG Xiaojie  CHEN Xiguang 《中国海洋大学学报(英文版)》2020,19(2):459-465

Uniform molecular weight(Mw)chitosan(CS)is highly demanded in medical biomaterial industry.This present article described heterogeneous degradation of CS in aqueous HCl/ethanol solution,in which progress uniform Mw CS was successfully prepared.The Mw distribution of CS was measured by gel permeation chromatography(GPC)analysis.Moreover,the structure and properties of degraded CS were characterized by Fourier transform infrared spectroscopy(FT-IR),nuclear magnetic resonance spectroscopy(^1H NMR),X-ray diffraction(XRD)and thermogravimetric(TG)analysis.In addition,the biocompatibility of degraded CS was also assessed by hemolysis rate(HR)measurement.The Mw of CS dramatically decreased from 246 KDa to 76 k Da at the initial 30 min,and stabilized at 18 kDa after 24 h.GPC analysis results showed that the degraded CS molecular become homogenization.FT-IR and 1 H NMR analysis confirmed the basic structure of CS molecular backbone was not destroyed during this progress.Besides,the water solubility of CS was not significantly influenced by this reaction.Moreover,the XRD analysis revealed that crystallinity of degraded CS increased from 70.32% to 99.25%with time.The TG analysis showed improved thermal stability of degraded CS.HR measurement demonstrated the degraded CS possessed excellent biocompatibility.This simple and efficient heterogeneous degradation would open up a new route to produce uniform Mw CS.  相似文献   

基于纹理合成的三维地形水墨风格渲染研究     

彭湃  李少梅 《测绘与空间地理信息》2017,(3)

提出了基于纹理合成的三维地形水墨风格渲染的方法,以规则格网DEM为数据源,基于OSG进行三维地形建模,在此基础上提取山体特征线,然后生成一幅灰度控制图像。对Efros01纹理合成算法进行改进,利用灰度控制图像指导水墨纹理的合成,将得到的纹理图像映射到三维地形上,实现对三维地形的水墨风格渲染,通过对水墨纹理样本的选择和纹理合成参数的设置能够实现对纹理合成过程的交互控制。结果表明,该渲染方法对三维地形的水墨风格渲染具有较好的效果。  相似文献   

A Research Synthesis and Theoretical Model of Relationships Between Factors Influencing Outdoor Domestic Water Consumption     

Albert Llausàs  David Saurí 《社会与自然资源》2017,30(3):377-392

Outdoor domestic water use is often targeted by demand management strategies. However, despite a rich empirical evidence base coming from primary studies, it is still unclear how factors that influence this type of demand interact and which are the most suitable to be addressed by water conservation programs. Based on 423 scientific contributions, we develop a research synthesis combining a variety of techniques to create a theoretical model of the relationships among factors most consistently observed in the literature. The findings uncover a great degree of complexity in terms of interactions between spatial-structural, social-structural, and cultural and psychological factors at different scales. For researchers, the methodology and the outcomes can be useful to better frame existing and future research within the literature on the topic. In practice, the adaptation of the theoretical model to local specificities can facilitate the design of more efficient and integrated demand management strategies.  相似文献   

油气无机成因学说的新进展   总被引：16，自引：2，他引：16  

张景廉  张平中  吕锡敏  关银录  廖天纯  张正刚  王爱勤 《地球科学进展》1998,13(1):44-50

介绍了油气无机成因学说的新发展,主要是目前在西方、俄罗斯等影响较大的关于无机生油气的几个学派以及在中国的一些学派。其中之一是Ｇｏｌｄ氏的地幔脱气理论,之二是费－托地质合成理论。  相似文献   

LBS导航认知地图服务系统设计与实现     

刘召芹  谢彩香  林宗坚  姚春卉 《测绘科学》2007,32(2):60-63

科技发展改变了电子地图制作和使用环境。本文在分析传统大数据量地图形式在LBS中的应用缺陷后,提出了符合用户需求和移动终端条件的认知地图可视化方案,这种不同于传统制图综合原则制作的认知地图能有效缓解目前在LBS应用中存在的地图数据与屏幕大小的矛盾,适应了移动环境下用户的多行为状态和终端硬件特点。  相似文献   

Variability in the speciation of iron in the northern North Sea     

Martha Gledhill  Constant M. G. van den Berg  Rob F. Nolting  Klaas R. Timmermans 《Marine Chemistry》1998,59(3-4)

Variations in the speciation of iron in the northern North Sea were investigated in an area covering at least two different water masses and an algal bloom, using a combination of techniques. Catalytic cathodic stripping voltammetry was used to measure the concentrations of reactive iron (Fe_R) and total iron (Fe_T) in unfiltered samples, while dissolved iron (Fe_D) was measured by GFAAS after extraction of filtered sea water. Fe_R was defined by the amount of iron that complexed with 20 μM 1-nitroso-2-napthol (NN) at pH 6.9. Fe_T was determined after UV-digestion at pH 2.4. Concentrations of natural organic iron complexing ligands and values for conditional stability constants, were determined in unfiltered samples by titration. Mean concentrations of 1.3 nM for Fe_R, 10.0 nM for Fe_T and 1.7 nM for Fe_D were obtained for the area sampled. Fe_R concentrations increased towards the south of the area investigated, as a result of the increased influence of continental run off. Fe_R concentrations were found to be enhanced below the nutricline (below 40 m) as a result of the remineralisation of organic material. Enhanced levels of Fe_T were observed in some surface samples and in samples collected below 30 m at stations in the south of the area studied, thought to be a result of high concentrations of biogenic particulate material and the resuspended sediments respectively. Fe_D concentrations varied between values similar to those of Fe_T in samples from the north of the area to values similar to those of Fe_R in the south. The bloom was thought to have influenced the distribution of both Fe_R and Fe_T, but less evidence was observed for any influence on Fe_R and Fe_D. The concentration of organic complexing ligands, which could possibly include a contribution from adsorption sites on particulate material, increased slightly in the bloom area and in North Sea waters. Iron was found to be fully (99.9%) complexed by the organic complexing ligands at a pH of 6.9 and largely complexed (82–96%) at pH 8. The ligands were almost saturated with iron suggesting that the ligand concentration could limit the concentration of iron occurring as dissolved species.  相似文献   

Production of methyl bromide and methyl chloride in laboratory cultures of marine phytoplankton II     

M. G. Scarratt  R. M. Moore 《Marine Chemistry》1998,59(3-4)

Methyl halides (monohalomethanes), especially methyl bromide, are known to contribute significantly to ozone destruction in the stratosphere. Budgets of natural and anthropogenic methyl bromide suggest that marine organisms may be the source of a significant proportion of the total global production. Since phytoplankton are abundant in surface waters, they are obvious candidates. Cultures of nine phytoplankton species were grown in CO₂-enriched, nitrate-limited medium in sealed glass vessels. Species tested include Chaetoceros calcitrans, Isochrysis sp., Porphyridium sp., Synechococcus sp., Phaeodactylum tricornutum, Tetraselmis sp., Prorocentrum sp., Emiliania huxleyi and Phaeocystis sp. Methyl bromide (CH₃Br) and methyl chloride (CH₃Cl) concentrations were determined by bubbling the cultures with high-purity air, cryotrapping the effluent and analyzing it on a gas chromatograph with an electron capture detector. The Phaeocystis sp. samples were monitored with GCMS. Cell population, bacterial population, Chl a, pH, and nitrate concentration were monitored for periods of at least two weeks. CH₃Cl was produced by all cultures. CH₃Br was absent in Tetraselmis sp. and Isochrysis sp. cultures, but present in all the others. Methyl iodide (CH₃I) was present in most cultures but could not be quantified due to analytical limitations. CH₃I and CH₃Br production was fastest in stationary phase and continued long after cell division had ceased. Axeic cultures of Phaeocystis sp. achieved almost identical production rates of CH₃Cl and CH₃Br as xenic cultures of the same species. Species from tropical waters had faster CH₃Cl and CH₃Br production rates than temperate species. Scaling the observed production rates using global standing stock estimates for Chl a and particulate nitrogen indicate that phytoplankton can account for only a fraction of the CH₃Cl and CH₃Br believed to be produced in the ocean. Calculations based on the estimated global biomass of Phaeocystis sp. and E. huxleyi blooms show that their contribution is insignificantly small.  相似文献   

渤海南部油气开发区浅层工程地质特性及其与沉积相的关系     

李玉瑛  毛凤军 《海洋科学》1998,22(1):44-46

根据渤海南部两个钻孔的实际材料,用成因土质学的观点和方法研究沉积物的沉积环境同其物理,力学性质的内在联系,探讨了本区浅层工程地质特性在时空上与环境的相互关系。  相似文献   

地震波斜入射对高面板坝地震反应的影响          下载免费PDF全文

岑威钧  袁丽娜  袁翠平  张自齐 《地震工程学报》2015,37(4):926-932

为研究地震波斜入射对高面板坝地震反应的影响,根据地震波动入射理论,采用FORTRAN进行波动荷载的编程计算,并与大型通用有限元软件ADINA相结合,实现基于黏弹性人工边界的地震波斜入射,研究P波和SV波分别以不同角度入射对高面板堆石坝地震反应的影响。结果表明,地震波斜入射时大坝地震动反应与垂直入射时明显不同,常规垂直入射的结果偏于不安全,因此在高面板坝地震反应分析和抗震设计中应考虑地震波斜入射的影响。  相似文献   

工作面电磁波高精度层析成像及其应用   总被引：7，自引：0，他引：7  

程久龙  于师建  邱伟  程洪良  宋振江 《煤田地质与勘探》1999,27(4):62-64

介绍了工作面电磁波透视法(简称坑透)高精度层析成像计算原理和工作方法,并结合电磁波衰减特征和应用实际,探讨了不同地质异常的解释方法。实践证明,坑透高精度CT技术应用大大提高了资料解释的精确度和可信度,增强了异常的识别能力。   相似文献