Diversities in biomarker compositions of Carboniferous–Permian humic coals in the Ordos Basin,China     

Q. Yuan 《Australian Journal of Earth Sciences》2018,65(5):727-738

The molecular composition of Carboniferous–Permian coals in the maturity range from 0.66 to 1.63% vitrinite reflectance has been analysed using organic geochemistry to investigate the factors influencing the biomarker compositions of humic coals. The Carboniferous–Permian coal has a variable organofacies and is mainly humic-prone. There is a significant difference in the distribution of saturated and aromatic hydrocarbons in these coals, which can be divided into three types. The Group A coals have biomarker compositions typical of humic coal, characterised by high Pr/Ph ratios, a lower abundance of tricyclic terpanes with a decreasing distribution from C₁₉ tricyclic terpane to C₂₄ tricyclic terpane and a high number of terrigenous-related biomarkers, such as C₂₄ tetracyclic terpane and C₂₉ steranes. The biomarker composition of Group B coals, which were deposited in a suboxic environment, have a higher abundance of rearranged hopanes than observed in Group A coals. In contrast, in Group C coals, the Pr/Ph ratio is less than 1.0, and the sterane and terpane distributions are very different from those in groups A and B. Group C coals generally have abnormally abundant tricyclic terpanes with a normal distribution maximising at the C₂₃ peak; C₂₇ steranes predominates in the m/z 217 mass fragmentograms. The relationships between biomarker compositions, thermal maturity, Pr/Ph ratios and depositional environments, indicate that the biomarker compositions of Carboniferous–Permian coals in Ordos Basin are mainly related to their depositional environment. This leads to the conclusion that the biomarker compositions of groups A and B coals collected from Shanxi and Taiyuan formations in the northern Ordos Basin are mainly related to their marine–terrigenous transitional environment, whereas the biomarker compositions for the Group C coals from Carboniferous strata and Shanxi Formation in the eastern Ordos Basin are associated with marine incursions.  相似文献   

Identification and geochemical significance of polarized macromolecular compounds in lacustrine and marine oils     

Jingwei Cui  Rukai Zhu  Jian Hu 《中国地球化学学报》2014,33(4):431-438

Polarized macromolecular compounds in typical lacustrine and marine shale oils collected from the Ordos Basin and Tarim Basin of China were analyzed by FT-ICR-MS. Maturity was taken into consideration by diagenesis physical simulation experiments on shale oils, which had been collected at various temperature and pressure stages. The results showed that similar components existed in non-hydrocarbon and asphaltenes and the main peak compound classes of Nl and 02 were potential parameters for identifying typical marine oil and lacustrine oil in China. Nitrogen compounds/（nitrogen compounds and oxygen compounds）, such as Nl/（O2＋Nt）, NL/（Oa＋Nt）, Ni/（NiO1＋N1O2） are the maturity indicators, which are related with C-N and C-O bond energy. Differences in molecular components and weights between marine and lacustrine oils are the effective index to identify source maturity and sedimentary environment.  相似文献   

Natural Gas Types,Distribution Controlling Factors,and Future Exploration in the Western Qaidam Basin   总被引：1，自引：0，他引：1  

GUO Zeqing  SUN Ping  LI Jian  ZHANG Lin  LIU Weihong  TIAN Jixian  ZHANG Shaosheng  ZENG Xu 《《地质学报》英文版》2014,88(4):1214-1226

The Paleogene and Neogene oil and gas in the western Qaidam basin have a regular distribution in three concentric zones from the edge to the center of the basin.Natural gas mainly occurs in the inner zone,and the gas-oil ratio of the northern area of the basin is significantly higher than that of the southern area.Large amounts of carbon isotope data of natural gas,plotted in Xshaped and comprehensive identification diagrams for the southern area and northern area,respectively,were used to identify the types of natural gas.The large-scale distribution of natural gas is highly consistent with the Ro values of major source rocks,but is poorly correlated with the type of organic matter.This indicates that the main controlling factor of natural gas distribution is organic matter maturity,and the kerogen types act as the basis for the formation of different types of natural gas.Paleouplifts and squeezed anticlines near hydrocarbon generation depression centers,which are major natural gas-rich regions,control the migration directions of natural gas,while hydrocarbon migration pathways and fault systems connecting gas sources are the most important factors for natural gas reservoir formation in the inner basin.Therefore,favorable zones for natural gas distribution can be predicted on the basis of the distribution of thermal evolution and the gas generation intensity of major source rocks as well as the structural map.The Shizigou-YoushashanYingdong-Dawusi,Youquanzi –Kaitemilike- Youdunzi,and Xiaoliangshan – Nanyishan- Dafengshan structural belts are favorable zones for natural gas accumulation.This study has important theoretical and practical significance for future natural gas exploration.  相似文献   

鲁乐地区早前寒武纪花岗岩类演化及大陆地壳生长     

李洪奎  耿科  禚传源  梁太涛  陈莉 《山东地质》2012,(4):8-14

通过对太古宙和古元古代花岗岩成分判别分析,提出了鲁东地区早前寒武纪花岗岩类可能分为3期,第一期为中太古代TTG组合,发育不完全;第二期为新太古代T1T2G1组合,具有贫K2O的奥长花岗岩演化趋势;第三期为古元古代早期G2组合,仅具富K2O的钙碱性演化趋势。探讨了不同组合花岗岩的形成环境,新太古代T2T2G1组合为岛弧环境,古元古代早期为大陆碰撞环境;不同的花岗岩类岩石组合分别对应的陆壳成熟度为：T1T2G1组合为新生的初始不成熟陆壳,G2组合则为最终的成熟陆壳。鲁东早前寒武纪花岗岩类随时间从新太古代至古元古代早期的演化,记录了鲁东大陆地壳形成的完整的地质演化过程。  相似文献   

The origin and maturation of lagoonal glauconites: a case study from the Oligocene Maniyara Fort Formation,western Kutch,India     

Santanu Banerjee  Shovan Lal Chattoraj  P. K. Saraswati  Somnath Dasgupta  Urbashi Sarkar  Adam Bumby 《Geological Journal》2012,47(4):357-371

An integrated study of the sedimentology, micropalaeontology, mineralogy and geochemistry of glauconites in the Oligocene Maniyara Fort Formation (western Kutch, India), has been undertaken. Authigenic glauconites, mostly of evolved type, formed within a back‐barrier lagoonal environment. Foraminifera help constrain the biostratigraphy and along with sedimentological evidence, provide information on the depositional conditions. Glauconite in the Maniyara Fort Formation occurs either as infillings within intra‐particle pores of larger foraminifers, or as an altered form of faecal pellets. X‐ray diffraction studies reveal the less mature nature of glauconite infillings compared to the glauconite pellets. Electron microprobe investigation confirms a relative enrichment of K₂O and total Fe₂O₃ in the latter. Both varieties of glauconite formed by initial authigenic precipitation of K‐poor glauconite and subsequently matured by addition of potassium in the interlayer sites and fixation of total iron in the octahedral sites; calcium, magnesium and aluminum were released from the glauconite structure concomitantly. Alkaline conditions during the entire process of glauconite formation did not allow dissolution of foraminiferal tests. Mineralogical and chemical characteristics of the Maniyara Fort Formation glauconites are more similar to deep marine glauconites than those reported from other shallow or marginal marine settings. A low negative cerium anomaly, as well as abundant pyrite, suggests formation of glauconite in sub‐oxic micro‐environments, created by decay of organic matter associated with foraminiferal chambers and faecal pellets. Sub‐oxic condition apparently prevailed relatively longer within the Maniyara Fort Formation lagoons. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

铀对(Ⅱ型)低熟烃源岩生烃演化的影响Ⅱ     

毛光周  刘池洋  张东东  邱欣卫  王建强  刘宝泉  刘静江  曲少东  张参  邓煜  王飞飞 《地质学报》2012,86(11):1833-1840

在油、气、煤、铀多种能源矿产形成演化富集成藏(矿)过程中,有机-无机相互作用是普遍存在的,在有机质的强大吸附作用及其所提供的还原环境为铀的富集成矿起促进作用的同时,铀也改变了烃源岩的生烃演化进程。本文在Ⅱ型低熟烃源岩中加入碳酸铀酰溶液的条件下进行了生烃模拟实验,对比无铀-加铀样品生烃模拟实验产物的相关参数,以探讨油气生成过程中无机铀所起的作用。从实验结果可以看出,铀可以使产物中不饱和烃向饱和烃转化;促进长链烃的裂解,促进低分子量烃类的产生,从而使CH4的含量提高,使生成的烃类的干气化程度增加。铀可以在低温阶段促进有机质的成熟度,降低烃源岩的生烃门限,使低熟烃源岩早期生成烃类;同时在高温阶段阻止有机质过度成熟,利于所生成烃的保存。因而铀可能是未熟-低熟油气生成可能的无机促进因素之一。  相似文献   

Geochemical characteristics of aromatic hydrocarbons in saline lacustrine crude oils and their significance as exemplified by the south area of western Qaidam Basin   总被引：2，自引：0，他引：2  

Xiaoye Mo  Min Zhang 《中国地球化学学报》2012,31(4):476-484

Based on quantitative GC-MS analysis of 40 crude oil samples collected from the south area of western Qaidam Basin,one of the largest saline lacustrine basins in China,the geochemical characteristics of aromatic hydrocarbons in oils were studied systematically in this paper.Among those constitutes,naphthalene(43% 59%),phenanthrene(12% 21%) and taromatic-sterane series(6% 28%) were the main ones of aromatic hydrocarbons.The ratio of aromatic hydrocarbon maturity parameter vs.saturated hydrocarbon maturity parameter C 29 20S/(20S+20R) shows that some aromatic hydrocarbon maturity parameters are not suitable for low-mature oils,including MPI,MNR,DNR,etc.Meanwhile,maturity parameters for dibenzothiophene and taromatic-sterane series are more appropriate for low maturity saline lacustrine crude oils.Based on the ratio of 4,6-DMDBT/1,4-DMDBT,the R c values are within the range of 0.59% 0.72%.However,the abundance of dibenzothiophene(DBT) is low,and the dibenzofuran(DBF) content is even lower,suggesting that the crude oils were formed in a saline lacustrine anaerobic environment.The high abundance of C 26 triaromatic steroid also indicates that the source material is brackish water-saline water with strong reducibility.  相似文献   

温度对页岩吸附解吸的敏感性研究   总被引：3，自引：0，他引：3  

李武广  杨胜来  陈峰  董谦  娄毅  王海洋 《矿物岩石》2012,32(2):115-120

页岩气的赋存方式主要是吸附,使吸附在页岩储层内表面的天然气解吸出来是提高页岩气井产量的最终目标。为了使吸附在页岩储层内的天然气完全地被采出来,提出了升温加速解吸的方法来提高页岩气采收率。通过室内吸附与解吸实验,对4块页岩岩心分别进行了不同温度下的等温吸附量与解吸量测定,分析影响页岩储层吸附量与解吸量的主要因素,研究提高储层温度来加速解吸页岩储层CH4吸附量的适应性。研究结果表明,页岩的吸附能力与页岩的有机碳含量和有机成熟度密切相关,随着页岩有机碳含量以及有机成熟度的提高,页岩的吸附能力增加。不同温度的吸附与解吸实验表明,温度越高,页岩的吸附能力越低,随着温度的升高,页岩气的解吸量增大。升温可以提高页岩气的解吸时间、解吸速度以及提高页岩气最终采收率。提高页岩储层温度进行加速解吸是一种提高页岩气产量的好方法,可以对页岩气藏开采和开发理论提供一定的指导意义。  相似文献   

池养乌苏里拟鲿雌雄鱼生长及周年性激素与性腺发育研究   总被引：2，自引：0，他引：2  

贾一何  黄鹤忠  李倩倩  张群英 《海洋科学》2012,36(3):61-66

乌苏里拟鲿(Pseudobagrus ussuriensis)的种质资源保护和商品鱼养殖正在我国悄然兴起。本文首次研究了乌苏里拟鲿雌、雄鱼在池塘养殖条件下的生长规律以及性成熟鱼周年性腺发育与性激素变化特性。研究结果表明,乌苏里拟鲿随着年龄的增长,雌鱼和雄鱼之间的体质量、体长差异逐渐明显,雌鱼体长与体质量的关系式为:W=0.182 5L1.964 6(R2=0.944 5);雄鱼体长与体质量的关系式为:W=0.188 1L2.0059(R2=0.961 8)。在12月份(2龄鱼)至翌年10月份(3龄鱼)期间,雌、雄鱼丰满度呈下降趋势,成熟度、血清雌二醇(E2)和睾酮(T)水平均呈先升高后下降的变化规律。雌鱼的E2和T在5月份达到最高值,分别为(1 624.23±331.4)pg/mL和(1 320.85±279.12)pg/mL;雄鱼的E2在5月份达到最高值(323.17±147.36)pg/mL,而T的最高值则出现在4月份,为(758.33±100.47)pg/mL。雌、雄鱼性腺发育和成熟度基本同步,从外观和组织学观察对性腺的分期显示,2龄乌苏里拟鲿在12月份的精巢和卵巢已发育至第Ⅲ期,在次年6月份均达到第Ⅴ期。  相似文献   

塔里木盆地库车坳陷中生界油源岩有机成熟度和生烃历史   总被引：17，自引：3，他引：14  

王飞宇  杜治利  李谦  张水昌  陈建平  肖中尧  梁狄刚 《地球化学》2005,34(2):136-146

库车坳陷存在上三叠统黄山街组(T3h)和中侏罗统恰克马克组(J2q)两套湖相油源岩,从三个方面研究了这两套油源岩现今成熟度分布及其在地质历史中的演化:一是对钻孔和露头剖面两套油源岩样品镜质组反射率实测分析;二是从中下侏罗统煤系源岩,特别是煤中镜质组反射率实测数据限定分别位于中下侏罗统(J1y和J2k)煤系地层上下的两套油源岩的有机成熟度;三是从地层分层数据和地温史对人工井(中)两套油源岩成熟度的模拟分析.库车坳陷黄山街组和恰克马克组露头剖面油源岩镜质组反射率自东向西总体上呈现明显的增高趋势,在东部基本上处于临界成熟-成熟阶段,而西部则处于凝析油-湿气阶段或干气阶段.库车坳陷黄山街组油源岩主要生油阶段位于65～5 Ma,生油高峰约在23～12 Ma,油源灶最早(约65 Ma)出现在坳陷西部,不断向东部扩展;恰克马克组湖相油源岩主要生油阶段位于12 Ma至现今,生油高峰约在5～2 Ma,油源灶最早(约12 Ma)出现在拜城凹陷腹部,后向四周扩展.  相似文献