利用AutoPrep技术抑制型电导离子色谱法检测土壤中碘     

刘肖  史亚利Archava Siriraks Mike Kinderman 《岩矿测试》2007,26(6):446-450

利用AutoPrep自动样品前处理技术，对土壤燃烧吸收液进行在线预浓缩，抑制型电导进行检测，建立了一种全新思路的检测土壤样品中碘的方法。选择亲水性非常强的氢氧化物选择性IonPac AS16阴离子交换色谱柱，淋洗液发生装置在线产生KOH进行等梯度淋洗，抑制型电导检测。结果表明，对于土壤燃烧吸收液中碘离子的测定，方法检出限（S／N=3）可达1．2μg/L，线性相关系数为0．9998，方法精密度（RSD，n=7）为1．161％～4．566％，回收率在90．6％～100．8％。采用AutoPrep电导检测和脉冲安培检测离子色谱法测定不同土壤样品中的碘，两种方法的检测结果基本一致。方法在提供了稳定的系统空白的同时，还具备自动化程度高、操作简单、重现性好、灵敏度高、系统稳定、节约时间、成本低廉和对环境友好等多方面特点，适合于大批量土壤普查中碘的分析。  相似文献   

楚雄龙岗地区超级不整合与金成矿     

郑明秋  谢先柏  李才先 《云南地质》2007,26(4):397-403

龙岗地区陇川运动-华力西运动间造成整个古生代地层缺失，中上三叠统直接覆于下元古界哀牢山岩群、大红山岩群等基底岩系之上，本文称为“超级不整合”。华力西期-喜马拉雅期历次地壳事件在“超级不整合”接触带形成“矿质”的“浪淘砂”式、叠次‘堆积’作用，对该区金成矿有决定性作用，先后发现小水井与大龙潭两个典型金矿床。前者为“地下水热卤水溶滤中低温热液蚀变角砾岩微粒浸染型金矿床”，可类比为“卡林型”；后者为“原生沉积地下热水溶滤中低温热液蚀变砂砾岩微粒-粗粒型金矿床”，为该区首次发现的新类型。  相似文献   

镇康芦子园铅锌矿床特征及成因   总被引：7，自引：0，他引：7  

董文伟  陈少玲 《云南地质》2007,26(4):404-410

芦子园铅锌矿产于镇康复背斜核部寒武系沙河厂组大理岩、板岩、片岩地层中，沿背斜轴部产生的断层及层间破碎带是主要的容矿构造，成矿物质来源于地层、酸性及基性岩浆热液，矿床成因为沉积-热液改造叠生型铅锌矿床。  相似文献   

A Parametric Approach for Dealing with Compositional Rounded Zeros   总被引：2，自引：0，他引：2  

Javier Palarea-Albaladejo  Josep A. Martín-Fernández  Juan Gómez-García 《Mathematical Geology》2007,39(7):625-645

In this work, a parametric approach for replacing data below the detection limit, also known as rounded zeros, in compositional data sets is proposed. Compositional rounded zeros correspond to small proportions of some whole that cannot be reliably detected by the analytical instruments under given operating conditions. This kind of zeros appear frequently in the data collection process in geosciences. They must be treated in an adequate way before some multivariate analysis can be applied. Our procedure results from a modification of the Expectation-Maximization (EM) algorithm and is based on the additive log-ratio transformation. Its coherence with the nature of compositional data and with basic operations in the simplex sample space is checked. Using real data sets, we find that this approach improves other parametric and non-parametric techniques for compositional rounded zeros.  相似文献   

2-D Crustal thermal structure along Thuadara-Sindad DSS profile across Narmada-Son lineament,central India   总被引：1，自引：0，他引：1  

S. N. Rai  S. Thiagarajan 《Journal of Earth System Science》2007,116(4):347-355

Central India is traversed by a WSW-ENE trending Narmada-Son lineament (NSL) which is characterized by the presence of numerous hot springs, feeder dykes for Deccan Traps and seismicity all along its length. It is divided in two parts by the Barwani-Sukta Fault (BSF). To the west of this fault a graben exists, whereas to the east the basement is uplifted between Narmada North Fault (NNF) and Narmada South Fault (NSF). The present work deals with the 2-D thermal modeling to delineate the crustal thermal structure of the western part of NSL region along the Thuadara-Sindad Deep Seismic Sounding (DSS) profile which runs almost in the N-S direction across the NSL. Numerical results of the model reveal that the conductive surface heat flow value in the region under consideration varies between 45 and 47mW/m². Out of which 23mW/m² is the contribution from the mantle heat flow and the remaining from within the crust. The Curie depth is found to vary between 46 and 47 km and is in close agreement with the earlier reported Curie depth estimated from the analysis of MAGSAT data. The Moho temperature varies between 470 and 500°C. This study suggests that this western part of central Indian region is characterized by low mantle heat flow which in turn makes the lower crust brittle and amenable to the occurrence of deep focused earthquakes such as Satpura (1938) earthquake.  相似文献   

一种求解旅行商问题的改进蚁群算法     

汤可宗  江新姿  张磊  高尚 《华东地质学院学报》2007,30(4):387-391

蚁群算法作为一种新型的优化算法,具有很强的适应性和鲁棒性,已广泛的应用于系统控制、人工智能、模式识别等工程领域。由于蚁群算法在搜索过程中易于陷入局部最优解,存在着加速收敛和早熟停滞现象的矛盾。文章针对这些问题,在基本蚁群算法的基础上,从参数的动态调整、信息量的更新规则、局部搜索策略进行相应的改进,引入信息素平滑机制,以求在加快收敛和防止早熟停滞之间取得较好的平衡。旅行商问题的仿真表明:改进后的蚁群算法具有较好的收敛性和稳定性,能够克服算法中早熟和停滞现象的过早出现。  相似文献   

Investigation of waste disposal areas using electrical methods: a case study from Chania,Crete, Greece   总被引：1，自引：0，他引：1  

Pantelis Soupios  Ilias Papadopoulos  Maria Kouli  Irene Georgaki  Filippos Vallianatos  Eleni Kokkinou 《Environmental Geology》2007,51(7):1249-1261

A geophysical investigation of a landfill area was conducted as inextricable phase of a preliminary geotechnical, geological and hydrogeological study of the area under investigation. Electrical resistivity tomography (ERT), one of the most promising prospecting techniques mainly concerning its effective contribution to resolve several environmental problems, was applied for the geophysical modeling. ERT is a robust imaging method the theory and implementation of which are well documented in geophysical research literature. The survey site is located in Akrotirion Peninsula, about 7 km east of Chania city in Crete I. The geological setting comprises Trypalion limestones, marly limestones and a clayed weathered layer. Cavities are also identified at various scales which are recent tectono-karstic voids. Due to the above-mentioned geological singularity and in the light of the requirement for an environmentally safe construction of the landfill, an ERT survey was carried out. Specifically, seven geoelectrical tomographies were conducted reaching the prospecting depth of 36 m. The resulted images conduced, to overcome geotechnical problems since the spatial distribution of karstic voids was determined, to plan the future sites for waste disposal as the geological conditions were studied in detail and to reliably estimate the thickness of the already deposited wastes. The resulted images were confirmed using available borehole logs and ambient noise measurements.  相似文献   

基于R树的分布式并行空间索引机制研究   总被引：2，自引：0，他引：2  

赵园春  李成名  赵春宇 《地理与地理信息科学》2007,23(6):38-41,81

为提高分布式并行计算环境下海量空间数据管理与并行化处理的效率,基于并行空间索引机制的研究,设计一种多层并行R树空间索引结构。该索引结构以高效率的并行空间数据划分策略为基础,以经典的并行计算方法论为依据,使其结构设计在保证能够获得较好的负载平衡性能的前提下,更适合于海量空间数据的并行化处理。以空间范围查询并行处理的系统响应时间为性能评估指标,通过实验证明并行空间索引结构具有设计合理、性能高效的特点。  相似文献   

A New Approach for Border Detection of the Dumluca (Turkey) Iron Ore Area: Wavelet Cellular Neural Networks     

A. Muhittin Albora  Abdullah Bal  Osman N. Ucan 《Pure and Applied Geophysics》2007,164(1):199-215

Anomaly analysis is used for various geophysics applications such as determination of geophysical structure's location and border detections. Besides the classical geophysical techniques, artificial intelligence based image processing algorithms have been found attractive for geophysical anomaly analysis. Recently, cellular neural networks (CNN) have been applied to geophysical data and satisfactory results are reported. CNN provides fast and parallel computational capability for geophysical image processing applications due to its filtering structure. The behavior of CNN is defined by two template matrices that are adjusted by a properly supervised learning algorithm. After training stage for geophysical data, Bouguer anomaly maps can be processed and analyzed sequentially. In this paper, CNN learning and processing capability have been improved, combining Wavelet functions and backpropagation learning algorithms. The new architecture is denoted as Wavelet-Cellular Neural networks (Wave-CNN) and it is employed to analyze Bouguer anomaly maps which are important to extract useful information in geophysics. At first, Wave-CNN performance is tested on synthetic geophysical data, which are created by a computer environment. Then, Bouguer anomaly maps of the Dumluca iron ore field have been analyzed and results are reported in comparison to real drilling results.  相似文献   

Time–frequency representation of earthquake accelerograms and inelastic structural response records using the adaptive chirplet decomposition and empirical mode decomposition     

P.D. Spanos  A. Giaralis  N.P. Politis 《Soil Dynamics and Earthquake Engineering》2007,27(7):675-689

In this paper, the adaptive chirplet decomposition combined with the Wigner-Ville transform and the empirical mode decomposition combined with the Hilbert transform are employed to process various non-stationary signals (strong ground motions and structural responses). The efficacy of these two adaptive techniques for capturing the temporal evolution of the frequency content of specific seismic signals is assessed. In this respect, two near-field and two far-field seismic accelerograms are analyzed. Further, a similar analysis is performed for records pertaining to the response of a 20-story steel frame benchmark building excited by one of the four accelerograms scaled by appropriate factors to simulate undamaged and severely damaged conditions for the structure. It is shown that the derived joint time–frequency representations of the response time histories capture quite effectively the influence of non-linearity on the variation of the effective natural frequencies of a structural system during the evolution of a seismic event; in this context, tracing the mean instantaneous frequency of records of critical structural responses is adopted.The study suggests, overall, that the aforementioned techniques are quite viable tools for detecting and monitoring damage to constructed facilities exposed to seismic excitations.  相似文献