平阴县土壤中重金属元素异常成因研究   总被引：1，自引：0，他引：1  

代杰瑞  庞绪贵  王红晋  曾宪东  胡雪平  李肖鹏 《山东国土资源》2009,25(7):37-41

通过对平阴县周边及其西部农田区采样调查，平阴县周边元素异常具有异常衬度较高，富集系数大等特征，西部农田区异常具有各元素套合关系好，多数异常衬度不高，富集系数小的特点。结果表明，西部农田区异常是以As，Cd为主要成分的异常，元素含量与SiO2，Al2O3，Fe2O3等常量组分间具有显著的相关性，随SiO2含量的增加而降低，随Al2O3，Fe2O3含量的增加而增加，说明土壤常量组分及其所决定的土壤质地是导致异常形成的主要因素；而平阴城区异常是以S，Hg，As，Zn，Mn等元素为主的异常，是典型的人为综合因素（化工烟尘、工厂污水、生活垃圾）产生的异常。  相似文献   

九龙江河口区表层沉积物重金属元素分布特征及其沉积环境   总被引：1，自引：0，他引：1  

和转  胡毅  陈坚 《台湾海峡》2009,28(4)

通过对九龙江河口表层沉积物的重金属元素含量、沉积物粒度等要素进行分析,结合相关与聚类分析等统计手段,探讨了九龙江河口地区的沉积环境与重金属元素含量特征的关系.结果表明,即使在沉积环境复杂的河口地区,重金属含量分布与沉积物粒度仍存在明显的对应关系.受沉积动力影响,不同的重金属元素分布在九龙江河口地区表现出较大差异,而嵩屿至屿仔尾一带呈带状南北向展布的重金属相对高值条带值得引起注意.  相似文献   

多期构造变形事件对吉林南部大横路Cu- Co矿床富集成矿的制约     

田忠华  刘福来  刘超辉  朱志勇  王慧宁 《地质学报》2023,97(11):3673-3695

钴矿是重要的战略性金属矿产资源之一,对其成矿作用(如构造与成矿的关系)进行深入的研究能为前期指导找矿提供理论依据。本文对中国东部吉林白山市三道沟镇三岔河村大横路Cu-Co矿开展了相关工作,包括野外构造解析、钻孔-岩芯资料分析、钻孔薄片综合矿物分析系统(TIMA)实验和区域相关岩石年代学等。构造解析显示大横路Cu-Co矿围岩变形包括层片交切、S₁面理和褶劈理等构造要素。钻孔-岩芯资料分析矿区发育大量F₂紧闭褶皱、逆冲断层及断层相关褶皱、倒转褶皱F₂等。钻孔、探槽薄片样品TIMA实验显示含Co流体大量富集于低角度逆冲断裂、倒转褶皱韧性剪切域和断层相关褶皱转折端处。这些工作显示走向为NE的低角度逆冲断裂及断层相关褶皱对大横路Cu-Co矿的富集起到关键的控制作用。相关年代学工作,结合前人研究及大量区域地质资料表明:(1)矿区内逆冲断层及褶皱等控矿构造要素为古元古代构造事件的产物;(2)中生代构造事件对成矿作用的制约(Cu-Co矿的再富集)可能来自于白垩纪大规模的伸展作用。  相似文献   

Determination of picomolar iron in seawater by double Mg(OH)₂ precipitation isotope dilution high-resolution ICPMS     

Jingfeng Wu   《Marine Chemistry》2007,103(3-4):370-381

A low-blank pre-concentration procedure is described for the analysis of picomolar iron (Fe) in seawater by isotope dilution high-resolution inductively coupled plasma mass-spectrometry (HR-ICPMS). The procedure uses a two-step Mg(OH)₂ co-precipitation procedure to extract Fe from a 50 ml seawater sample into a 100 μl 4% nitric acid (HNO₃) solution followed by HR-ICPMS measurement. The high pre-concentration ratio ( 500:1) achieved by the procedure minimizes the Fe blank due to ICPMS instrumental Fe background and results in a detection limit of  2 pM and a precision of  4% at the 50 pM Fe level. The measurement of a low-Fe seawater sample spiked with gravimetric Fe standard shows that the method can clearly distinguish 0.01 nM Fe from 0.02 nM Fe in seawater with high accuracy. The method is demonstrated by the analysis of dissolved Fe in the equatorial Pacific Ocean.  相似文献   

陕西省泾惠渠灌区土壤重金属地质累积指数评价     

易秀  谷晓静  侯燕卿  刘秀花  谢娟 《西安地质学院学报》2010,(3):288-291

通过对陕西省泾惠渠灌区现场调查及土壤样品的采集,分析了灌区土壤中Hg、Cd、Cr、Pb、As、Cu、Zn等7种元素的含量,应用地质累积指数对灌区土壤进行了评价。结果表明：从区域分布看,阎良区、临潼区、高陵县所属采样点污染较严重;Hg污染最严重,地质累积指数为1.007～3.117,58%的采样点级别为3级,属中度污染到强污染,38%的采样点级别为2级,属中度污染;Zn污染程度次之,地质累积指数为-0.407～1.644,71%的采样点级别为1级,属无污染到中污染;Cd污染变异程度最大,地质累积指数为-2.705～3.312,70%的采样点级别0级,属无污染,但个别采样点达到了强污染;Cu的地质累积指数为-0.535～0.421,Pb为-1.119～-0.144,Cr为-1.005～-0.458,As为-0.562～0.077,除个别点外这些重金属污染级别皆为0级,属无污染。  相似文献   

Concentrations and contamination trends of heavy metals in the sediment cores of Taihu Lake,East China,and their relationship with historical eutrophication   总被引：2，自引：0，他引：2  

Zhangdong Jin  Hangxin Cheng  Li Chen  Xiangdong Li  Guangwei Zhu  Guangmin Zhuang  Na Qian 《中国地球化学学报》2010,29(1):33-41

To assess the contamination trends and potential bio-availability of sediment-bound heavy metals, concentrations of heavy metals in acid-leaching fraction and in bulk sediments from the two typical bays (the Meiliang Bay and Xuhu Bay) of the Taihu Lake, East China, were studied. Pb and Zn showed elevated concentrations in the sediments from both areas, although sedimentation history and degree of pollution are different between the two bays. In the Meiliang Bay, both Pb and Zn pollutions started in the late 1970’s, the same time as the beginning of eutrophication of the lake, while the in the Xuhu Bay the metal contamination started since recent 10 years. The concentrations of acid-leachable Pb in the sediments from the Meiliang Bay are correlated with the historical eutrophication process. Before the eutrophication and heavy metal pollution, the chemical properties of the lake sediments were the same as the source compositions of the Xiashu loess. Both Pb and Zn in the sediments mainly occur in leachable forms by nitric or hydrochloric acid, whilst most of Cu is in residual fraction. The results indicate that both Pb and Zn may have higher mobility and bioavailability in water and biology than Cu.  相似文献   

Heavy metal concentrations in soils and plants in the vicinity of Arufu lead-zinc mine,Middle Benue Trough,Nigeria     

Nganje T.N.  Adamu C.I.  Ukpong E.E. 《中国地球化学学报》2010,29(2):167-174

This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from cul-tivated farmlands in and around the mine, the unmineralized site and a nearby forest (the control site). The samples were analyzed for heavy metals (Fe, Zn, Mn, Cu, Pb, Cr and Cd) by Atomic Absorption Spectrophotometry (AAS). The physical properties of soils (pH and LOI) were also measured. Results showed that soils from cultivated farm-lands have neutral pH values (6.5-7.5), and low organic matter contents (10%). Levels of Zn, Pb and Cd in culti-vated soils were higher than the concentrations obtained from the control site. These heavy metals are most probably sourced from mining and agricultural activities in the study area. Heavy metal concentrations measured in plant parts decreased in the order of rice leavescassava tuberspeelings. In the same plant species, metal levels decreased in the order of ZnFeMnCuPbCrCd. Most heavy metals were found in plant parts at average concentrations normally observed in plants grown in uncontaminated soil, however, elevated concentrations of Pb and Cd were found in a few cassava samples close to the mine dump. A stepwise linear regression analysis identified soil metal contents, pH and LOI as some of the factors influencing soil-plant metal uptake.  相似文献   

攀枝花市大气降尘的地球化学特征     

蒋实  张成江  徐争启  徐进勇 《物探化探计算技术》2010,32(1):84-89

运用ICP-MS和ICP-OES分析了攀枝花市不同时段不同地点大气降尘中重金属元素含量,并对大气降尘中重金属的地球化学特征进行了分析,得出以下结论:①攀枝花市大气尘中As、Co、Mn、Pb、Ti、V的含量,与四川省其他城市相比均偏高,Zn的含量相对较低;②Cd、Mn、Pb主要分布在冶炼区和石灰石矿区,Co、Cu、Ti主要分布在石灰石矿区,Cr和V主要分布在冶炼区,As在仁和河富集较为富集,Zn集中在排土场附近,Fe集中在冶炼区和煤矿区;③除Pb外,其余十种元素旱季含量基本都高于雨季,而雨季Pb的含量却明显高于旱季。通过主成份分析,得出了在攀枝花市大气降尘中,重金属元素的来源主要为矿山污染和开采过程中产生的废水、废气。  相似文献   

土壤铅含量高光谱遥感反演中波段选择方法研究   总被引：7，自引：0，他引：7  

温健婷  张霞  张兵  赵冬 《地球科学进展》2010,25(6):625-629

利用高光谱遥感数据进行了南京郊外土壤重金属元素铅的含量反演,由于高光谱数据波段众多,波段选择或变换至关重要。比较了基于次贪婪的前向选择模型的最小角度拟合和基于遗传算法进行波段选择的最小二乘和偏最小二乘拟合,结果发现基于遗传算法的偏最小二乘反演结果优于全波段的偏最小二乘,表明波段选择在高光谱反演重金属中是有益的。尽管采取了波段选择后的各方法在反演时均能达到70%以上的训练精度,但因遗传算法搜索的解空间范围更宽广,使得基于遗传算法的偏最小二乘优于前向选择模型的最小角度拟合。最后还比较了基于遗传算法的普通最小二乘和偏最小二乘拟合,结果表明偏最小二乘更优,因此在高光谱反演重金属含量当中,偏最小二乘精度较高,而在波段选择方法中,遗传算法更优。  相似文献   

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究     

黄健敏  黄润秋  焦赳赳  段海澎 《地下水》2010,32(6):16-20

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。  相似文献