颗粒状纳米碳酸钡锶钙的研制     

王其富  王小霞  罗积润  赵青兰 《海洋学报》2010,32(10):7383-7389

介绍一种气-液相合成技术合成氧化物阴极用三元碳酸盐,研究沉淀温度、浓度及搅拌速率对合成碳酸钡锶钙结晶形貌的影响,分析其结晶过程.通过优化合成溶液温度及合成浓度,控制碳酸盐的成核和生长速率,合成了一种颗粒状纳米三元碳酸盐,并进行直流发射测试.实验表明,这种纳米碳酸盐能明显提高氧化物阴极的发射性能.  相似文献   

Nitrous oxide production and denitrification rates in estuarine intertidal saltmarsh and managed realignment zones     

Martin S.A. Blackwell  Sirwan Yamulki  Roland Bol 《Estuarine, Coastal and Shelf Science》2010

Increasing concerns over habitat loss and rising costs of sea defence maintenance due to rising sea levels, has seen increases in the practice of managed realignment and reflooding of former reclaimed areas of intertidal saltmarsh and mudflat around the world. These practices are taking place with little knowledge of their impact on soil biogeochemical processes. Rates of denitrification (using the acetylene inhibition technique) and nitrous oxide (N₂O) production were measured from a long-established saltmarsh (SM) and an adjacent, recently re-flooded managed realignment (MR) site comprising former arable land in the estuary of the River Torridge, Devon, UK. Incubations were carried out in closed chambers in which patterns of tidal flooding were simulated automatically. Measurements were made during periods of flood and non-flood over a total of four tidal inundations with estuarine water. During the latter two flooding episodes floodwater was amended with nitrate (NO₃⁻). Nitrous oxide production in the SM soil generally was lower than in the MR soil, with mean values and standard errors over the whole incubation of 0.27 ± 0.16 mg N₂O-N m⁻² h⁻¹ and 0.65 ± 0.15 mg N₂O-N m⁻² h⁻¹ respectively. Denitrification rates demonstrated a similar trend although generally were an order of magnitude higher than N₂O production, with mean rates and standard errors of 2.88 ± 1.12 mg N₂O-N m⁻² h⁻¹ in the SM soil and 3.39 ± 1.16 mg N₂O-N m⁻² h⁻¹ in the MR soil. The data suggest that both soils are net sinks for NO₃⁻ and net sources for N₂O. Both patterns of tidal inundation and floodwater chemistry affect the process rates in each soil differently. The impact of flooding with NO₃⁻ – amended water was greater on the SM soil than the MR soil, and it is likely that decomposing vegetation buried in the accreting sediments following reflooding at the MR site were supplying a source of N in the soil, and so process rates were less dependent upon external supplies. The act of managed realignment in intertidal zones could therefore result in an increase in mean production of N₂O in intertidal zones, at least in the short term.  相似文献   

Nitric oxide profiles measured in situ during the Globus '85 campaign     

W. A. Matthews  Y. Kondo  P. Fabian  B. C. Krüger 《Journal of Atmospheric Chemistry》1989,8(3):229-240

Nitric oxide profiles obtained from three flights of chemiluminescent instruments during the Globus '85 campaign held in France in the autumn of 1985 are reported. When the profile obtained in the early morning of 20 September is compared with the flight made the previous afternoon, an average morning to midday NO ratio of 0.7 for the region between 26 and 33 km is obtained. This value is in good agreement with theoretical studies involving the photolysis of N₂O₅ and the establishment of the NO₂–NO equilibrium.  相似文献   

Intercomparison of NO column measurements during MAP/GLOBUS 1985     

R. L. McKenzie  W. A. Matthews  Y. Kondo  R. Zander  Ph. Demoulin  P. Fabian  D. G. Murcray  F. J. Murcray  O. Lado-Bordowsky  C. Camy-Peyret  H. K. Roscoe  J. A. Pyle  R. D. McPeters 《Journal of Atmospheric Chemistry》1988,7(4):353-367

Column measurements of nitric oxide were made using several techniques during the MAP/GLOBUS campaign in France in September 1985. The data sets are nearly co-located and simultaneous, therefore allowing a valid intercomparison of the various measurement methods. The range of altitudes sampled differs from instrument to instrument. This complicates the comparison because the data sets are to some extent complementary. The NO distributions apparently vary significantly from day to day, and possibly over shorter timescales. Changes in dynamics may be responsible for these variations. The results from the instruments which measure in the infrared and the ultraviolet are self-consistent, and show good agreement with photochemical predictions. On 19 September, when the intercomparison was made, the profile measured by the in-situ chemiluminescent instrument differed significantly from the predicted profile, and the measured columns were generally higher.  相似文献   

攀西地区铁钛氧化物矿物的显微结构     

李朝晖  彭志忠 《地球科学》1988,(1)

本文用矿石显微镜及单晶X射线分析方法,研究了攀枝花—西昌地区铁钛氧化物矿物的显微结构共生组合特点、各出溶相间的关系和分布方位以及不同岩石和矿石显微结构共生组合上的差异。业已查明它们受岩浆旋回和岩石类型所控制。本文指出了磁铁矿-钛铁晶石固溶体显微出溶结构可能是拐点分解经调制结构后的终期产物。  相似文献   

游离氧化铁形态转化对红粘土工程性质的影响   总被引：6，自引：5，他引：6  

孔令伟  罗鸿禧 《岩土力学》1993,14(4):25-39

本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。  相似文献   

Studies of Nitrous Oxide Emission from Farmlands in North China     

Wang Shaobin  Su Weihan  Song Wenzhi  Zeng Jianghai  Zhang Yuming 《大气科学进展》1993,10(4):489-496

Measurements of nitrous oxide emission from agricultural lands were conducted. The results show that nitrous oxide fluxes on several soils are at the range of 2-60 μg . N / m2 h. Factors influencing the production rates of nitrous oxide from the soils, such as soil temperature, soil moisture and fertilization, are discussed. The calculated amount of nitrous oxide emission from China farmlands is 9.8 × 107 Kg . N per year, which accounts for about 10% of the total source strength in China areas.  相似文献   

四川紫色水稻土氧化铁的分异     

徐建忠 《山地学报》1993,(4)

以岷江冲积物、黄壤残积物发育成的水稻土为对照,研究了紫色砂岩泥岩母质发育成的紫色水稻土氧化铁的形态及其含量和转化。揭示了紫色水稻土具有无定形铁含量,铁活化度较高,氧化铁的转化作用较弱等独特的发生特性。  相似文献   

由MgMn_2O_4制备新型离子筛吸附剂及其对锂的吸附性质   总被引：1，自引：0，他引：1  

张绍成  董丽春 《盐湖研究》1993,(1)

从Mg、Mn混合溶液制备了镁锰氧化物MgMn_2O_4,并由此制得新型离子筛氧化锰HMnO(Mg)。它在碱金属及碱土金属离子中对Li~+显示了很高的选择性,pH8时分配系数Kd值顺序为Li>>Ca>Mg>K>Na,可以从实际卤水中将Li~+选择性吸附,吸附容量达20.4mg/g,用稀HCI溶液易于将吸附的Lj~+洗脱并使吸附剂再生。经用卤水和HCI五次吸附——洗脱循环,Li~+吸附容量没有降低,洗脱率总是大于90％。  相似文献   

Trace gas measurements during aircraft flights in the tropopause region over Europe and North Africa     

M. Schmidt  R. Borchers  P. Fabian  G. Flentje  W. A. Matthews  A. Szabo  S. Lal 《Journal of Atmospheric Chemistry》1984,2(2):133-143

During aircraft flights in May 1981 from Munich (40°N) to north of the Spitsbergen Islands (82°N) and to Monrovia, Liberia (6°N), air samples were obtained in the altitude range of 8 to 11 km and during the ascents and descents near the airports. These samples have been analyzed for the trace gas mixing ratios of CH₄, CO and N₂O. The results of these analyses are presented and discussed.The results provide new evidence of tropospheric-stratospheric exchange events in the vicinity of the subpolar and subtropical tropopause foldings and possibly show a case of transport of CO-enriched air in the upper troposphere above the North Atlantic Ocean.  相似文献