Evolution of the fogwater composition in Strasbourg (France) from 1990 to 1999     

Pierre Herckes  Henri Wortham  Philippe Mirabel  Maurice Millet   《Atmospheric Research》2002,64(1-4)

The chemical composition of fogwater has been studied in the city of Strasbourg (France) from 1990 to 1999. During these years, fogwater samples have been collected and analysed for major ions and trace metals. This paper reports on the analysis of the collected dataset. The analysis revealed a significant decrease in acidity of approximately one pH unit over the course of the study. This decrease in acidity appears to be linked to a decrease in SO_2(g) and the resulting SO₄²⁻. Trace metal concentrations have also strongly decreased over the 10-year period. Pb concentrations, following the elimination of leaded gasoline, decreased by more than one order of magnitude.  相似文献   

Crustal structure of the Ruby Mountains and southern Carlin Trend region, Nevada, from magnetotelluric data     

Philip E. Wannamaker  William M. Doerner 《Ore Geology Reviews》2002,21(3-4)

We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings reside in three east–west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass, and Secret Pass latitudes). One short cross-line was also taken to assess an east–west structure to the north of the northern profile. Model resistivity cross-sections were derived from the MT data using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity–thickness product) from east to west. These increases are attributed to graphitization caused by Elko–Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, steeply dipping fault zones. The zones provide pathways to the lower crust for heterogeneous, upper crustal induced, electric current flow. Resistive core complex crust appears steeply bounded under the middle of the neighboring grabens and not to deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness (T_e) estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east–west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to nearby graphitic metasediments, with possible alteration by middle Tertiary magmatism. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (<1 vol.%) containing hypersaline brines and possible water-undersaturated crustal melts, residual to the mostly Miocene regional extension. The resistivity expression of the southern Carlin Trend (CT) in the Pinon Range is not a simple lineament but rather a family of structures attributed to Eocene intrusion, stratal deformation, and alteration/graphitization. Substantial reactivation or overprinting by core complex uplift or Basin–Range extensional events seems likely. We concur with others that the Carlin Trend may result in part from overlap of the large Eocene Northeast Nevada Volcanic Field with Precambrian–Paleozoic deep-water clastic source rocks thickening abruptly to the west of the Pinon Range, and projecting to the north–northwest.  相似文献   

天山西部中山带积雪变化趋势与气温和降水的关系——以巩乃斯河谷为例   总被引：12，自引：9，他引：12  

张丽旭  魏文寿 《地理科学》2002,22(1):67-71

根据位于巩乃斯河谷的天山积雪雪崩研究站近30年来的年最大雪深、月平均气温、月降水量观测记录，用平均差值法、最小二乘法、自回归滑动平均法检验了天山西部中山带积雪、冷季降水、冷季平均气温的变化趋势，结果表明，天山西部中山带积雪呈增加趋势，近30年来年平均增加1.43%，与青藏高原、南极大陆及格陵兰冰盖表面积雪积累增加相一致。天山西部中山带冷季气温和降水的变化趋势也是增加的，其中冷季降水平年平均增加0．12％，而冷季气温升高了0．8℃，积雪与冷季气温之间存在着弱的负相关关系，而与冷季降水呈显著的正相关关系。积雪的增加主要是因为气候变暖引起的冷季降水的增加对积雪增加的贡献大于由于冷季气温升高而造成积雪减少的贡献的结果。  相似文献   

Extreme climate events over northern China during the last 50 years     

HAN Hui  GONG Daoyi 《地理学报》2003,13(4):469-479

Climate extremes for agriculture-pasture transitional zone, northern China, are analyzed on the basis of daily mean temperature and precipitation observations for 31 stations in the period 1956-2001. Analysis season for precipitation is May-September, i.e., the rainy season. For temperature is the hottest three months, i.e., June through August. Heavy rain events, defined as those with daily precipitation equal to or larger than 50 mm, show no significant secular trend. A jump-like change, however, is found occurring in about 1980. For the period 1980-1993, the frequency of heavy rain events is significantly lower than the previous periods. Simultaneously, the occurring time of heavy rains expanded, commencing about one month early and ending one month later. Long dry spells are defined as those with longer than 10 days without rainfall. The frequency of long dry spells displays a significant (at the 99% confidence level) trend at the value of +8.3%/10a. That may be one of the major causes of the frequent droughts emerging over northern China during the last decades. Extremely hot and low temperature events are defined as the uppermost 10% daily temperatures and the lowest 10% daily temperatures, respectively. There is a weak and non-significant upward trend in frequency of extremely high temperatures from the 1950s to the mid-1990s. But the number of hot events increases as much as twice since 1997. That coincides well with the sudden rise in mean summer temperature for the same period. Contrary to that, the frequency of low temperature events have been decreasing steadily since the 1950s, with a significant linear trend of -15%/10a.  相似文献   

Vertical Ozone Profile over Tibet Using Sage I and II Data   总被引：8，自引：0，他引：8  

Zou Han  Gao Yongqi 《大气科学进展》1997,14(4):505-512

ＶｅｒｔｉｃａｌＯｚｏｎｅＰｒｏｆｉｌｅｏｖｅｒＴｉｂｅｔＵｓｉｎｇＳａｇｅＩａｎｄＩＤａｔａ①ＺｏｕＨａｎ（邹捍）ａｎｄＧａｏＹｏｎｇｑｉ（郜永祺）ＩｎｓｔｉｔｕｔｅｏｆＡｔｍｏｓｐｈｅｒｉｃＰｈｙｓｉｃｓ，ＣｈｉｎｅｓｅＡｃａｄｅｍｙｏｆＳｃｉｅ...  相似文献   

NUMERICAL SIMULATION OF OZONE DISTRIBUTIONS AND ITS VARIATION MECHANISM_*     

Ren Chuansen  Zhou Xiuji  Li Weiliang  Qin Yu 《Acta Meteorologica Sinica》1997,11(2):129-142

A 2-D global chemistry-transport model is set up in this paper.The model simulates the atmospheric ozone distributions well with specified dynamical conditions.The analysis of ozone variation mechanism shows that ozone is chemically in quasi-equilibrium except for the polar night region where the variation of ozone concentration is under the control of dynamical processes,that the oxygen atoms which produce ozone are mainly provided by the photolysis of O₂ in the upper stratosphere and by the photolysis of NO₂ in the lower stratosphere and the troposphere.and that the ozone is destroyed mainly by NO_x:the reactions between NO_x and O₃ and the odd oxygen cycle contribute 80% to more than 90% of the ozone destruction.  相似文献   

Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994     

TH. Blumenstock  H. Fisher  A. Friedle  F. Hase  P. Thomas 《Journal of Atmospheric Chemistry》1997,26(3):311-321

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.  相似文献   

First-Order Chemistry in the Surface-Flux Layer     

L. Kristensen  C. E. Andersen  H. E. Jørgensen  P. Kirkegaard  K. Pilegaard 《Journal of Atmospheric Chemistry》1997,27(3):249-269

We have discussed the behavior of a non-conserved scalar in the stationary, horizontally homogeneous, neutral surface-flux layer and, on the basis of conventional second-order closure, derived analytic expressions for flux and for mean concentration of a gas, subjected to a first-order removal process. The analytic flux solution showed a clear deviation from the constant flux, characterizing a conserved scalar in the surface-flux layer. It decreases with height and is reduced by an order of magnitude of the surface flux at a height equal to about the typical mean distance a molecule can travel before destruction. The predicted mean concentration profile, however, shows only a small deviation from the logarithmic behavior of a conserved scalar. The solution is consistent with assuming a flux-gradient relationship with a turbulent diffusivity corrected by the Damköhler ratio, the ratio of a characteristic turbulent time scale and the scalar mean lifetime. We show that if we use only first-order closure and neglect the effect of the Damköhler ratio on the turbulent diffusivity we obtain another analytic solution for the profiles of the flux and the mean concentration which, from an experimental point of view, is indistinguishable from the first analytic solution. We have discussed two cases where the model should apply, namely NO which, by night, is irreversibly destroyed by interaction with mainly O₃ and the radioactive ²²⁰Rn. Only in the last case was it possible to find data to shed light on the validity of our predictions. The agreement seemed such that a falsification of our model was impossible. It is shown how the model can be used to predict the surface flux of ²²⁰Rn from measured concentration profiles.  相似文献   

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls     

W. J. Collins  D. S. Stevenson  C. E. Johnson  R. G. Derwent 《Journal of Atmospheric Chemistry》1997,26(3):223-274

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.  相似文献   

Water-quality trends in White Rock Creek Basin from 1912-1994 identified using sediment cores from White Rock Lake reservoir, Dallas, Texas   总被引：2，自引：0，他引：2  

Peter C. Van Metre  Edward Callender 《Journal of Paleolimnology》1997,17(2):239-239

Historical trends in selected water-quality variables from 1912 to 1994 in White Rock Creek Basin were identified by dated sediment cores from White Rock Lake. White Rock Lake is a 4.4-km² reservoir filled in 1912 and located on the north side of Dallas, Texas, with a drainage area of 259 km². Agriculture dominated land use in White Rock Creek Basin before about 1950. By 1990, 72% of the basin was urban. Sediment cores were dated using cesium-137 and core lithology. Major element concentrations changed, and sedimentation rates and percentage of clay-sized particles in sediments decreased beginning in about 1952 in response to the change in land use. Lead concentrations, normalized with respect to aluminum, were six times larger in sediment deposited in about 1978 than in pre-1952 sediment. Following the introduction of unleaded gasoline in the 1970s, normalized lead concentrations in sediment declined and stabilized at about two and one-half times the pre-1952 level. Normalized zinc and arsenic concentrations increased 66 and 76%, respectively, from before 1952 to 1994. No organochlorine compounds were detected in sediments deposited prior to about 1940. Concentrations of polychlorinated biphenyls (PCB) and DDE (a metabolite of DDT) increased rapidly beginning in the 1940s and peaked in the 1960s at 21 and 20 µg kg^-1, respectively, which is coincident with their peak use in the United States. Concentrations of both declined about an order of magnitude from the 1960s to the 1990s to 3.0 and 2.0 µg kg^-1, respectively. Chlordane and dieldrin concentrations increased during the 1970s and 1980s. The largest chlordane concentration was 8.0 µg kg^-1 and occurred in a sediment sample deposited in about 1990. The largest dieldrin concentration was 0.7 µg kg^-1 and occurred in the most recent sample deposited in the early 1990s. Agricultural use of chlordane and dieldrin was restricted in the 1970s; however, both were used as termiticides, and urban use of chlordane continued at least until 1990. Recent use of dieldrin and aldrin, which degrades to dieldrin, has not been reported; however, increasing trends in dieldrin since the 1970s suggest recent urban use could have occurred.  相似文献