泡沫塑料吸附分离富集-电感耦合等离子体质谱法测定稀土矿石中的镓   总被引：1，自引：1，他引：0  

董学林  何海洋 《岩矿测试》2016,35(1):42-47

采用电感耦合等离子体质谱法(ICP-MS)测定稀土矿石中的镓,高含量的稀土元素会造成严重的质谱干扰。本文采用聚氨酯泡沫塑料在6 mol/L盐酸介质中吸附样品溶液中的镓后,以0.5 mol/L氯化铵水浴加热解脱30 min,镓的吸附-解脱效率超过99%,稀土元素等干扰物质基本不进入解脱液中,即在富集镓的同时实现了镓与基体元素的高效分离,降低了质谱干扰。本方法检出限低(0.022μg/g),经土壤及水系沉积物标准物质验证,镓的测定值与标准值吻合(绝对偏差为0.38%~4.70%),实际稀土矿石样品的加标回收率为94.1%~100.6%,精密度(RSD)低于4%(n=12),可应用于分析一般地质样品以及稀土矿石中的镓。  相似文献   

利用微波等离子体炬四极杆质谱在线测定稀土矿样中的多种稀土元素     

初晨  张瑛  王尚贤  周润芝  蒋涛  朱志强  卢爱民 《岩矿测试》2016,35(5):468-474

随着稀土的应用越来越广泛,开发稀土元素的快速在线检测技术已日趋成为行业发展的需求。本文以微波等离子体炬(MPT)为离子源,以四极杆质谱仪(QMS)作为质量分析器建立了一种快速、直接检测水样中稀土元素的质谱检测方法,并将其应用于分析稀土矿样中的多种稀土元素。研究表明,应用MPT-QMS测定水样中的钇、镧、铈、钕、铕五种稀土元素,检出限(LOD)可达11.0~60.5μg/L,测定范围为50~1000μg/L。当分析固体稀土矿样时,样品经酸溶处理后通过气动雾化形成气溶胶,再进行冷却干燥,气溶胶由MPT的中心管道进入等离子体中,产生稀土元素复合离子,再引入QMS中进行分析,即可以定量地测定矿样中稀土元素的含量。同一样品用电感耦合等离子体质谱(ICP-MS)进行对比实验,两者的检测结果在数量级上接近,证明了MPTQMS方法在半定量的意义下是准确、可靠的,因而这种快速的检测方法可发展成为水体中金属元素的现场分析方法,应用于环境水、生活水质量在线监测等领域。  相似文献   

三稀矿产资源新兴产业发展及政策建议     

周园园 《地质论评》2016,62(S1):13-14

三稀矿产资源是战略性新兴产业发展的基础原料,广泛应用在国防、航天、高端电子设备、核工业、发光材料等高精尖技术领域。本文在系统收集国内外三稀矿产资源生产、消费领域、价格以及进出口资料的基础上,提出了促进三稀矿产资源新兴产业发展的政策建议  相似文献   

The Upstream “Strong Signals” of the Water Vapor Transport over the Tibetan Plateau during a Heavy Rainfall Event in the Yangtze River Basin   总被引：2，自引：0，他引：2  

Yang Zhao  Xiangde Xu  Bin Chen  Yinjun Wang 《大气科学进展》2016,33(12):1343-1350

A heavy rainfall event that occurred over the middle and lower reaches of the Yangtze River Basin(YRB) during July11–13 2000 is explored in this study. The potential/stream function is used to analyze the upstream "strong signals" of the water vapor transport in the Tibetan Plateau(TP). The studied time period covers from 2000 LST 5 July to 2000 LST 15 July(temporal resolution: 6 hours). By analyzing the three-dimensional structure of the water vapor flux, vorticity and divergence prior to and during the heavy rainfall event, the upstream "strong signals" related to this heavy rainfall event are revealed. A strong correlation exists between the heavy rainfall event in the YRB and the convective clouds over the TP. The "convergence zone" of the water vapor transport is also identified, based on correlation analysis of the water vapor flux two days and one day prior to, and on the day of, the heavy rainfall. And this "convergence zone" coincides with the migration of the maximum rainfall over the YRB. This specific coupled structure actually plays a key role in generating heavy rainfall over the YRB. The eastward movement of the coupled system with a divergence/convergence center of the potential function at the upper/lower level resembles the spatiotemporal evolution of the heavy rainfall event over the YRB. These upstream "strong signals" are clearly traced in this study through analyzing the three-dimensional structure of the potential/stream function of upstream water vapor transport.  相似文献   

湖南湘潭锰矿的地球化学特征及成矿机制     

史富强  朱祥坤  闫斌  刘燕群  张飞飞  赵妮娜  褚明恺 《岩石矿物学杂志》2016,35(3):443-456

湘潭锰矿床的锰矿层赋存于新元古代南华系(成冰系)大塘坡组底部含锰黑色页岩中,含锰矿物主要为菱锰矿。湘潭锰矿的Fe/Mn值低,Th/U、V/(V+Ni)和V/Cr值等地球化学指标显示其发育在氧化-次氧化的沉积环境中,暗示菱锰矿并不是由Mn~(2+)和CO_3~(2-)直接沉淀形成的。湘潭锰矿稀土元素含量高,稀土元素配分模式存在轻微的中稀土元素富集,具有明显的Ce正异常,这些特征指示湘潭锰矿含锰矿物是以锰氧化物或氢氧化物的形式沉淀的。同时,锰矿的碳同位素富集碳的轻同位素,说明有机物参与了菱锰矿的形成过程。综合分析表明,湘潭锰矿成矿过程可以分为沉淀和转化两个阶段:在氧化性的水体中,Mn以氧化物或氢氧化物的形式沉淀;在缺氧且富含有机物质的成岩环境中,Mn氧化物或氢氧化物被有机物还原而转化生成菱锰矿。这与华南地区其他几个典型的大塘坡式锰矿的成矿机制一致。  相似文献   

敦密断裂带白垩纪两期重要的变形事件   总被引：1，自引：1，他引：0  

孙晓猛  张旭庆  何松  王璞珺  郑涵  万阔  李多姿 《岩石学报》2016,32(4):1114-1128

本文报道了敦密断裂带糜棱岩中黑云母~(40)Ar/~(39)Ar定年结果和大规模走滑-逆冲断裂的几何学、运动学特征及其形成时代,以便揭示断裂带两期变形事件的构造属性。黑龙江省密山市花岗质糜棱岩中黑云母~(40)Ar/~(39)Ar加权平均年龄为132.2±1.2Ma,它是敦密断裂带经历伸展事件的冷却年龄,也是东北亚大陆边缘在早白垩世Hauterivian期-Albian期发生强烈区域伸展作用的产物。密山市至辽宁省清原县系列大型走滑-逆冲断层和断层相关褶皱揭示出在晚白垩世晚期-末期发生右旋走滑-逆冲事件,该事件规模大,影响范围广,导致整个断裂带遭受到强烈改造,形成对冲式断裂系统。将研究区走滑-逆冲断裂与山东省郯庐断裂带中段挤压构造对比,认为郯庐断裂带北段和中段在晚白垩世末期都发生了强烈的走滑-逆冲事件,它们具有相同的构造特征和构造属性。  相似文献   

Oil dispersal modelling: reanalysis of the Rena oil spill using open-source modelling tools     

HFE Jones  MTS Poot  JC Mullarney  WP de Lange 《新西兰海洋与淡水研究杂志》2016,50(1):10-27

ABSTRACT

Oil spill forecast modelling is typically used immediately after a spill to predict oil dispersal and promote mobilisation of more effective response operations. The aim of this work was to map oil dispersal after the grounding of the MV Rena on Astrolabe Reef and to verify the results against observations. Model predictions were broadly consistent with observed distribution of oil contamination. However, some hot spots of oil accumulation, likely due to surf-zone and rip current circulation, were not well represented. Additionally, the model was run with 81 differing wind conditions to show that the events occurring during the grounding represented the typical likely behaviour of an oil spill on Astrolabe Reef. Oil dispersal was highly dependent on prevailing wind patterns; more accurate prediction would require better observations of local wind patterns. However, comparison of predictions with observations indicated that the GNOME model was an effective low-cost approach.  相似文献   

Occurrence and Chemical Compositions of Amphiboles in Altered Dioritic Rocks of Laiwu Skarn‐Type Iron Deposit in West Shandong Area,China     

《Resource Geology》2018,68(4):425-445

The Laiwu Fe deposit is the largest skarn‐type deposit in West Shandong in China, with an estimated reserve of 290 Mt of iron ore. Here, we investigate the occurrence and chemical composition of amphiboles in altered dioritic rocks of this deposit. Three generations of amphibole group minerals were identified in these rocks. The first type (Type 1) is a hornblende with a generally euhedral crystal shape, 150–500 μm in size, and dominantly occurs in the host monzonite. The second type (Type 2) of hornblende occurs as fine grains (<100 μm) or concentric rims, less than 50 μm in thickness, around the Type 1 hornblende. The third type (Type 3) of amphibole is anhedral actinolite occurring along the boundary or the cracks of the Type 1 or 2 hornblende grains. The Type 1 hornblende has higher FeO (12.5–15.6 wt.%) and lower MgO contents (11.2–14.6 wt.%) than the Type 2 hornblende, which has an FeO content ranging from 8.8 to 10.5 wt.% and MgO content ranging from 14.2 to 17.1 wt.%. The Type 3 actinolite shows the lowest FeO (4.6–6.4 wt.%) and highest MgO (19.8–21.2 wt.%) contents. We infer that the Type 2 hornblende formed from Fe‐rich hydrothermal fluids released during rapid upwelling of the crystallizing magma. The fluids were relatively reduced and enriched in Fe. The Type 3 actinolite formed by coupled dissolution and reprecipitation, and its formation is one of the features denoting Fe‐enrichment events. Our study of these types of amphibole provides insights into the ore formation process.  相似文献   

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation     

A.A. Vorontsov  O.Yu. Perfilova  N.N. Kruk 《Russian Geology and Geophysics》2018,59(12):1640-1659

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.  相似文献   

准格尔煤田黑岱沟露天矿煤中稀土及微量元素的分配规律     

刘大锐  高桂梅  池君洲  王永旺  郭昭华 《地质学报》2018,92(11):2368-2375

对准格尔煤田黑岱沟露天矿煤的主量元素、稀土元素和微量元素含量和矿物组成进行了研究。结果表明,黑岱沟露天矿煤中稀土元素平均含量为248.12×10-6,约为中国煤平均值的2.83倍。LREE平均含量为236.66×10-6,HREE平均含量为11.46×10-6,LREE/HREE平均值为20.81,(La/Yb)N平均值为1.59,表明煤中LREE相对HREE富集。煤中部分稀土元素可能富集在勃姆石和黏土矿物中。稀土元素分配曲线δCeS变化区间(0.89～2.21)和δEuS中度亏损(0.46～0.86),验证了沉积环境在煤层形成演化过程中对煤中稀土元素输入的稳定性。黑岱沟煤层中微量元素明显偏高的有Ga、Pb、Se、Sr、Th 和Zr,这些元素的含量高于中国、中国华北晚古生代和美国煤的算术均值,也高于地壳克拉克值。  相似文献