To determine if Cu mediated reactions on atmospheric particles are important to HO2 chemistry in the ambient atmosphere, Cu molalities were calculated from measured Cu aerosol particle concentrations, mass and number size distribution data from a site in central Sweden. A comparison of characteristic times indicates that at low relative humidities the reaction is limited by the mass transport of gas phase HO2 to the particle surface and not by the chemical kinetics of the aqueous reaction. Comparison of half-lives for particle reactions and the gas phase destruction of HO2 to form H2O2 indicate that heterogeneous reactions on aerosol particles may have important consequences on the chemistry of HO2 and H2O2 in the troposphere. 相似文献
Three dating techniques for metamorphic minerals using the Sm–Nd, Lu–Hf and Pb isotope systems are combined and interpreted in context with detailed petrologic data from crustal segments in NW Namibia. The combination of isochron ages using these different approaches is a valuable tool to testify for the validity of metamorphic mineral dating. Here, PbSL, Lu–Hf and Sm–Nd garnet ages obtained on low- to medium-grade metasedimentary rocks from the Central Kaoko Zone of the Neoproterozoic Kaoko belt (NW Namibia) indicate that these samples were metamorphosed at around 550–560 Ma. On the other hand, granulite facies metasedimentary rocks from the Western Kaoko Zone underwent two phases of high-grade metamorphism, one at ca. 660–625 Ma and another at ca. 550 Ma providing substantial evidence that the 660–625 Ma-event was indeed a major tectonothermal episode in the Kaoko belt. Our age data suggest that interpreting metamorphic ages by applying a single dating method only is not reliable enough when studying complex metamorphic systems. However, a combination of all three dating techniques used here provides a reliable basis for geochronological age interpretation. 相似文献
The Anarak, Jandaq and Posht-e-Badam metamorphic complexes occupy the NW part of the Central-East Iranian Microcontinent and are juxtaposed with the Great Kavir block and Sanandaj-Sirjan zone. Our recent findings redefine the origin of these complexes, so far attributed to the Precambrian–Early Paleozoic orogenic episodes, and now directly related to the tectonic evolution of the Paleo-Tethys Ocean. This tectonic evolution was initiated by Late Ordovician–Early Devonian rifting events and terminated in the Triassic by the Eocimmerian collision event due to the docking of the Cimmerian blocks with the Asiatic Turan block.
The “Variscan accretionary complex” is a new name we proposed for the most widely distributed metamorphic rocks connected to the Anarak and Jandaq complexes. This accretionary complex exposed from SW of Jandaq to the Anarak and Kabudan areas is a thick and fine grain siliciclastic sequence accompanied by marginal-sea ophiolitic remnants, including gabbro-basalts with a supra-subduction-geochemical signature. New 40Ar/39Ar ages are obtained as 333–320 Ma for the metamorphism of this sequence under greenschist to amphibolite facies. Moreover, the limy intercalations in the volcano-sedimentary part of this complex in Godar-e-Siah yielded Upper Devonian–Tournaisian conodonts. The northeastern part of this complex in the Jandaq area was intruded by 215 ± 15 Ma arc to collisional granite and pegmatites dated by ID-TIMS and its metamorphic rocks are characterized by some 40Ar/39Ar radiometric ages of 163–156 Ma.
The “Variscan” accretionary complex was northwardly accreted to the Airekan granitic terrane dated at 549 ± 15 Ma. Later, from the Late Carboniferous to Triassic, huge amounts of oceanic material were accreted to its southern side and penetrated by several seamounts such as the Anarak and Kabudan. This new period of accretion is supported by the 280–230 Ma 40Ar/39Ar ages for the Anarak mild high-pressure metamorphic rocks and a 262 Ma U–Pb age for the trondhjemite–rhyolite association of that area. The Triassic Bayazeh flysch filled the foreland basin during the final closure of the Paleo-Tethys Ocean and was partly deposited and/or thrusted onto the Cimmerian Yazd block.
The Paleo-Tethys magmatic arc products have been well-preserved in the Late Devonian–Carboniferous Godar-e-Siah intra-arc deposits and the Triassic Nakhlak fore-arc succession. On the passive margin of the Cimmerian block, in the Yazd region, the nearly continuous Upper Paleozoic platform-type deposition was totally interrupted during the Middle to Late Triassic. Local erosion, down to Lower Paleozoic levels, may be related to flexural bulge erosion. The platform was finally unconformably covered by Liassic continental molassic deposits of the Shemshak.
One of the extensional periods related to Neo-Tethyan back-arc rifting in Late Cretaceous time finally separated parts of the Eocimmerian collisional domain from the Eurasian Turan domain. The opening and closing of this new ocean, characterized by the Nain and Sabzevar ophiolitic mélanges, finally transported the Anarak–Jandaq composite terrane to Central Iran, accompanied by large scale rotation of the Central-East Iranian Microcontinent (CEIM). Due to many similarities between the Posht-e-Badam metamorphic complex and the Anarak–Jandaq composite terrane, the former could be part of the latter, if it was transported further south during Tertiary time. 相似文献
The regionally extensive, coarse-grained Bakhtiyari Formation represents the youngest synorogenic fill in the Zagros foreland basin of Iran. The Bakhtiyari is present throughout the Zagros fold-thrust belt and consists of conglomerate with subordinate sandstone and marl. The formation is up to 3000 m thick and was deposited in foredeep and wedge-top depocenters flanked by fold-thrust structures. Although the Bakhtiyari concordantly overlies Miocene deposits in foreland regions, an angular unconformity above tilted Paleozoic to Miocene rocks is expressed in the hinterland (High Zagros).
The Bakhtiyari Formation has been widely considered to be a regional sheet of Pliocene–Pleistocene conglomerate deposited during and after major late Miocene–Pliocene shortening. It is further believed that rapid fold growth and Bakhtiyari deposition commenced simultaneously across the fold-thrust belt, with limited migration from hinterland (NE) to foreland (SW). Thus, the Bakhtiyari is generally interpreted as an unmistakable time indicator for shortening and surface uplift across the Zagros. However, new structural and stratigraphic data show that the most-proximal Bakhtiyari exposures, in the High Zagros south of Shahr-kord, were deposited during the early Miocene and probably Oligocene. In this locality, a coarse-grained Bakhtiyari succession several hundred meters thick contains gray marl, limestone, and sandstone with diagnostic marine pelecypod, gastropod, coral, and coralline algae fossils. Foraminiferal and palynological species indicate deposition during early Miocene time. However, the lower Miocene marine interval lies in angular unconformity above ~ 150 m of Bakhtiyari conglomerate that, in turn, unconformably caps an Oligocene marine sequence. These relationships attest to syndepositional deformation and suggest that the oldest Bakhtiyari conglomerate could be Oligocene in age.
The new age information constrains the timing of initial foreland-basin development and proximal Bakhtiyari deposition in the Zagros hinterland. These findings reveal that structural evolution of the High Zagros was underway by early Miocene and probably Oligocene time, earlier than commonly envisioned. The age of the Bakhtiyari Formation in the High Zagros contrasts significantly with the Pliocene–Quaternary Bakhtiyari deposits near the modern deformation front, suggesting a long-term (> 20 Myr) advance of deformation toward the foreland. 相似文献
The utility of paleomagnetic data gleaned from the Bhander and Rewa Groups of the “Purana-aged” Vindhyanchal Basin has been hampered by the poor age control associated with these units. Ages assigned to the Upper Vindhyan sequence range from Cambrian to the Mesoproterozoic and are derived from a variety of sources, including 87Sr/86Sr and δ13C correlations with the global curves and Ediacara-like fossil finds in the Lakheri–Bhander limestone. New analyses of the available paleomagnetic data collected from this study and previous work on the 1073 Ma Majhgawan kimberlite, as well as detrital zircon geochronology of the Upper Bhander sandstone and sandstones from the Marwar SuperGroup suggest that the Upper Vindhyan sequence may be up to 500 Ma older than is commonly thought. Paleomagnetic analysis generated from the Bhander and Rewa Groups yields a paleomagnetic pole at 44°N, 214.0°E (A95 = 4.3°). This paleomagnetic pole closely resembles the VGP from the well-dated Majhgawan intrusion (36.8°N, 212.5°E, α95 = 15.3°).Detrital zircon analysis of the Upper Bhander sandstone identifies a youngest age population at 1020 Ma. A comparison between the previously correlated Upper Bhander sandstone and the Marwar sandstone detrital suites shows virtually no similarities in the youngest detrital suite sampled. The main 840–920 Ma peak is absent in the Upper Bhander. This supports our assertion that the Upper Bhander is older than the 750–771 Ma Malani sequence, and is likely close to the age of the 1073 Ma Majhgawan kimberlite on the basis of the paleomagnetic similarities. By setting the age of the Upper Vindhyan at 1000–1070 Ma, several intriguing possibilities arise. The Bhander–Rewa paleomagnetic pole allows for a reconstruction of India at 1000–1070 Ma that overlaps with the 1073 ± 13.7 Majhgawan kimberlite VGP. Comparisons between the composite Upper Vindhyan pole (43.9°N, 210.2°E, α95 = 12.2°) and the Australian 1071 ± 8 Ma Bangamall Basin sills and the 1070 Ma Alcurra dykes suggest that Australia and India were not adjacent at this time period. 相似文献
Soil nails have been widely used to stabilize slopes and earth retaining structures in many countries and regions, especially, in Hong Kong. The analysis of the interaction between a soil nail and the surrounding soil is of great interests to both design engineers and researchers. In this paper, authors present a simple mathematical model for the interaction analysis of a soil nail and the surrounding soil considering a few key factors which are soil dilation, bending of the soil nail, vertical pressure, and non-linear subgrade reaction stiffness. The lateral subgrade reaction between the soil and the soil nail is assumed to obey a hyperbolic relation. Reported test data in the literature are used to verify the present model. The contributions of the soil-nail bending on the pull-out resistance are evaluated in two case studies. 相似文献
Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment. 相似文献
Comparison of a database of interpreted sinkholes made using airborne laser swath mapping (ALSM) with databases of sinkholes
made from interpretation of aerial photographs reveals substantial disagreement. The discrepancies involve the location, number,
areas, and circularity of interpreted sinkholes. Methodological factors that contribute to the discrepancies include blockage
of ALSM laser returns in thick vegetation, multi-path reflections, and misrepresentation of the true extent of sinkholes.
Comparison of two ALSM-derived databases made (1) independently from versus (2) in combination with earlier air photo analysis
in undeveloped regions had the following result: one-fourth of the sinkholes interpreted by using the composite method were
missed by the independent analysis, and one-third of the sinkholes that were interpreted from the independent analysis were
not interpreted as sinkholes using the composite method. Subjective interpretation leads to a high level of uncertainty such
that the results of the remote sensing studies are suspect, if not invalid. 相似文献
