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981.
Lithoprobe and industry seismic profiles have furnished evidence of major zones of easterly dipping Grenville deformed crust extending southwest from exposed Grenville rocks north of Lake Ontario. Additional constraints on subsurface structure limited to the postulated Clarendon–Linden fault system south of Lake Ontario are provided by five east–west reflection lines recorded in 1976. Spatial correlations between seismic structure and magnetic anomalies are described from both Lake Ontario and the newly reprocessed New York lines.In the Paleozoic to Precambrian upper crust, the New York seismic sections show: (1) An easterly thickening wedge of subhorizontal Paleozoic strata unconformably overlying a Precambrian basement whose surface has an apparent regional easterly dip of 1–2°. Minor apparent normal offsets, possibly on the order of tens of meters, occur within the Paleozoic section. The generally poorly reflective unconformity may be locally characterized by topographic relief on the order of 100 m; (2) Apparent local displacement on the order of 90 m at the level of the Black River Group diminishes upward to little or no apparent offset of Queenston Shale; (3) Within the limited seismic sections, there appears to be no evidence that the complete upper crustal section is vertically or subvertically offset; (4) Dipping structure in the Paleozoic strata (15° to 35°) resembles some underlying Precambrian basement elements; (5) The surface continuity of inferred faults constituting the Clarendon–Linden system is not strongly supported by the seismic data.Beneath the Paleozoic strata, the seismic sections show both linear and arcuate reflector geometry with easterly apparent dips of 15° to 35° similar to the deep structures imaged on seismic lines from nearby Lake Ontario and on Lithoprobe lines to the north. The similarity supports an extension of easterly dipping Central Metasedimentary Belt structures of the Grenville orogen from southern Ontario to beneath western New York State.From a comparison of the magnetic and gravity fields with the New York seismic sections, we suggest: (1) The largely nonmagnetic Paleozoic strata appear to contribute negligibly to magnetic anomalies. Seismically imaged fractures in the New York Paleozoic strata appear to lie mainly west of a positive gravity anomaly. The relationship between magnetic and gravity anomalies and the changes in the geometry of interpreted Precambrian structures remains enigmatic; (2) North to northeast trending curvilinear magnetic and gravity anomalies parallel, but are not restricted to the principal trend of the postulated Clarendon–Linden fault system. Paleozoic fractures of the Clarendon–Linden system may partly overlie a southward extension of the Composite Arc Belt boundary zone.  相似文献   
982.
About 30 samples representing major lithologies of Sulu ultrahigh-pressure (UHP) metamorphic rocks were collected from surface exposures and exploration wells, and compressional (Vp) and shear wave (Vs) velocities and their directional dependence (anisotropy) were determined over a range of constant confining pressures up to 600 MPa and temperatures ranging from 20 to 600 °C. Samples range in composition from acidic to ultramafic. P- and S-wave velocities measured at 600 MPa vary from 5.08 to 8.64 km/s and 2.34 to 4.93 km/s, respectively. Densities are in the range from 2.60 to 3.68 g/cm3. To make a direct tie between seismic measurements (refraction and reflection) and subsurface lithologies, the experimental velocity data (corresponding to shallow depths) were used to calculate velocity profiles for the different lithologies and profiles of reflection coefficients at possible lithologic interfaces across the projected 5000-m Chinese Continental Scientific Drilling Program (CCSD) crustal segment. Comparison of calculated in situ velocities with respective intrinsic velocities suggests that the in situ velocities at shallow depths are lowered by an increased abundance of open microcracks. The strongly reflective zone beneath the Donghai drill site can be explained by the impedance contrasts between the different lithologies. Contacts between eclogite/peridotite and felsic rocks (gt-gneiss, granitic gneiss), in particular, may give rise to strong seismic reflections. In addition, shear-induced (lattice preferred orientation (LPO)-related) seismic anisotropy can increase reflectivity. For the explanation of the high velocity bodies (>6.4 km/s) around 1000 m and below 3200-m depth, large proportions of eclogite/peridotite (about 40 and 30 vol.%, respectively) are needed.  相似文献   
983.
We show that spurious large non-double-couple components can be obtained in inversions for the full deviatoric moment tensor for shallow crustal earthquakes due to inaccurate Earth models. The traditional “best double-couple” solution does not in general provide an optimal estimate of a double-couple mechanism, and is only reliable when the non-double-couple component of the full deviatoric solution is small. The inverse problem for the moment tensors of the 1998 Antarctic Plate and 2000 Wharton Basin strike-slip earthquakes is shown in each case to have two well-fitting minima in the misfit function of pure double-couple solutions. Such pairs of solutions are most likely to exist for earthquakes which are close either to vertical strike-slip or to dip-slip on a fault plane dipping at 45°. It is shown theoretically that these pairs of solutions arise from the combination of the pure double-couple constraint and the instability of two elements of the moment tensor. No significant non-double-couple component is found for the shallow thrusting 1996 Biak, Indonesia earthquake.  相似文献   
984.
Large sheath folds in the basal high-pressure nappes of the Cabo Ortegal complex are described and a kinematic interpretation provided. The principal penetrative and map structures relate to regional D2 deformation, which produced foliations (S2) bearing mineral and stretching lineations (L2) and several types of folds (a-type, sheath-like and ‘folded folds’). The latter structures are subparallel to the trend of the orogen. Their attitude suggests that the units involved shared a common tectonic evolution during progressive ductile deformation of an anisotropic medium. Reconstruction of major geological structures was accomplished through projection of map-scale features onto the ductile flow plane and the plane perpendicular to the ductile flow direction. The structures reconstructed illustrate their development in the deeper structural levels of an orogenic channel subjected to high-pressure metamorphism during the early phases of the Hercynian orogeny in NW Iberia. We argue that orogen-normal tectonic displacements (of up to a few hundreds of kilometers) represent the minor components of the transpression with possibly thousands of kilometers along-strike dextral displacement between the intervening plates (during subduction/collision).  相似文献   
985.
Geochemical stream sediment survey in Winder Valley, Balochistan, Pakistan   总被引:1,自引:0,他引:1  
A pilot scale geochemical survey of sediments from the Winder Stream (SW Pakistan) and its tributaries was carried out. The Winder Stream mainly receives sediment from the southern extensions of the Mor and Pab Ranges in the District of Lasbela (Balochistan). In these two mountain ranges, rocks from Jurassic to Cretaceous age are exposed. Rocks of the Ferozabad Group comprise of carbonates and siliciclastics of Lower–Middle Jurassic age and occupy the dominant part of the Mor Range. These strata host syngenetic and epigenetic Zn–Pb–Ba mineralizations of Stratiform Sediment-Hosted (SSH) and Mississippi Valley Type (MVT) deposits.Quantitative estimates of mobile and immobile elements were made from active stream sediments of the Winder stream and its tributaries. The samples were analyzed for Ag, Zn, Pb, Cu, Ni, Co, V, Mn, Fe and Ba using atomic absorption spectroscopy. The abundance of these elements is discussed in relation to local geological conditions such as bedrock, climate, weathering, mobility and pH of the dispersing waters. A number of Zn anomalies have been distinguished in the study area. Kharrari (Zn, 360 ppm), Sand (Zn, 340 ppm) and Draber (Zn, 210 ppm) are demarcated as new areas for Zn mineralization. The present study also indicates prospects of Ag, Cu and V in the rocks of the Mor Range.Relationships between various elements have been identified from scattergrams and reflect genetic associations. Whereby the positive correlation between Cu–Zn (0.55, n=18) and Cu–Pb (0.63) is related to possible sulphide mineralization.  相似文献   
986.
Many studies have shown systematic correlations between the composition of plutons worldwide and the metal content of associated skarns. This is the first report of similar correlations between the composition of Çelebi granitoid and skarns of the Çelebi district in Central Anatolia, Turkey. The Çelebi district is well known for its polymetallic Fe–W and Cu vein ores. These are hosted by calcic skarn zones. Both exoskarns (pyroxene–garnet) and endoskarns (epidote–pyroxene) occur in the district formed mainly along the granitoid contacts and along the fractures within the marble. Based on mineralogy, petrology and geochemistry, two different igneous rocks were recognized in the Çelebi granitoid, referred to as leucocratic (felsic) and mesocratic (intermediate) Çelebi granitoid. The leucocratic Çelebi occurs as dominant rock type, and is classified as granite. The mesocratic Çelebi is not widespread and is classified as adamellite, tonalite, quartz monzonite and quartz monzodiorite. The mesocratic Çelebi has I-type characteristics, and have subalkaline, calc-alkaline and metaluminous characteristics like most worldwide skarn granitoids.A post-collisional tectonic setting is proposed on the basis of field evidence, the relative timing of intrusions with respect to metamorphic and obducted ophiolitic rocks and trace element geochemistry. The high abundance of La and Ce and the enrichment of V in mafic components suggest that Çelebi granitoids are formed by partial melting of mantle rocks, but have been contaminated by interaction with continental crust involving possible magma mixing processes (i.e. mixing of coexisting felsic and mafic magmas). In the district, the mesocratic type and mafic microgranular enclaves (MME) mainly within leucocratic type represent a mafic underplating magma that was mixed with and/or injected into felsic magma of the leucocratic type.The present study shows that Fe mineralization is associated with mesocratic Çelebi type, whereas W mineralization is associated with leucocratic type. Mesocratic Çelebi granitoid is significantly different from the worldwide average of plutons associated with Fe skarns. In particular, MgO vs. SiO2, FeOt+CaO+Na2O/K2O vs. SiO2, Fe2O3/Fe2O3+FeO vs. SiO2 and V vs. Ni vary from typical values (are lower than values typical for plutons associated with Fe skarns) for plutons associated with Fe skarns. Instead, it resembles the geochemical characteristics of plutons associated with worldwide Cu and possibly Au skarns. This suggests new exploration possibilities for copper and gold in the Çelebi district.  相似文献   
987.
 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na1.90K0.22Ca0.06)[Al2.24Si2.76O10nH2O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K−1 mol−1 for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K−1 mol−1 for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C p (298.15)=359.1 J K−1 mol−1, S(298.15) −S(0)=362.8 J K−1 mol−1. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001  相似文献   
988.
With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO3.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO32− ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE3+ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.  相似文献   
989.
The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H3PO4 mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   
990.
蓄能器容积的变化与夯管锤的工作过程是紧密联系在一起的,由于活塞的前后运动以及在运动过程中的每一时刻所需要的油量不同的,理想状态就要通过蓄能器的容积变化来调节,就是说蓄能器的容积变化要与夯管锤的冲击振动相耦合。简要介绍了油压夯管锤结构原理,分别解释了油压夯管锤蓄能器与夯管锤的容积压力耦合。  相似文献   
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