硫和氧同位素示踪黄河及支流河水硫酸盐来源   总被引：10，自引：0，他引：10  

张东  黄兴宇  李成杰 《水科学进展》2013,24(3):418-426

为了准确识别河水硫酸盐受自然风化和人为活动影响的过程,做好地表水资源管理,选择黄河小浪底水库以下干流和支流河水为主要研究对象,分期采集河水样品,采用硫酸盐硫和氧同位素,结合水化学组成及潜在硫酸盐来源硫和氧同位素范围,判定黄河及支流河水硫酸盐的来源及混入比例。结果表明:① 研究区黄河河水硫酸盐主要来源于第四纪黄土中易溶硫酸盐,干流河水SO₄2-含量均值为2.23 mmol/L,δ34S_SO4和δ18O_SO4均值分别为+8.9‰和+10.4‰;② 研究区沁河丰水期河水硫酸盐24%来源于大气降水,61%来源于土壤硫酸盐溶解,15%来自于石膏溶解;平水期河水硫酸盐39%来源于大气降水,36%来源于土壤硫酸盐溶解,25%来源于石膏溶解。沁河河水SO₄2-含量均值为2.44 mmol/L,δ34S_SO4和δ18O_SO4均值分别为+9.8‰和+9.7‰;③ 研究区洛河河水硫酸盐受生活污水影响较大,伊河河水硫酸盐受到土壤硫酸盐溶解和化学肥料溶解的共同影响,伊洛河河水SO₄2-含量均值为1.27 mmol/L,δ34S_SO4和δ18O_SO4均值分别为+10.4‰和+6.5‰。蒸发盐类矿物溶解以及土壤硫酸盐溶解等自然风化过程是控制区域河水硫酸盐来源的重要过程,人为活动对伊洛河河水硫酸盐的贡献不容忽视。  相似文献   

Stable isotopic compositions and controlling factors of precipitation and atmospheric vapour in the headwaters of the Shule River     

Zihan Zhang  Liangju Zhao  Ninglian Wang  Hang Liu  Cong Xie  Xiying Dong  Xingru Li 《水文研究》2024,38(1):e15067

Stable isotopic compositions of precipitation (δ¹⁸O_p, δ²H_p and d-excess_p) and atmospheric vapour (δ¹⁸O_v, δ²H_v and d-excess_v) with high spatial–temporal resolution are crucial in revealing hydrologic cycle. Based on the variation characteristics of δ¹⁸O_p/δ¹⁸O_v, δ²H_p/δ²H_v and d-excess_p/d-excess_v in the headwaters of the Shule River (HSR) on hourly and daily scales from June to September 2018, this study analysed the relationships between δ¹⁸O_p/δ²H_p and δ¹⁸O_v/δ²H_v combined with the equilibrium fractionation model, as well as δ¹⁸O_p/δ¹⁸O_v and meteorological factors. The slopes of local meteoric water line (LMWL) and the δ²H_v-δ¹⁸O_v fitting equation were similar (7.96 and 7.94) with both intercepts exceeding 10, reflecting the great contribution of recycling moisture. The values of δ¹⁸O_v/δ²H_v were lower than δ¹⁸O_p/δ²H_p but with consistent variation patterns throughout the period. The equilibrium simulation results suggested that precipitation and atmospheric vapour almost approached isotopic equilibrium state, especially during monsoon intrusion period. Affected by monsoon intrusion, the slopes and intercepts of the LMWLs and the δ²H_v-δ¹⁸O_v fitting equations were smaller than those during non-monsoon period and d-excess and δ¹⁸O were negatively correlated. Relative humidity had significant negative correlations with δ¹⁸O_p and δ¹⁸O_v in the whole period, however, the positive correlations between δ¹⁸O_p/δ¹⁸O_v and temperature were observed during non-monsoon and monsoon intrusion period, respectively. Our results demonstrated that precipitation and atmospheric vapour isotopic compositions exhibited consistency under the influence of diverse moisture sources, while more complex relationships were found between δ¹⁸O_p/δ¹⁸O_v and meteorological factors. This research provided evidence for using the isotopic compositions of atmospheric vapour to indicate moisture sources, and can improve understanding of the water cycle and eco-hydrological process from the perspective of the interaction between water and gas phases of the inland river basin in northwest China.  相似文献   

Understanding hydrological processes of glacierized catchments in the western Himalayas by a multi-year tracer-based hydrograph separation analysis     

Tanveer Dar  Nachiketa Rai  Sudhir Kumar  Mohd Aadil Bhat 《水文研究》2024,38(2):e15083

Snow and glacier melt are significant contributors to streamflow in Himalayan catchments, and their increasing contributions serve as key indicators of climate change. Consequently, the quantification of these streamflow components holds significant importance for effective water resource management. In this study, we utilized the spatio-temporal variability of isotopic signatures in stream water, rainfall, winter fresh snow, snowpack, glaciers, springs, and wells, in conjunction with hydrometeorological observations and Snow Cover Area (SCA) data, to identify water sources and develop a conceptual understanding of streamflow dynamics in three catchments (Lidder, Sindh, and Vishow) within the western Himalayas. The following results were obtained: (a) endmember contributions to the streamflow exhibit significant spatial and seasonal variability across the three catchments during 2018–2020; (b) snowmelt dominates streamflow, with average contributions across the entire catchment varying: 59% ± 9%, 55% ± 4%, 56% ± 6%, and 55% ± 9% in Lidder, 43% ± 6%, 38% ± 6%, 32% ± 4%, and 33% ± 5% in Sindh and 45% ± 8%, 40% ± 6%, 39% ± 6%, and 32% ± 5% in Vishow during spring, summer, autumn, and winter seasons, respectively; (c) glacier melt contributions can reach ~30% to streamflow near the source regions during peak summer; (d) The primary uncertainties in streamflow components are attributed to the spatiotemporal variability of tracer signatures of winter fresh snow/snowpack (±1.9% to ±20%); (e)regarding future streamflow components, if the glacier contribution were to disappear completely, the annual average streamflow in Lidder and Sindh could decrease up to ~20%. The depletion of the cryosphere in the region has led to a rapid increase in runoff (1980–1900), but it has also resulted in a significant streamflow reduction due to glacier mass loss and changes in peak streamflow over the past three decades (1990–2020). The findings highlight the significance of environmental isotope analysis, which provides insights into water resources and offers a critical indication of the streamflow response to glacier loss under a changing climate.  相似文献   

Evidence for variations in cryogenic extraction deuterium biases of plant xylem water across foundational northeastern US trees     

Matthew Sobota  Kevin Li  Michael Hren  James Knighton 《水文研究》2024,38(2):e15079

Measurements of oxygen and hydrogen isotopes in plant xylem water (²H, ¹⁸O) have helped to redefine conceptual and numerical models of the hydrological cycle and understand how plants compete for subsurface water. Recent experiments have shown that Cryogenic Vacuum Extraction (CVE) of plant xylem water can result in a δ²H bias. We tested if CVE δ²H-biases varied significantly across seven foundational northeastern US forest trees with a series of tree core rehydration experiments. Our analysis demonstrated that CVE δ²H-biases were well predicted by sample gravimetric water content and varied significantly with tree species identity. We show that species-level δ²H-bias corrections can result in substantially different understandings of plant water uptake and transpiration versus uncorrected data or generic bias corrections. This research demonstrates an urgent need for the critical evaluation of CVE for plant water extraction. In the absence of a stronger understanding of CVE δ²H-biases, we recommend that xylem water δ²H observations should not be used in plant water uptake studies.  相似文献   

Rhuddanian to Aeronian (Llandovery,early Silurian) carbon isotope stratigraphy throughout carbonate sequences in the upper Yangtze region,South China block     

Shenyang Yu  Qijian Li  Stephen Kershaw  Axel Munnecke  Yingyan Mao  Yue Li 《Island Arc》2024,33(1):e12512

The Xiangshuyuan Formation (middle Rhuddanian to middle Aeronian stages of the Llandovery Series, lower Silurian) records a shelly fauna representing recovery after the end-Ordovician mass extinction in a well-oxygenated shallow carbonate platform of the Upper Yangtze region, South China Block. Carbon isotope stratigraphy is documented from limestone sequences of the formation at the Qiankou section, northeast Guizhou. The early Aeronian carbon isotope excursion (EACIE, with an amplitude of about 2 ‰ and peak value of 2.44 ‰) is identified in the middle and upper parts of the formation (Ozarkodina obesa conodont Biozone). The EACIE recorded herein correlates well with those in Baltica, Canada, and the United States; together with its records from organic material (δ¹³C_org) the data verify that the EACIE is a global event. The beginning of the EACIE can be used as a chemostratigraphic marker defining the Rhuddanian/Aeronian boundary in strata that lack high-resolution biostratigraphic constraints.  相似文献   

A review of diagnostic emission line ratios in the Narrow Line Region of Active Galactic Nuclei     

M. Radovich  G. Hasinger  P. Rafanelli 《Astronomische Nachrichten》1998,319(6):325-346

The availability of new observing facilities both from ground and space such as the Keck 10m telescope and the Hubble Space Telescope is casting new light on the spectroscopic investigation of emission line galaxies. In particular, it is now possible to detect spectra with a significantly improved signal to noise ratio in a very wide wavelength range, from the ultraviolet to the near infrared (HST, Keck) and beyond (ISO is unveiling the far infrared domain). As we move to high redshifts, however, it is more likely that the observed spectra are given by the contribution of different components in the galaxy: in particular, this may be the case if an Active Galactic Nucleus (AGN hereafter) emitting a power-law continuum is surrounded by regions with strong star formation activity. The identification of the source which ionizes the line emitting regions is then complicated by the fact that we are observing the integrated spectrum from regions which are ionized by different sources. In this paper we wish to review which line ratios may be used in order to discriminate between photoionization by young stars and power-law continuum in the wavelength range from 1200 Å to 100 μm. To this aim we used the photoionization code Cloudy (Ferland 1996) to present a series of diagnostic diagrams showing the dependence of emission line ratios on the main input parameters of photoionization models in the case of one component models with gaseous clouds ionized by (1) a stellar continuum typical of an HII region and (2) a power-law continuum typical of an AGN: these line ratios are plotted as isoratio maps for different values of the hydrogen density, ionization parameter and slope of the power-law continuum. We then show how the results may be affected by more realistic assumptions about the environment of the ionized gas: to this aim, we show the effects on selected line ratios of (a) the presence of two populations of clouds with different densities and (b) an AGN surrounded by regions with strong star formation activity.  相似文献   

胶东半岛洪水岚汤温泉水化学特征与成因分析     

袁星芳 《地质与勘探》2020,56(2):427-437

胶东半岛蕴藏着丰富的低温地热资源,以温泉为主要出露方式。洪水岚汤温泉位于胶东半岛东部威海市境内,出露在阳泉河北岸的一级阶地,出露标高为66. 83 m,水温约69℃,下伏基岩为侏罗纪二长花岗岩。为查明其水化学特征及成因,本文采用同位素水文地球化学方法进行研究。水化学成分表明:温泉水中主要阳离子为Na~+,主要阴离子为HCO_3~-、SO_4~(2-),水化学类型为HCO_3·SO_4~-Na,pH值为7. 6,总溶解性固体为610. 6 mg/L,F~-含量为4. 2 mg/L,偏硅酸含量为98. 8 mg/L。氢、氧同位素分析结果显示:温泉热水补给来源为大气降水,估算温泉热水补给高程为427～599 m,地下热储温度约为106. 25℃,地下热水循环深度约为2091 m。综合分析洪水岚汤温泉成因模式为:在正棋山山区获得大气降水入渗补给后,沿F1断裂破碎带下渗经历深循环获得大地热流加热后上升,上升过程中混入浅层地下水,在第四系静水压力最小的部位出露成泉。  相似文献   

华北板块北缘中段二叠纪岩浆岩年代学、地球化学及锆石Hf同位素测试数据集          下载免费PDF全文

王文龙  刘洋  赵利刚  滕飞  杨泽黎 《中国地质》2020,47(S1):32-39

华北板块北缘中段位于华北板块与白乃庙弧的结合处,以赤峰-白云鄂博断裂为界,南、北归属不同的大地构造单元,并且具有不同的基底属性。二叠纪岩浆岩在华北板块北缘广泛分布,断裂带两侧均有出露,源区组成十分复杂,制约着对其岩石成因及构造背景的深刻认识。本文通过对横跨赤峰–白云鄂博断裂的“北柳图庙幅等4幅区调”和“乌兰布拉格幅等2幅区调”2个项目的1∶50 000区调工作,共计6个1∶50 000图幅内的二叠纪岩浆岩的年代学、地球化学及锆石Hf同位素测试数据进行整合、分析,为进一步研究华北板块北缘中段二叠纪岩浆岩的源区及构造-岩浆演化过程提供详实的数据支撑。区内二叠纪侵入岩广泛出露,岩石类型以花岗闪长岩、（石英）闪长岩及二长花岗岩为主,并含有少量的正长花岗岩。二叠纪火山岩主要分布在断裂带以南,岩性包括安山质、英安质及少量流纹质火山岩。锆石U–Pb测年表明工作区内二叠纪岩浆岩的形成时代主要为中–晚二叠世,断裂带南北两侧的岩浆岩具有截然不同的锆石Hf同位素特征,总体而言,南侧相对富集,北侧相对亏损。本数据集包括3个.xls类型文件（Zircon U–Pb dating data.xls,Zircon Hf isotope data.xls,Whole-rock geochemistry data.xls）,分别记录了104件样品的地球化学数据、16件样品的锆石U–Pb测年数据和12件样品的锆石Hf同位素数据。本数据集测试样品主要在中国地质调查局天津地质调查中心实验测试中心完成,数据质量可靠。  相似文献   

Kainsaz(CO3)陨石中两个富Al球粒的氧同位素组成特征与形成演化     

戴德求  包海梅  刘爽  尹锋 《岩石学报》2020,36(6):1850-1856

富Al球粒是原始球粒陨石中一种矿物岩石学特征介于富钙铝包体(CAIs)和镁铁质硅酸盐球粒之间的特殊集合体,所以常常认为富Al球粒在认识CAIs和镁铁质硅酸盐球粒形成演化过程中的相互联系具有特殊意义。然而,对富Al球粒的初始物质组成以及形成演化过程一直存在较多争议,而氧同位素组成研究能够对球粒演化和早期星云环境等提供重要的信息。在本文中我们报导了来自Kainsaz(1937年降落于俄罗斯,CO3型)碳质球粒陨石中的2个富Al球粒(编号K1-CH1和K2-CH2)的矿物岩石学和氧同位素组成特征。K1-CH1的矿物组成主要为橄榄石、低钙辉石和富钙长石,K2-CH2为橄榄石和富钙长石。2个球粒中的矿物均具有贫~(16)O同位素组成特征。K1-CH1中矿物的△~(17)O组成基本上位于2个区间:-11.1‰～-8.7‰和-3.9‰～0.4‰;而K2-CH2的△~(17)O介于-6.6‰～-0.6‰之间,且具有从中部至边部升高的趋势。矿物岩石学和氧同位素特征表明,这2个富Al球粒的初始物质组成为富CAIs和镁铁质硅酸盐。在球粒熔融结晶过程中,与贫~(16)O同位素组成(△~(17)O:-8.7‰～-7.8‰)的星云发生了氧同位素交换。球粒形成后,发生迁移进入陨石母体,在相对更贫~(16)O同位素组成(△~(17)O:-0.6‰～0.4‰)的母体中(流体参与)发生变质作用,并再次发生了氧同位素交换。  相似文献   

A Late Pleistocene marine clay succession at Kriegers Flak,westernmost Baltic,southern Scandinavia     

Fredrik Klingberg 《第四纪科学杂志》1998,13(3):245-253

In the Baltic Sea south of Skåne county in southern Sweden, an over- consolidated marine clay succession on the northeastern slope of Kriegers Flak was observed in shallow seismic data as a unit overlain by younger Weichselian sediments. Two cores were taken from the clay succession. The Foraminifera present were predominantly of two species, Elphidium excavatum and Elphidium albiumbilicatum, reflecting deposition under arctic– boreal conditions. Stable oxygen isotope analyses were performed on foraminiferal tests, and the results show extremely light δ¹⁸O values ranging between −11‰ and −12‰. The cause of these extreme values is uncertain but may result from the high influence of meltwater. Brackish conditions are also indicated by the tolerance for low salinity shown by the Foraminifera. Radiocarbon dating shows an infinite age >40000 yr BP. The pollen flora seems mainly to have been redeposited, which makes interpretation difficult. The sea may have entered the Baltic basin during periods with high eustatic levels, an isostatic downloading of the crust, or a combination of both. It is suggested that the deposition of the overconsolidated marine clay succession occurred in the Late Saalian, Early Eemian or Early Weichselian. © 1998 John Wiley & Sons, Ltd.  相似文献