Rapid change in nitrate and sulfate concentrations observed in early stage of precipitation and their deposition processes     

Hiroaki Minoura  Yasunobu Iwasaka 《Journal of Atmospheric Chemistry》1996,24(1):39-55

The concentrations of H⁺, nitrate (NO₃ ^-), and sulfate (SO₄ ^2-) in rainwater and their temporal changes were analyzed on the basis of continuous observation from 1 July 1991 to 30 June 1992 at a suburb of Nagoya, Japan. The yearly average for pH was 4.4. In general, an increasing pH with increase in precipitation amount was observed for rain events. Relatively high pH rainwater was sometimes observed at the beginning of rainfall, even though high concentrations of NO₃ ^- and SO₄ ^2- were involved. The high pH values were considered to be caused by the neutralization process with particulate matter containing cations. The yearly averaged ratio of equivalent concentration of nitrate to sulfate (N/S) in rainwater was 0.58. In the early stage of rain, the N/S value was usually more than 1.0 due to the difference of scavenging process between NO₃ ^- and SO₄ ^2-. High values of N/S ranging from 5 to 10 were found under the atmospheric conditions of calm winds and low humidity, during which it is possible that atmospheric particles float for a long time in the air before a rain event. The adsorption of NO₃ ^- in the early stage of rainfall by particulate matter was suggested from the difference in scavenging processes of NO₃ ^- and SO₄ ^2-. A possible scavenging process, called limb cloud scavenging, is presented to explain the interaction of particles and nitrate ions at the early stage of rain. In limb cloud scavenging, the repeated migration of cloud particles or raindrops between the inside and outside of clouds increases the absorption of ions to a highly condensed level, thus increasing the N/S value of rainwater. The influence of global scale seasonal phenomena with large amounts of particulates, such as typhoons or Asian dust storms, was also studied.  相似文献   

用含铝矿石生产硫酸铝的工艺     

何新秀  李武雄 《矿物岩石》1996,16(2):96-99

本文用含铝矿石生产硫酸铝。在反复试验的基础上所拟定的最佳工艺流程，经建厂投产质量达标。并对工艺条件和影响质量因素进行了有效的探索。  相似文献   

Reservoir geochemistry of South Pass 61 Field, Gulf of Mexico: compositional heterogeneities reflecting filling history and biodegradation   总被引：1，自引：0，他引：1  

A.G. Holba  L.I.P. Dzou  J.J. Hickey  S.G. Franks  S.J. May  T. Lenney 《Organic Geochemistry》1996,24(12):1179-1198

Cluster analysis of GC data for gasoline and mid-range hydrocarbon ratios from fifty-one South Pass 61 Field oils reveals geochemically similar oil clusters corresponding to geographically coherent groups. Insight into the groupings is obtained from examination of indicators of geochemical processes, e.g., anaerobic biodegradation, aerobic biodegradation and extensive remigration of light ends. Six duplicate samples collected in 1986 and 1992 as well as replicate runs on a single sample showed excellent analytical reproducibility.Subtle but consistent differences in both gasoline and oil-range hydrocarbon maturity indicators are observed between the east, west, and far west flanks of the field, suggesting filling of different segments of the reservoir from different kitchens at slightly different stages of thermal maturity or with slightly different chemical character. The west flank of the salt dome was charged with slightly more thermally mature petroleum than the east flank. The stratigraphically oldest and deepest sand on the far west flank has received the most mature petroleum. Different fluid contacts and GORs are observed in different sands and different fault blocks. The stacked pay geometry of the field and widespread faulting have led to considerable remigration of gas and condensate as observed in other fields in the Gulf of Mexico (Thompson, 1987).Biodegradation varies in severity with depth and reservoir zone, but is frequently overprinted by remigration of light end hydrocarbons. Anaerobic biodegradation by sulfate-reducing bacteria is probably the cause of light to moderate alteration in intermediate depth Pliocene sands which are hydraulically connected to the salt dome (with dissolution of anhydrite from the salt dome providing the sulfate). Widespread late pyrite formation in reservoir sandstones is inferred to represent the ultimate sink for reduced sulfur from sulfate reduction during oil biodegradation. Co-produced water compositions suggest no oxygenated freshwater infusion.  相似文献   

Nitrate in the atmospheric boundary layer of the tropical South Pacific: Implications regarding sources and transport     

Dennis L. Savoie  Joseph M. Prospero  John T. Merrill  Mitsuo Uematsu 《Journal of Atmospheric Chemistry》1989,8(4):391-415

Weekly bulk aerosol samples collected at Funafuti, Tuvalu (8°30S, 179°12E), American Samoa (14°15S, 170°35W), and Rarotonga (21°15S, 159°45W), from 1983 through most of 1987 have been analyzed for nitrate and other constituents. The mean nitrate concentration is about 0.11 g m^–3 at each of these stations: 0.107±0.011 g m^–3 at Funafuti; 0.116±0.008 at American Samoa; and 0.117±0.010 at Rarotonga. Previous measurements of mineral aerosol and trace metal concentrations at American Samoa are among the lowest ever recorded for the near-surface troposphere and indicate that this region is minimally affected by transport of soil material and pollutants from the continents. Consequently, the nitrate concentration of 0.11 g m^–3 can be regarded as the natural level for the remote marine boundary layer of the tropical South Pacific Ocean. In contrast, over the tropical North Pacific which is significantly impacted by the transport of material from Asia and North America, the mean nitrate concentrations are about three times higher, 0.29 and 0.36 g m^–3 at Midway and Oahu, respectively. The major sources of the nitrate over the tropical South Pacific are still very uncertain. A very significant correlation between the nitrate concentrations at American Samoa and the concentrations of ²¹⁰Pb suggests that transport from continental sources might be important. This continental source could be lightning, which occurs most frequently over the tropical continents. A near-zero correlation with ⁷Be indicates that the stratosphere and upper troposphere are probably not the major sources. A significant biogenic source would be consistent with the higher mean nitrate concentrations, 0.16 to 0.17 g m^–3, found over the equatorial Pacific at Fanning Island (3°55N, 159°20W) and Nauru (0°32S, 166°57E). The lack of correlation between nitrate and nss sulfate at American Samoa does not necessarily preclude an important role for marine biogenic sources.  相似文献   

扬子地台灯影组碳酸盐岩中的硫和碳同位素记录   总被引：17，自引：3，他引：17  

张同钢储雪蕾  张启锐冯连君 霍卫国 《岩石学报》2004,20(3):717-724

扬子地区灯影组的海相碳酸盐岩地层不仅记录了当时海水的碳同位素变化，也保存了海水的硫同位素记录，能够通过测定所提取的微量硫酸盐的硫同位素组成来获得。灯影组碳酸盐岩中微量硫酸盐的δ^34S值大部分在 20.0‰～ 38．7‰之间变化，碳酸盐岩的δ^13C值变化在 0．5‰～ 5．0‰之间。除灯影组顶、底界线处外，δ^34S和δ^13C值总体上变化幅度较小，大体上呈逐渐降低的变化趋势。灯影组碳酸盐岩中连续的硫、碳同位素记录分别反映了同期海水中溶解硫酸盐和碳酸盐的硫、碳同位素的变化特征。灯影组微量硫酸盐和碳酸盐岩的同位素特征，意味着灯影期海洋中具有高的生物产率和有机碳埋藏速率；除了顶底界线处，具有相对稳定的古气候条件和古海洋环境。灯影期海水的δ^34S值和δ^13C值同时呈逐渐降低的变化趋势，可能是由海洋深部水体逐渐氧化所致。  相似文献   

Possible Carbonate Origin of Ore Sulfur from Geumseong Mo Deposit, South Korea     

Shunso ISHIHARA  Yoshimichi KAJIWARA  Myung–Shik JIN 《Resource Geology》2002,52(3):279-282

Abstract: In order to know the cause of the high δ³⁴S values of the Korean ore deposits (Ishihara et al., 2000), Geumseong molybdenum skarn deposit and related Jurassic granitoids and Cambro-Ordovician carbonates were selected for the δ³⁴S analyses. Two sulfide samples occurring in hydrothermal veins in fresh granitoids quarry at Songhaksan yielded δ³⁴S values of +6.9 and +8.8 permil. These are slightly higher than +5.3 permil δ³⁴S of the averaged rock sulfides for the Jurassic Daebo granitoids. Pyrite and molybdenite from the Geumseong deposit vary from +8.6 to +11.5 permil (average + 10.7 permil). The intruded carbonates contain very low amount of SSS (structurally substituted sulfate) as 2.9 to 8.1 ppm with high δ³⁴S values between +28.8 and + 40.0 permil, and sulfides sulfur of 52 to 779 ppm with variable δ³⁴S values between +3.2 and +22.5 per–mil. It is concluded that sulfur of the host carbonates was extracted and migrated into the skarn deposit at the time of the granitoid intrusion and the related hydrothermal convection, on the basis of the location of the skarn deposit occurring between the carbonates and Jurassic granitoids, and of very low contents of SSS sulfur in the carbonates. A part of SSS possibly contaminated into the Jurassic granite.  相似文献   

Comparison of methods for calculating annual solute exports from six forested appalachian watersheds     

BRYAN R. SWISTOCK  PAMELA J. EDWARDS  FREDERICA WOOD  DAVID R. DEWALLE 《水文研究》1997,11(7):655-669

Six methods were compared for calculating annual stream exports of sulfate, nitrate, calcium, magnesium and aluminum from six small Appalachian watersheds. Approximately 250–400 stream samples and concurrent stream flow measurements were collected during baseflows and storm flows for the 1989 water year at five Pennsylvania watersheds and during the 1989–1992 water years at a West Virginia watershed. Continuous stream flow records were also collected at each watershed. Solute exports were calculated from the complete data set using six different scenarios ranging from instantaneous monthly measurements of stream chemistry and stream flow, to intensive monitoring of storm flow events and multiple regression equations. The results for five of the methods were compared with the regression method because statistically significant models were developed and the regression equations allowed for prediction of solute concentrations during unsampled storm flows. Results indicated that continuous stream flow measurement was critical to producing exports within 10% of regression estimates. For solutes whose concentrations were not correlated strongly with stream flow, weekly grab samples combined with continuous records of stream flow were sufficient to produce export estimates within 10% of the regression method. For solutes whose concentrations were correlated strongly with stream flow, more intensive sampling during storm flows or the use of multiple regression equations were the most appropriate methods, especially for watersheds where stream flows changed most quickly. Concentration–stream flow relationships, stream hydrological response, available resources and required level of accuracy of chemical budgets should be considered when choosing a method for calculating solute exports. © 1997 John Wiley & Sons, Ltd.  相似文献   

褐藻酸钠硫酸酯的抗凝血及抗血栓作用     

许实波  赵桂玲  曾志  郑国栋 《热带海洋学报》1998,(2)

褐藻酸钠硫酸酯是以褐藻酸为原料合成的硫酸酯钠盐系列物。首次报道该系列化合物（Ⅰ,Ⅱ,Ⅲ,Ⅳ,主要是Ⅰ）的抗血栓和抗凝血作用。实验发现,褐藻酸钠硫酸酯系列物均有抗凝血作用。其作用具有浓度和磺化度依赖性。实验测定化合物Ⅰ,Ⅱ,Ⅲ,Ⅳ的抗凝效价,分别相当于肝素钠的22．5％,16．7％,11．1％和11．7％。以该化合物10mg·kg－1静脉注射能增加小鼠的出血量并能抑制大鼠实验性动脉血栓的形成。化合物Ⅰ还具有延长大鼠凝血酶原时间和抑制静脉血栓形成的作用。结果提示：褐藻酸钠硫酸酯的抗凝血与抗血栓作用的活性基团可能为该化合物上的硫酸根,具有肝素样作用。  相似文献   

四川盆地高含H2S天然气的分布与TSR成因证据   总被引：49，自引：5，他引：44  

朱光有  张水昌  梁英波  马永生  郭彤楼  周国源 《地质学报》2006,80(8):1208-1218

四川盆地是中国高含硫化氢天然气分布最集中的地区,目前已在震旦系(威远气田)、下三叠统飞仙关组(罗家寨、普光、渡口河、铁山坡、七里北)、嘉陵江组(卧龙河)和中三叠统雷口坡组(磨溪、中坝)发现了近10个高含硫化氢的大中型气田(藏),探明储量5000×108 m3.这些高含硫化氢气藏普遍经历过较大的埋深过程(储层经历过较高温度),储层上下或储层中间均发育有膏质岩类,且气源充足,具备硫酸盐热化学还原反应(Thermochemical Sulfate Reduction,TSR)发生的物质基础和热动力条件.从气藏地质特征以及天然气组成和碳、硫同位素等方面的证据表明,四川盆地中、下三叠统和震旦系气藏的硫化氢属于TSR成因.而且TSR对烃类的大量选择性消耗一方面导致天然气干燥系数增大,另一方面导致气藏充满度降低,气藏压力系数变小.  相似文献   

Characterization of sulfate mineral deposits in central Thailand          下载免费PDF全文

Junichiro Kuroda  Hidetoshi Hara  Katsumi Ueno  Thasinee Charoentitirat  Teruyuki Maruoka  Takashi Miyazaki  Akira Miyahigashi  Stefano Lugli 《Island Arc》2017,26(2)

In this paper we present petrographic and geochemical data of sulfate mineral deposits in northeast Nakhon Sawan, central Thailand, and provide new constraints on their age. The deposits are made up mainly of strongly deformed nodular and massive gypsum in the upper part, and less deformed layered anhydrite in the lower part. They are intruded by andesitic dikes that contain Middle Triassic zircons (ca 240 Ma). These dikes are probably part of the regional magmatic activity of the Sukhothai Arc during the Early to Middle Triassic. Sulfur (δ³⁴S) and strontium (⁸⁷Sr/⁸⁶Sr) isotopic compositions of the sulfates range from 15.86 ‰ to 16.26 ‰ and from 0.70810 to 0.70817, respectively. Comparisons with the Phanerozoic seawater isotopic evolution curve indicate that those values are best explained by precipitation of the sulfates from Carboniferous seawater, in particular seawater of late Mississippian age (ca 326 Ma), and this would be consistent with previous studies of calcareous fossils in the limestones that crop out around this site. Our interpretation is that evaporitic gypsum was originally precipitated from hypersaline seawater on a shallow lagoon or shelf on the Khao Khwang Platform during the Serpukhovian, and that this gypsum changed to anhydrite during early burial. The anhydrite was then cut by andesitic dikes during the Middle Triassic, and more recently the upper part of which was rehydrated during exhumation to form secondary gypsum near the surface.  相似文献