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61.
利用硫酸镁和造纸草浆黑液制备含镁氧化合物的吸附剂,通过化学分析、表面性质分析、X射线衍射和红外光谱等对吸附剂进行了表征.考察了吸附剂焙烧温度、投加量、吸附时间以及pH值等因素对活性黄ST-4RFN吸附性能的影响,吸附过程可用Freundlich模型来描述. 相似文献
62.
Marianne Holmer Ole Pedersen Dorte Krause-Jensen Birgit Olesen Malene Hedegrd Petersen Stephanie Schopmeyer Marguerite Koch Bente Aa. Lomstein Henning S. Jensen 《Estuarine, Coastal and Shelf Science》2009,85(2):319-326
Sulfur and oxygen dynamics in the seagrasses Thalassia testudinum and Syringodium filiforme and their sediments were studied in the US Virgin Islands (USVI) in order to explore sulfide intrusion into tropical seagrasses. Four study sites were selected based on the iron concentration in sediments and on proximity to anthropogenic nutrient sources. Meadow characteristics (shoot density, above- and below-ground biomass, nutrient content) were sampled along with sediment biogeochemistry. Sulfide intrusion was high in T. testudinum, as up to 96% of total sulfur in the plant was derived from sediment-derived sulfides. The sulfide intrusion was negatively correlated to the turnover of sulfides in the sediments regulated by both plant parameters and sediment sulfur pools. Sediment iron content played an indirect role by affecting sulfide turnover rates. Leaf production was negatively correlated with sulfide intrusion suggesting that active growth reduced sulfide intrusion. Sulfide intrusion was lower in S. filiforme (up to 44%) compared to T. testudinum consistent with a higher internal nighttime oxygen concentrations found for S. filiforme. When S. filiforme can take advantage of its ability to maintain high internal oxygen concentrations, as was the case on the USVI, it could increase its success in colonizing unvegetated disturbed sediments with potentially high sulfide concentrations. 相似文献
63.
Urban air pollution in Pakistan is a serious challenge and it causes significant damage to human health and ecosystems. This paper presents a modelling study using the Weather Research and Forecasting Model coupled with Chemistry(WRF-Chem) to simulate the spatial distributions and temporal variations of aerosol concentrations over Pakistan, focusing on contributions of domestic emission sectors(transport, industry, residential, and energy) to mass concentrations of sulfate(SO2–4), nitrate(NO–3), ammonium(NH+4), black carbon(BC), and organic carbon(OC) during the months of January, April, July, and October in 2010. Sensitivity studies indicate that, averaged over January, April, July, and October of 2010, energy and industry sectors have the largest contributions to SO2–4 concentrations, each of which contributes about 10%?20% to SO2– 4over the polluted eastern Pakistan. The contributions from residential and transport sectors to NO–3 concentrations reach 40%?50% in central Pakistan. The residential sector has the highest contribution of 50%–80% to BC and OC loading in northeastern and southern Pakistan. Examination of sector contributions to aerosol levels in Lahore, the most polluted city in Pakistan, suggests that reductions in emissions in the residential sector should be an efficient measure for improving particulate matter air quality in this region. 相似文献
64.
本文构建以掺硼金刚石(Boron-doped diamond,BDD)为阳极、不锈钢为阴极、硫酸盐为电解质的电化学体系,考察了电流密度、pH值、硫酸盐浓度以及初始四环素浓度等四个因素对电化学氧化降解废水中四环素的影响,运用响应曲面法对运行参数进行优化;通过电子自旋共振检测技术分析电化学反应中产生的自由基,探究了间歇通电模式下电化学体系持续氧化机理。结果表明,四个因素对TOC去除率的影响大小次序为:电流密度>初始四环素浓度>初始pH值>硫酸盐浓度,其中初始pH值和硫酸盐浓度与电流密度和初始四环素浓度的交互作用对TOC去除率的影响较为显著;最佳运行参数为pH值为5,电流密度为100 mA·cm-2,硫酸盐浓度为0.25 mol·L-1,初始四环素浓度为1000 mg·L-1;间歇通电模式下,BDD电极表面产生的SO4·-等高活性物质间相互转化提供了体系的可持续氧化能力。该研究结果为电化学氧化技术的实际应用提供了节省能耗的有效途径。 相似文献
65.
66.
Sulfate chitosan derivatives have good solubility and therapeutic effect on the cell model of NAFLD. The aim of this study was to examine the therapeutic effect of sulfate chitosan derivatives on NAFLD. The male Wistar rats were orally fed high fat emulsion and received sulfate chitosan derivatives for 5 weeks to determine the pre-treatment effect of sulfate chitosan derivatives on NAFLD. To evaluate the therapeutic effect of sulfate chitosan derivatives on NAFLD, the rats were orally fed with high concentration emulsion for 5 weeks, followed by sulfate chitosan derivatives for 3 weeks. Histological analysis and biomedical assays showed that sulfate chitosan derivatives can dramatically prevent the development of hepatic steatosis in hepatocyte cells. In animal studies, pre-treatment and treatment with sulfate chitosan derivatives significantly protected against hepatic steatohepatitis induced by high fat diet according to histological analysis. Furthermore, increased TC, ALT, MDA, and LEP in NAFLD were significantly ameliorated by pre-treatment and treatment with sulfate chitosan derivatives. Furthermore, increased TG, AST, and TNF-α in NAFLD were significantly ameliorated by treatment with sulfate chitosan derivatives. Sulfate chitosan derivatives have good pre-treatment and therapeutic effect on NAFLD. 相似文献
67.
Intense thermochemical sulfate reduction (TSR) and up to 18% H2S are found in the Upper Permian Changxing Formation (P3ch) in the northeast (NE) Sichuan Basin, China, despite that rare gypsum or anhydrite was found in this formation. Here, we present new concentration data of carbonate-associated sulfate (CAS) from carbonate host rocks, C, O, and Sr isotope data for TSR-related calcites, and S isotope data for sulfur compounds obtained during this study. These data along with spatial-temporal changes in palaeogeopressure conditions, hydraulic conductivity and the physical capacity indicate that the H2S was generated locally from TSR within the P3ch reservoirs. We propose that the reactive sulfates were derived from CAS released during dolomitization and recrystallization of earlier dolomite within the P3ch Fm. and from the cross-formational migration of evaporative brines from the Lower Triassic Feixianguan Formation (T1f) to P3ch Fm. Our calculation shows that the two sources could provide enough SO42− for the generation of H2S within the P3ch reservoirs. Early downward migration of sulfate-rich evaporative brines from the T1f formation occurred in near-surface and shallow burial diagenetic settings (mainly <1000 m). The evaporative brines seeped into porous grainstones and displaced preexisting seawater, causing pervasive dolomitization within the P3ch Fm. Subsequently, TSR calcites precipitated from the pore water have high Sr concentrations (up to 7767 ppm), close to the T1f TSR calcites, and 87Sr/86Sr ratios mainly from 0.7074 to 0.7078, which are significantly higher than those of Late Permian seawater but within the range of early Triassic seawater. 相似文献
68.
Gas occurrences consisting of carbon dioxide (CO2), hydrogen sulfide (H2S), and hydrocarbon (HC) gases and oil within the Dodan Field in southeastern Turkey are located in Cretaceous carbonate reservoir rocks in the Garzan and Mardin Formations. The aim of this study was to determine gas composition and to define the origin of gases in Dodan Field. For this purpose, gas samples were analyzed for their molecular and isotopic composition. The isotopic composition of CO2, with values of −1.5‰ and −2.8‰, suggested abiogenic origin from limestone. δ34S values of H2S ranged from +11.9 to +13.4‰. H2S is most likely formed from thermochemical sulfate reduction (TSR) and bacterial sulfate reduction (BSR) within the Bakuk Formation. The Bakuk Formation is composed of a dolomite dominated carbonate succession also containing anhydrite. TSR may occur within an evaporitic environment at temperatures of approximately 120–145 °C. Basin modeling revealed that these temperatures were reached within the Bakuk Formation at 10 Ma. Furthermore, sulfate reducing bacteria were found in oil–water phase samples from Dodan Field. As a result, the H2S in Dodan Field can be considered to have formed by BSR and TSR.As indicated by their isotopic composition, HC gases are of thermogenic origin and were generated within the Upper Permian Kas and Gomaniibrik Formations. As indicated by the heavier isotopic composition of methane and ethane, HC gases were later altered by TSR. Based on our results, the Dodan gas field may have formed as a result of the interaction of the following processes during the last 7–8 Ma: 1) thermogenic gas generation in Permian source rocks, 2) the formation of thrust faults, 3) the lateral-up dip migration of HC-gases due to thrust faults from the Kas Formation into the Bakuk Formation, 4) the formation of H2S and CO2 by TSR within the Bakuk Formation, 5) the vertical migration of gases into reservoirs through the thrust fault, and 6) lateral-up dip migration within reservoir rocks toward the Dodan structure. 相似文献
69.
Aerosols make a considerable contribution to the climate system through their radiative and cloud condensation nuclei effects, which underlines the need for understanding the origin of aerosols and their transport pathways. Seasonal distribution of mineral dust around the globe and its correlation with atmospheric circulation is investigated using satellite data, and meteorological data from ECMWF. The most important sources of dust are located in North Africa, the Middle East and Southwest Asia with an observed summer maximum, and East Asia with a spring peak. Maximum dust activity over North Africa and the Middle East in summer is attributed to dry convection associated with the summertime low-pressure system, while unstable weather and dry conditions are responsible for the spring peak in dust emission in East Asia. Intercontinental transport of mineral dust by atmospheric circulation has been observed, including trans-Atlantic transport of North African dust, trans-Pacific transport of Asian dust, and transport of dust from the Middle East across the Indian Ocean. The extent of African dust over the Atlantic Ocean and its latitudinal variation with season is related to the large-scale atmospheric circulation, including seasonal changes in the position of the intertropical convergence zone (ITCZ) and variation of wind patterns. North African aerosols extend over longer distances across the North Atlantic in summer because of greater dust emission, an intensified easterly low level jet (LLJ) and strengthening of the Azores-Bermuda anticyclonic circulation. Transport of East Asian aerosol is facilitated by the existence of a LLJ that extends from East Asia to the west coast of North America. 相似文献
70.
正In recent decades,meromictic ponds attract the attention of researchers in different directions,because here the character of the physical,chemical and biological processes differ from those of typical mixing waters(Kuznetsov,1970;Hutchinson,1969).In Transbaikalia widely distributed soda and salt lakes with different salinity.Notable among them is Lake Doroninskoye,which has a pronounced stratification for a 相似文献