硫介导细菌还原载砷铁矿对砷迁移转化的影响          下载免费PDF全文

王晶  谢作明  王佳  杨洋  刘恩杨 《地球科学》2021,46(2):642-651

硫在铁和砷的生物地球化学循环中发挥着重要作用,但地下水系统中硫循环的中间产物S(0)对细菌转化铁和砷的影响尚不清楚.采用室内模拟实验,研究硫参与下细菌D2201对液相和载砷针铁矿中Fe(III)和As(V)的还原作用.结果表明:细菌D2201具有很强的铁还原能力,可以将液相中74%的Fe(III)还原;加入硫后,细菌还原S(0)产生的S(-II)使铁还原率提高到94%.但是,硫没有明显影响细菌对砷的还原.在实验初期,细菌明显加速了载砷针铁矿的还原,最终还原释放到液相中的Fe(II)浓度为32.12 μmol/L;硫的加入增强了细菌对载砷针铁矿的还原,还原溶解的Fe(II)增加至284.13 μmol/L,同时,砷的释放量也增加了1.6倍.这些结果表明硫显著促进了细菌对针铁矿的还原溶解并加速砷的释放.XRD和SEM-EDS结果显示,细菌还原针铁矿但不改变其矿相,而硫的加入也仅使矿物发生一定程度的团聚,并没有使其转变为其他矿物,也未导致砷的再吸附.   相似文献   

陕西旬阳地区小河金矿硫铅同位素组成及地质意义     

孟五一  刘家军  魏立勇  张振  吴欢欢  范堡程  潘元  李国英  贾彬 《现代地质》2021,35(6):1587-1596

小河金矿是近年来在南秦岭中带发现的中型金矿床,矿石类型为微细浸染型,矿床受地层和构造双重控制。在野外工作基础上,根据矿物组合及穿插关系划分了4个成矿阶段:Ⅰ,成矿早期少硫化物石英脉成矿阶段;Ⅱ,石英脉、黄铁矿、毒砂成矿主阶段;Ⅲ,石英脉-多金属硫化物成矿主阶段;Ⅳ,方解石、石英脉成矿晚阶段。其中Ⅱ、Ⅲ阶段是主要金矿化阶段。不同阶段样品的原位硫同位素结果显示:成矿早阶段石英脉期的黄铁矿δ³⁴S值为20.80‰~25.77‰,均值为23.59‰;主成矿期II阶段中黄铁矿、毒砂δ³⁴S值为15.46‰~19.12‰,均值为17.5‰;主成矿期Ⅲ阶段中方铅矿、闪锌矿δ³⁴S值为11.35‰~16.78‰,均值为13.88‰。硫同位素特征指示硫以沉积硫为主,成矿过程可能存在低δ³⁴S值热液的持续加入。金属硫化物Pb同位素测试结果显示²⁰⁶Pb/²⁰⁴Pb为17.882 1~18.367 4,²⁰⁷Pb/²⁰⁴Pb为15.614 0~15.674 1,²⁰⁸Pb/²⁰⁴Pb为38.016 3~38.934 2,指示小河金矿铅主要源于地壳,同时伴随幔源铅的混入。综合矿床地质特征及硫、铅同位素地球化学特征,认为小河金矿成矿过程可能存在流体混合作用。  相似文献   

南秦岭柞水—山阳矿集区夏家店金矿床黄铁矿微量元素和氢、氧、硫同位素对矿床成因的制约     

丁坤  王瑞廷  刘凯  王智慧  申喜茂 《现代地质》2021,35(6):1622-1632

为了研究柞水—山阳矿集区夏家店金矿床成因,采用LA-ICP-MS和LA-MC-ICP-MS技术分析夏家店金矿床矿体及围岩样品中黄铁矿原位微量元素及氢、氧、硫同位素组成特征。结果表明,该矿床黄铁矿的Co/Ni 比值为0.11~0.76,说明其与沉积作用有关。矿石中黄铁矿的δ³⁴S值(-9.40‰~7.16‰)与围岩碳质板岩的δ³⁴S值(-8.84‰~10.64‰)接近,黄铁矿的δ³⁴S均值(2.47‰)基本落在岩浆硫的范围内,指示矿石硫可能由地层硫和岩浆硫混合而成。氢、氧同位素测试结果表明,夏家店矿床成矿流体可能主要来自岩浆水,成矿后期有大气降水的加入。综合矿床地质特征、成矿温度、金赋存状态等特征和黄铁矿微量元素、硫同位素组成可知,夏家店金矿床属于卡林型金矿,其成矿流体主要来自岩浆水,成矿后期有大气降水加入;其成矿物质是由深部岩浆与地层混合而成。  相似文献   

印度尼西亚Cikotok矿区帕瑟埃拉金矿成因及成矿潜力     

张顺洋  王海滨  王淞  王忠凯 《地质与资源》2021,30(2):136-142

印度尼西亚Cikotok矿区帕瑟埃拉金矿位于巽他-班达岛弧的中部Bayah穹隆中,宏观上具有找到大型矿床的地质前提.成矿围岩为始新世末-中新世早期的安山岩,围岩蚀变强烈,分带性明显,金矿脉具有多条近平行产出特征.矿床有4个成矿阶段：石英-蒙脱石-绿泥石阶段,石英-绢云母-黄铁矿阶段,石英-冰长石-硫化物-含锰矿物阶段,块状石英阶段.矿床成因类型为大洋岛弧型低硫浅成低温热液型,细分类型为"Pongkor型"条带状低硫含金石英锰氧化物矿脉型金矿,其浅表部为热泉型金矿.矿床的深部找矿潜力大,具有大型金矿的成矿潜力.  相似文献   

Silurian and Devonian systems     

Maxwell R. Banks  E. D. Gill  K. L. Burns 《Australian Journal of Earth Sciences》2013,60(2):177-187

The Ediacara mineral field is situated 30 km W of Beltana on the western margins of the Flinders Ranges, South Australia, and consists of silver‐lead and copper deposits in lower Cambrian carbonate rocks that contain anomalous base‐metal contents throughout the Adelaide Geosyncline. The lower Cambrian rocks, which consist of the basal Parachilna Formation and overlying Ajax Limestone, rest disconformably on the Precambrian, and at Ediacara occupy a shallow N‐S elongate syncline near the hinge zone of the Adelaide Geosyncline. The main primary ore minerals of the silver‐lead mineralization are galena and pyrite, with very minor chalcopyrite and sphalerite, and rare tetrahedrite and pearceite. The gangue consists mainly of silica (both chalcedony and quartz), with minor dolomite and rare barite. The mineralization is stratabound and occurs in conformable zones, the lowest of which commences about 30–50 m above the base of the Cambrian sequence. The host to the silver‐lead mineralization, the Ajax Limestone, can be subdivided into three units which represent a set of lithologies, structures and organic traces indicative of a shallow near‐shore carbonate environment. The silver‐lead mineralization is mainly present in sandy and laminated dolomites which were deposited in an environment ranging from sub‐tidal to bar and channel and tidal flat, respectively. Four types of mineralization have been recognized; disseminated sulphides of syngenetic and/or diagenetic origin and epigenetic concentrations along stylolites, in veins and as breccia fillings. Post‐depositional solution activity has affected a large proportion of the carbonate sequence. The effects of this activity range from stylolites through stylobreccias to solution collapse breccias. The epigenetic concentrations of mineralizations have apparently been formed by the remobilization of the disseminated sulphides during solution activity. The ore and gangue minerals of the epigenetic mineralization display both euhedral forms and distinct colloform banding, and framboidal textures have also been observed in both pyrite and galena. There is evidence of repeated episodic precipitation and no simple paragenetic sequence can be recognized. Fluid inclusions in silica and dolomite associated with the epigenetic mineralization have homogenization temperatures of 159 to 199°C and freezing temperatures that indicate the fluids to be saline brines containing NaCl with CaCl₂ and/or MgCl₂. Sulphur isotope analyses show a range of 8³⁴S values from ‐12.5 to +8.6 per mil, with no evidence of significant differences between the four types of mineralization. The data suggest deposition of the disseminated sulphides as a result of biological reduction of seawater sulphate in a system partially open with respect to sulphate supply. Subsequent remobilization of sulphides apparently involved little or no sulphur isotope fractionation. The Ediacara silver‐lead deposits have many features in common with Mississippi Valley‐type lead‐zinc deposits and appear to have similarities in terms of genesis, in that the epigenetic mineralization has been formed as a result of post‐depositional solution activity during diagenesis in a sedimentary basin. The scale of transport of the metals deposited as the epigenetic mineralization at Ediacara appears, however, to have been very much less than that of the metals in other Mississippi Valley‐type deposits.  相似文献   

华北地台北缘东段金矿带硫同位素特征及其找矿意义     

王义文 《吉林大学学报(地球科学版)》1989,(3)

华北地台北缘东段金矿带主要类型金矿床的矿石硫同位素组成受矿源层破同位素背景值制约,成矿与不同时代花岗岩侵入或混合岩化作用引起的成矿物质活化作用有关。深成作用过程中的硫同位素平衡分馏效应使矿石硫稍富S~(34)。热变质过程中的硫同位素扩散分馏效应使矿石流稍富S~(32)。该区太古代层状岩系为金的潜在矿源,具有发现新矿化集中区和新类型金矿床的巨大潜力。根据金矿床硫同位素变化规律可进行深部成矿预测。  相似文献   

The influence of medium-range transport on O3 levels at a rural site in Israel     

Batia Lifshitz  Mordechai Peleg  Menachem Luria 《Journal of Atmospheric Chemistry》1988,7(1):19-33

Simultaneous ozone measurements were made at a rural site, 25 km SSW of the city of Jerusalem, and in the center of the city during a period of 28 months. The ozone data were supplemented by SO₂, NO/NO _x ,and meteorological measurements at both sites. Elevated ozone concentrations were recorded at the rural site, mostly during the spring months (May and June) during which the monthly averages and the monthly averages of the daily 30 min maximum levels equalled those measured in the city. During the summer months, both average and peak levels were lower at the rural site by 20 and 35 ppb. The increased ozone levels at the rural site were accompanied by a parallel increase of SO₂ and NO _x ,suggesting hat the excess ozone at the rural site is a result of a transformation during transport of air pollutants from coastal sources.  相似文献   

胶东金矿成矿系列硫同位素研究   总被引：24，自引：2，他引：24  

黄德业 《矿床地质》1994,13(1):75-87

胶东金矿的早晚两期成矿系列中，岩浆成因或在岩浆期即有天然水和表生矿质加入的矿床，δ＾３４Ｓ值均有自早而晚依次降低的规律。为重熔岩浆分异成矿理论和成矿系列的建立提供了重要证据。焦家式和某些晚期矿床，在形成矿液后有表生硫加入，扰乱了这一规律性。胶东群中的硫同位素没有达到均匀化，副变质岩偏重，而斜长角闪岩偏轻，接近陨石硫值，是近似原始岩浆的产物。  相似文献   

内蒙古乌拉山石英－钾长石脉金矿床铅和硫同位素研究   总被引：4，自引：1，他引：4  

聂凤军  裴荣富  吴良士  张洪涛 《矿床地质》1994,(2)

内蒙古乌拉山金矿床是近年在我国北方发现的大型金矿床之一。矿床主要由赋存在太古界乌拉山群变质岩地层中一系列石英－钾长石脉和石英脉组成。矿区范围内晚古生代—中生代花岗岩类分布广泛并且同金矿化具密切时、空分布关系。本文对乌拉山金矿床，大桦背花岗岩体和变质岩地层的硫、铅同位素比值进行了系统测定，并解释了不同地质体硫、铅同位素变化特征。研究表明：金成矿作用发生在２４０×１０￣６ａ，成矿物质主要来自大桦背花岗岩体及有关的岩脉，乌拉山金矿床形成过程中，亦有部分非岩浆物质混入。  相似文献   

辉碲铋矿单矿物的化学分析   总被引：1，自引：1，他引：1  

郑大中  郑若锋 《岩矿测试》1995,14(4):250-253

辉碲铋矿物经ＨＮＯ３－ＫＣｌＯ３溶解，用火焰原子吸收法或乙二胺四乙酸二钠事滴定法测定Ｂｉ，火焰原子吸收法测定Ｔｅ、Ｆｅ、Ｃｕ，３，３＇－二氨基联苯胺光度法测定Ｓｅ，硫酸重量法测定Ｓ。其结果与矿物化学成分理论值十分接近，主、次量元素平行测定６次，其ＲＳＤ小于０．８％，痕量元素ＲＳＤ（ｎ＝６）小于１０％。  相似文献