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101.
依托“西部煤炭资源高精度三维地震勘探技术”工程,对晋城矿区进行了旨在提高小断层,小陷落柱探测能力的高密度三维地震勘探。根据面元选择因素及该区地质任务,采用5m×5m网格进行野外数据采集;考虑炮检距、方位角、覆盖次数、排列片横纵比及煤层埋深(350~500m)等因素,采用中点放炮、60道接收,24次覆盖(横向4次,纵向6次)的8线16炮束状观测系统,基岩中激发。原始资料经同一处理流程后,获得5m×5m×1ms、5m×10m×1ms、10m×10m×1ms及2.5m×2.5m×1ms不同单元的三维数据体多个,通过对比可以发现小断层,小陷落柱在其小面元叠加时间剖面、顺层切片及相干切片都有清晰的反映。实例说明,小面元采集技术可以提高对小构造的纵、横向分辨能力,满足山区对三维地震精确勘探的要求。  相似文献   
102.
屯兰矿南五采区地形复杂,最大高差达271m,地表大面积为第四系黄土覆盖,激发困难。为探索研究小面元三维地震勘探技术的应用效果。在常规三维地震勘区域内划出1km^2,采用5m×5m小面元进行采集。在地震数据采集过程中,采取了加大激发井深、提高覆盖次数、减小CMP面元网格和加大接收排列等技术措施,做到“四小三高、二中一深、两个等高面”。通过插值、抽线及扩大面元处理。获得2.5m×2.5m×1ms、5m×5m×1ms、5m×10m×1ms、10m×10m×1ms以及不同叠加次数的三维数据体。资料解释工作主要是在5m×5m×1ms、2.5m×2.5m×1ms两个数据体上进行,解释落差大于或等于5m的断层6条,落差3~5m的断层8条;查明长轴直径20~30m的陷落柱4个。30~100m的陷落柱1个,大于100m的陷落柱3个。与相邻区常规三维地震比较,小面元三维地震勘探有利于对小陷落柱、小断层的控制和解释。  相似文献   
103.
以流线、流面、汇点的概念为基础,对稳定流双井干扰和直线隔水边界附近涌水量理论公式进行对比分析,提出了二个虚拟界面,其中虚拟界面Ⅰ,运用流线、流面的性质,流线方程等给出证明;虚拟界面Ⅱ则通过半无限条形降落漏斗的分析,应用元流和总流的能量方程得到流量为零,流线为零的平面。在同样条件下,条形无限涌水量是半无限潜含水层涌水量的二倍。应用总流能量方程对三种情况水头损失的分析,解释了这种关系存在的合理性,得出虚拟界面Ⅱ,并以此得出该界面内的最大残余水头计算公式。将基坑降水运用虚拟界面简化为扇形,条形半无限含水层,从而实现单井预测,该方法应用到昊华水泥厂基坑降水中,预测效果理想。  相似文献   
104.
在山区或地表复杂地区进行地震勘探,采用基于地表一致性假设的静校正将会严重影响勘探效果,该影响主要源于地表一致性假设存在着不合理因素。如较高的低速带、巨厚的低速带、基岩裸露、地形起伏较大等。为分析一致性假设静校正偏差产生的原因及大小.构建一地形起伏、基岩出露的复杂模型,通过正演其射线路径,对比其时距曲线与理论时距曲线的差异,以及二者静校正量误差大小。模型分析证实该差异与偏移距、地震波穿透深度及基准面高程之间存在直接的联系,据此提出了改进方法,如浮动基准面校正及分块静校正等。理论模型和实际地震资料试算表明,使用改进的方法可有效改善地震时间刮面同相轴聚焦效果及连续性。  相似文献   
105.
Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O3+R1R2C=CH2 (HCHO+R1R2COO)+(1–)(R1COR2+H2COO) where formaldehyde and the ketone R1 COR2 are the primary carbonyls and R1R2COO and H2COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H2COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R1R2COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.  相似文献   
106.
The survey for the HEIFE(Atmosphere-Land Surface Processes Experiment at Heihe River Basin,Western China) is given in the paper.The following basic subjects for land-surface processes in arid areas are studied:(1) the general characteristics of the energy budget on ground surface in arid areas;(2) the parameterization of the land surface processes;(3) the interaction between oasis and its desert circumstances,a special phenomenon in arid areas.The analysis shows that the sensible heat flux in the surface energy budget is in the majority,and the latent heat flux may be neglected.The influence of atmospheric stratification stability on the turbulent transfer of energy and substance must be considered in parameterization of land surface processes in arid areas.The "cold island effect" phenomenon in oasis and the "humidity inversion" phenomenon in desert near oasis are the result of the interaction between them.The results would improve the understanding of land surface processes in arid areas.  相似文献   
107.
In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.  相似文献   
108.
The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > FeIII-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)3(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.  相似文献   
109.
The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.  相似文献   
110.
Bivariate and trivariate functions for interpolation from scattered data are derived. They are constructed by explicit minimization of a general smoothness functional, and they include a tension parameter that controls the character of the interpolation function (e.g., for bivariate case the surface can be tuned from a membrane to a thin steel plate), Tension can be applied also in a chosen direction, for modeling of phenomena with a simple type of anisotropy. The functions have regular derivatives of all orders everywhere. This makes them suitable for analysis of surface geometry and for direct application in models where derivatives are necessary. For processing of large datasets (thousands of data points), which are now common in geosciences, a segmentation algorithm with a flexible size of overlapping neighborhood is presented. Simple examples demonstrating flexibility and accuracy of the functions are presented.On leave from the Department of Physical Geography and Cartography, Comenius University, Mlynská dolina, Bratislava, Czechoslovakia.On leave from the Institute of Physics, Dúbravská cesta 9, Bratislava, Czechoslovakia.  相似文献   
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