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大洋多金属结核中1nm锰矿相的相变及其主要控制因素研究   总被引:1,自引:3,他引:1  
多金属结核样品在室温中放置或加热干燥后 ,其中的 1nm锰矿相会部分或全部地相变为 0 7nm锰矿相 ,这说明 0 7nm锰矿相可能不是多金属结核的原生锰矿相 ,而仅仅是 1nm锰矿相的相变产物。研究结果表明 :1nm锰矿相结构中的Cu2 + 、Co2 + 、Ni2 + 等金属阳离子的含量与其结构稳定性有正相关关系 ,即金属离子含量越高 ,其结构越稳定 ,1nm锰矿相越不易相变为 0 7nm锰矿相 ,反之亦然 ;另外 ,不同金属阳离子稳定 1nm锰矿相结构的能力也不同 ,结核中几种主要金属阳离子对 1nm锰矿相结构的稳定能力从大到小为 :Ni2 + >Cu2 + >Co2 + >Zn2 + >Ca2 + =Mg2 + 。  相似文献   
64.
湖北省南漳县震旦系沉积型红星磷矿矿体P_2O_5平均含量23.91%,矿石自然类型主要为角砾状磷块岩,其次为白云质磷块岩、泥质纹层状和条带状致密块状磷块岩。工业类型主要为钙(镁)质和硅钙(镁)质磷矿,其次为硅质磷矿。矿石矿物为胶状磷灰石和微晶磷灰石,经x-射线衍射物相分析,其种属为含碳氟磷灰石。嵌布粒度以细-中粒为主。脉石矿物主要为白云石、伊利石、高岭石、铁质。经测定当磷块岩磨矿粒度小于0.1mm,其磷酸盐矿物单体解离率可达92.53%,这为确定合理的选矿流程具有实际意义。  相似文献   
65.
大张坨凝析气藏是在我国发现的高含量凝析气藏之—.开发中据相态特征及流体组份研究结果,适时调整开发方式.1994年开始试采,1995年初实施循环注气开发.该气藏的开发经历了衰竭试采循环注气2个开采过程,开发过程中定期取地层流体样品进行相态特征和流体组份研究,并注重其成果的应用,凝折油采出率29.0%,取得了较好的开发效果.证实了相态研究在凝析气藏循环注气开发全过程应用的重要性.  相似文献   
66.
A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.  相似文献   
67.
Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the kSp relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent kSp relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions.  相似文献   
68.
Predictions from dynamic modelling of the lithospheric deformation are presented for Northern Europe, where several basins underwent inversion during the Late Cretaceous and Early Cenozoic and contemporary uplift and erosion of sediments occurred. In order to analyse the evolution of the continental lithosphere, the equations for the deformation of a continuum are solved numerically under thin sheet assumption for the lithosphere. The most important stress sources are assumed to be the Late Cretaceous Alpine tectonics; localized rheological heterogeneities can also affect local deformation and stress patterns. Present-day observations available in the studied region and coming from seismic structural interpretations and stress measurements have been used to constrain the model. Our modelling results show that lateral variation in lithospheric strength below the basin systems in Central Europe strongly controls the regional deformation and the stress regime. Furthermore, we have demonstrated that the geometry of the boundary between Baltica and Avalonia, together with different rheological characteristics of the two plates, had a crucial role on local crustal deformation and faulting regime resulting in the Baltica–Avalonia transition zone from the S–N Alpine convergence.  相似文献   
69.
The numerical models of mantle convection agree to depict avalanches behaviour according to the level of endothermicity of the spinel → perovskite phase change. Their potential effects on the global thermal and dynamical states of the mantle have been computed thanks to a numerical code, which takes into account both the 400-km exothermic and the 660-km endothermic phase changes. The cycle followed by the avalanches is: local layering, destabilization of the 660-km thermal layer, travelling and spreading on the core, and reappearing of the local layering. Therefore, mantle convection is characterized by quiet periods of partial layering embedded in catastrophic events. During the avalanche, the amplitude of the surface velocity is multiplied by two, which would imply an enhanced plate tectonic and ridge activities. The global thermal effects of the avalanche are compatible with a high mantle temperature and an acceleration of Earth's rotation during the Cretaceous. They also offer a coherent explanation to locate the origin of mantle plumes both within the CMB and just below the transition zone.  相似文献   
70.
冬季北极涛动和华北冬季气温变化关系研究   总被引:33,自引:6,他引:33  
利用北极涛动指数(AOI)、NCEP/NCAR40a再分析资料中的海平面气压(SLP)、850、500、200hPa等压面高度场资料及中国160站月平均气温资料,运用小波分析,经验正交函数(EOF)分析等方法,分析了华北冬季气温和冬季北极涛动指数的变化特征及其关系。结果表明它们之间存在有着显著相关,特别是在年代际尺度上关系尤其密切。华北在20世纪70年代初以前为持续冷冬,80年代中期之后变为持续暖冬,其间相对正常,而冬季北极涛运指数亦存在类似的3个阶段,冬季北极涛动高(低)低数年,华北地区为暖(冷)冬年。其原因在于,北极涛动在于对流层低层和高层都可激发类似EU遥相关型的异常,通过影响西伯利亚高压和东亚大槽影响华北地区气温。强(弱)涛运年大气环流具有弱(强)东亚冬季风特征,西伯利亚高压减弱(增强),亚洲大陆地面东北风减弱(增强),高空东亚大槽减弱(增强)。  相似文献   
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