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1.
Crystallization under confinement conditions is a very important process in geochemistry and geophysics. Computer simulations of fluids in nanometer scale pore spaces can provide a unique microscopic insight into the structure, dynamics and forces arising from the crystallization process. We discuss in this paper molecular dynamics computer simulations of crystallization in pores of nanometer dimensions. The crystallization pressure due to the freezing of a model of Argon in a nanopore is computed using molecular dynamics simulations. We also investigate the influence of pore geometry in determining the dynamics of confined fluids, as well as mass separation in binary mixtures. It turns out that the pore geometry reveals itself as an important variable, leading to 1) new mechanisms for fast diffusion in confined spaces, and 2) accumulation of solute in specific regions inside the pore. 相似文献
2.
Neal T. Skipper Peter A. Lock James O. Titiloye Jan Swenson Zakaria A. Mirza W. Spencer Howells Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196
The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH3OD and (CH2OD)2 in deuterated clay allows us to measure the diffusion of the CH3- and CH2-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution. 相似文献
3.
大开间小型混凝土砌块10层模型房屋抗震性能试验研究(Ⅰ) 总被引:8,自引:3,他引:8
我国抗震设计规范(GB50011-2001)规定在6、7、8度区,混凝土小砌块结构分别可以建七、六、五层。由于混凝土小砌块结构的最大优势在于10-20层(与混凝土框架或框架剪力墙结构比)。本文按1/4比例制作了10层混凝土小砌块结构模型,按7度设防要求实施构造措施,通过振动台试验研究模型结构的抗震性能。结果表明,模型结构完全能够满足在7度区“小震不坏,大震不倒”的要求。圈梁、构造柱以及水平拉结筋构成的约束体系抗震作用是明显的。试验利用砌块的非注芯孔灌注铁砂来模拟墙体出平面动力效应。在本模型的构造措施下,平出面反应不对结构破坏起控制作用。 相似文献
4.
5.
This study tests the assumption that the characteristics of channels within multiple channel rivers are different from those of single channel rivers. Some river restoration approaches propose radical transformation of river patterns, from multiple to single channels, based on the link between river patterns and their in-channel characteristics. Determining the links between river patterns and their in-channel characteristics is complicated by differences in geology, history, climate and discharge among rivers. Furthermore, multiple channel rivers are composed of a mosaic of channel types with a range of in-channel characteristics. This study minimizes these problems by analysing a single river containing neighbouring single and multiple channel patterns with little change in discharge downstream, and by analysing all channel types. The study addressed two objectives: to determine the hydraulic geometry, energy, and sediment mobility characteristics of neighbouring single and multiple channel river patterns, and to test for statistical differences in these characteristics between patterns. The Renous River shows a wandering pattern for 11.5 km, with multiple channels around semipermanent islands and abandoned channels in the flood plain. The river displays a single channel river pattern where channels are confined by their valley walls, upstream and downstream of wandering. The analysis was conducted at three scales. First, the confined single channel and wandering multiple channel patterns were compared (pattern scale). Second, the confined channel pattern was compared to single and multiple channel sections within the wandering pattern (section scale). Third, all channel types were compared (channel type scale). Multi response permutation procedure (MRPP) and analysis of variance (ANOVA) were used to analyze differences between channels. Difference tests found no simple discrimination between the single and multiple channel river patterns of the Renous River. Tests between the single confined and multiple wandering channel patterns found few differences in the in-channel variables. The tests did find differences between multiple channel sections within the wandering pattern and confined single channels; however, a greater number of differences were found between multiple channel and single channel sections within the wandering pattern, highlighting the variability within the wandering pattern. Two groups emerged when all channel types were tested for differences: perennial main-channels containing the thalweg, and ephemeral side-channels. Therefore, side-channels define the in-channel characteristics of wandering rivers because few differences were found among main-channels in either pattern. This analysis suggests that all channel types, not just main-channels, should be investigated to obtain a complete picture of a river pattern prior to any restoration efforts. Engineers must exercise caution when applying the link between river patterns and in-channel characteristics to river restoration efforts. 相似文献
6.
F. Colangelo 《地震工程与结构动力学》2005,34(10):1219-1241
This paper presents pseudo‐dynamic test results on the in‐plane seismic behaviour of infilled frames. Thirteen single‐storey, single‐bay, half‐size‐scale, reinforced concrete‐frame specimens, most of which infilled with non‐structural masonry made of perforated bricks and cement mortar are tested. The infills are in contact with frames, without any connector; openings are not covered. The frames are different in their strength and details, reinforcement grade, and aspect ratio. Seismic input is the 1976 Tolmezzo (Friuli, Italy) ground acceleration, to which specimens are subjected two times: virgin and damaged by the previous test. The global seismic response of initially virgin infilled specimens considerably differs from that of bare specimens. This follows a dramatic change of properties: compared to a bare frame, the initial stiffness increases by one order of magnitude, and the peak strength more than doubles. The peak drift lessens; however, the displacement ductility demand does not. The energy demand is greater. Nevertheless, the influence of infill decreases as damage proceeds. Displacement time histories of damaged specimens are quite similar. At the local level, infill causes asymmetry and concentration of the frame deformation. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
7.
Uur Doan 《Geomorphology》2005,71(3-4):389-401
Karstification-based land subsidence was found in the Upper Tigris Basin with dimensions not seen anywhere else in Turkey. The area of land subsidence, where there are secondary and tertiary subsidence developments, reaches 140 km2. Subsidence depth ranges between 40 and 70 m. The subsidence was formed as a result of subsurface gypsum dissolution in Lower Miocene formation. Although there are limestones together with gypsum and Eocene limestone below them in the area, a subsidence with such a large area is indicative of karstification in the gypsum. The stratigraphical cross-sections taken from the wells and the water analyses also verify this fact. The Lower Miocene gypsum, which shows confined aquifer features, was completely dissolved by the aggressive waters injected from the top and discharged through by Zellek Fault. This resulted in the development of subsidence and formation of caprock dolines on loosely textured Upper Miocene–Pliocene cover formations. The Tigris River runs through the subsidence area between Batman and Bismil. There are four terrace levels as T1 (40 m), T2 (30 m), T3 (10 m) and T4 (4–5 m) in the Tigris River valley. It was also found that there were some movements of the levels of the terraces in the valley by subsidence. The subsidence developed gradually throughout the Quaternary; however no terrace was formed purely because of subsidence. 相似文献
8.
具有悠久历史的石结构是砌体结构的重要组成部分,本文作者经广泛调研和试验分析:(1)提出以石粉为集料对石砌体进行抗震加固,寓环保与防灾于一体;(2)给出新型浆体配比和复合砂浆的强度等级,阐述加固技术和方法,建立灌浆石砌体抗震抗剪强度公式;(3)阐明抗震验算方法,提出基于模糊随机可靠理论的可靠性分析方法。 相似文献
9.
Two procedures are developed and implemented in a hybrid simulation system (HSS) with the aim of enhancing the accuracy and reliability of the online, i.e. pseudo‐dynamic, test results. The first procedure aims at correcting the experimental systematic error in executing the displacement command signal. The error is calculated as the difference between command and feedback signals and correlated to the actuator velocity using the least‐squares method. A feed‐forward error compensation scheme is devised leading to a more accurate execution of the test. The second procedure employs mixed variables with mode switching between displacement and force controls. The newly derived force control algorithm is evaluated using a parametric study to assess its stability and accuracy. The implementation of the mixed variables procedure is designed to adopt force control for high stiffness states of the structural response and displacement control otherwise, where the resolution of the involved instruments may favour this type of mixed control. A simple pseudo‐dynamic experiment of steel cantilever members is used to validate the HSS. Moreover, two experiments as application examples for the two developed procedures are presented. The two experiments focus on the seismic response of (a) timber shear walls and (b) reinforced concrete frames with and without unreinforced masonry infill wall. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
10.
Historic masonry buildings in seismically active regions are severely damaged by earthquakes, since they certainly have not been explicitly designed by the original builders to withstand seismic effects, at least not in a ‘scientific’ way from today’s point of view. The assessment of their seismic safety is an important first step in planning the appropriate interventions for improving their pertinent resistance. This paper presents a procedure for assessing the seismic safety of historic masonry buildings based on measurements of their natural frequencies and numerical simulations. The modelling of the brittle nonlinear behaviour of masonry is carried out on the macro-level. As an example, a recently completed investigation of the seismic behaviour of the Aachen Cathedral is given, this being the first German cultural monument to be included in the UNESCO cultural heritage list in 1978. Its construction goes back to the 9th century a.d. and it is considered as one of the finest examples of religious architecture in Central Europe. The investigation is based on measurements of the natural frequencies at different positions and numerical simulations using a detailed finite element model of the Cathedral. 相似文献