快速城镇化进程中珠江三角洲高铵地下水赋存环境及驱动因素          下载免费PDF全文

吕晓立  刘景涛  韩占涛  朱亮  杨明楠  李海军 《中国地质》2021,48(6):1770-1780

地下水中高浓度的铵态氮对生活饮用水安全及生态环境存在潜在威胁。相比较硝态氮，高浓度的铵态氮不仅有各种人为来源，天然沉积环境更是造成高铵地下水的主要成因。本文以城镇化快速发展的珠江三角洲为研究区，运用数理统计、主成分分析等方法深入探讨了研究区高铵地下水的赋存环境特征及驱动因素。结果表明，研究区地下水中NH₄⁺质量浓度介于未检出~180 mg/L。研究区1539组地下水样品中，NH₄⁺质量浓度大于10 mg/L的高铵地下水69组，其中含NH₄⁺质量浓度大于30 mg/L的高铵"肥水"23组。对比2005-2008年历史水化学数据，2009-2018年新增建设用地孔隙含水层高铵地下水样品比例增加25%。高铵地下水呈斑块状分布于三角洲平原区第四系底部低洼的基底、洼地等退积层序发育的淤泥质含水层中。淤泥层等富含有机质和总有机碳的沉积层是珠江三角洲地区的"生铵层"，有机氮的矿化是三角洲平原区城市化孔隙含水层中高铵地下水的主要驱动力。城镇化扩张引起生活污水及富铵工业废水的泄漏入渗是城乡结合部高铵地下水铵氮的重要来源。三角洲平原区中性至弱碱性富含有机质的还原环境是高铵地下水的主要成因。风化溶滤、阳离子交换吸附、海陆交互作用是珠江三角洲高铵地下水质演变的主要水文地球化学过程。  相似文献   

地下连续墙治理地下水污染   总被引：12，自引：1，他引：11  

丛蔼森 《地质与勘探》1997,33(1):59-64

介绍一种治理已被严重污染的地下水的方法。即修建一道底部深入到不透水岩层的地下墙,把污染物封闭在由底部不透水岩层和周围地下防渗墙组成的“地下盆”中,降低周围地下水中有害物质的浓度,然后再治理封闭圈内的污染物,以达到彻底根治地下水污染的目的。  相似文献   

漳州热田的对流热流和传导热流的研究   总被引：5，自引：1，他引：4       下载免费PDF全文

熊亮萍  汪集YANG 《地球物理学报》1990,33(6):702-711

漳州地热系统属对流型地热系统.漳州热田是我国东南沿海地区目前所见热田中温度最高（121.5℃）的一个.地表热流值的研究表明,热田中心具有最大的实测热流值（359mw/m²）.本文根据热田内152个钻孔的测温资料和56块岩石样品的热导率数据,采用三种不同方法计算出漳州热田及其邻近地区的大地热流值,并讨论了热流值分布的特点.  相似文献   

论四川盆地三叠系地下水水文地质条件   总被引：3，自引：0，他引：3       下载免费PDF全文

林耀庭 《盐湖研究》2006,14(1):1-8

四川盆地三叠系地下水可划分出碎屑岩孔隙裂隙和碳酸盐岩岩溶裂隙两大储集类型。按此处构造开启程度和埋深条件等的不同,下中三叠统地下水有沉积变质水和渗入淋滤水两种基本成因类型,水动力特征各异。沉积变质水处于深埋封闭条件,受地静压力驱动控制;渗入淋滤水分布于背斜露头区和浅部地区,受静水压力驱动控制。并由此控制了盆地三叠系盐类的保存条件。  相似文献   

中国科学院院士 薛禹群     

《水文地质工程地质》2006,33(5):F0002-F0002

薛禹群，地下水动力学家和水文地质学家，擅长地下水数值模拟，南京大学地球科学系教授，博士生导师，中国科学院院士，1931年11月2日生于江苏无锡。1952年7月毕业于北方交通大学唐山工学院。  相似文献   

亚利桑那州的巨型干裂缝     

Raymond  C．Harris  于小芳 《水文地质工程地质技术方法动态》2006,(6):33-35

自1998年以来，亚利桑那州地质调查局就收到许多州周边大范围多个分散地点出现新裂缝的有关报告。此前90年代中期，报告的大部分裂缝均是人们所熟悉的类型，即开采地下水造成地面塌陷引发的地裂缝。然而，这些新裂缝大部分被证明具有不同的诱因——富含粘土的土壤或沉积物的干燥或被烘干。通过绘制这些被报道裂缝的地图及观察其航空照片，结果显示，这些“巨型干裂缝（GDC）”要比预先想象的普遍的多，并且比由开采地下水引起的地裂缝广泛的多。通过绘制亚利桑那州这些巨型干裂缝的地图，最近完成的一项研究证明了勘测的结果。这篇文章概述了那篇报道。  相似文献   

A study of fluoride occurrence in groundwater and dental fluorosis in Nathenje, Lilongwe, Malawi     

《中国地球化学学报》2006,25(B08):60-60

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XANES analysis of the mechanisms of arsenic removal in biological iron and manganese treatment unit     

Yoko Fujikawa Daisuke Yoneda Atushi Minami Hiroshi Yashima Toshio Tonokai Sotoji Tani Masami Fukui Tatuhide Hamasaki Masataka Sugahara 《中国地球化学学报》2006,25(B08):113-113

Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria （IRB hereafter） in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As （Ⅲ）] removal. The floc samples were collected from two drinking water plants using IRB （Jyoyo and Yamatokoriyama, Japan）, and our pilot - scale test site where arsenic and iron removal using IRB is under way （Mukoh, Japan）. The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As （Ⅲ） and As（Ⅴ） sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 （Hyogo, Japan）. FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in ＋5 valence state when As （Ⅲ） （or As （Ⅴ）） was added in laboratory sorption test, Fe in ＋3 valence state, and Mn a mixture of＋3 and ＋4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As （Ⅲ） associated with IRB or change in arsenic binding with sorption site were the probable mechanism.  相似文献   

Metal contamination in southern Brazil vineyard softs     

《中国地球化学学报》2006,25(B08):120-120

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Synergistic effect of combining sulfate reducing bacteria and zerovalent iron permeable reactive barriers on the treatment of groundwater rich in uranium, sulfate and heavy metals     

Zhengji YI Kaixuan TAN Zhenxun YU Aili TAN Shiqiang WANG 《中国地球化学学报》2006,25(B08):125-126

Uranium processing and mining activities that generate many contaminants, such as high concentrations of U （VI）, sulfate and heavy metals （Zn, Cu, Ni, etc）, may pose a serious threat to the groundwater resources. In recent years, considerable research has been conducted respectively on two kinds of permeable reactive barriers （PRB）, including zerovalent iron （ZVI） and sulfate reducing bacteria （SRB）, for in-situ removal of these pollutants from groundwater. However, little investigation has been carried out on the potential benefits of bioaugmenting ZVI barriers to enhance the elimination of the pollutants by combining ZVI with SRB systems. The main goal of this study was to conduct batch and column experiments to determine whether the combination of SRB and ZVI can function synergistically and accelerate the rate of pollutant removal. The results of anaerobic batch experiments demonstrated that although the integrated ZVI/PRB system itself has no ability to reduce and remove sulfate directly, SRB can utilize hydrogen gas produced during the slow process of ZVI corrosion as an electron donor to raise biomass yields significantly and accelerate reductive sulfate removal. In particular, ferrous cations produced as the byproduct of ZVI corrosion process reacted with hydrogen sulfide from sulfate reduction and formed iron-bearing sulfide precipitates, which can stimulate the growth of SRB and promote sulfate removal activity by eliminating the biotoxicity of hydrogen sulfide. It was also shown that secondary mineral products （pyrite/ferrous sulfide） formed as a consequence of microbial sulfate reduction and ZVI corrosion process can enhance the microbial precipitation of soluble U （VI） as insoluble uraninite（uranium dioxide）.  相似文献