Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska     

Robert G. Eppinger Paul H. Briggs Cynthia Dusel-Bacon Stuart A. Giles Larry P. Gough Jane M.Hammarstrom Bernard E. Hubbard 《中国地球化学学报》2006,25(B08):232-232

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.  相似文献   

Changes to cadmium associations in canal sediments on drying and oxidation     

Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.  相似文献   

Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China     

Fan YANG Qinghui HUANG Jianhua LI Xiaomin ZHU 《中国地球化学学报》2006,25(B08):262-262

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.  相似文献   

Effect of particles on the photodegradation of PAHs in natural waters-A case study for the Yellow River     

Xinghui XIA 《中国地球化学学报》2006,25(B08):263-263

Photodegradation of chrysene, benzo （a） pyrene and benzo （g, h, i） perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. （1） The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. （2） The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo （a） pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo （g, h, i） perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. （3） The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. （4） Since the soluble humic substances in the suspended solids of the river have been dissolved in water,  相似文献   

新疆三工河流域冲洪积平原区潜水蒸发特征与潜水调控     

孙宝林  魏守忠  马健  杨瑾  刘绿林 《地下水》2005,27(5):352-353

利用三工河阜北地下水潜水均衡试验场资料,对该区潜水有效蒸发期4～10月的潜水蒸发量特征进行了分析,提出了该区潜水埋深调控范围.  相似文献   

盛源盆地南部铀成矿水文地球化学条件分析     

石平 《铀矿地质》2005,21(1):38-44,51

本文阐述了盛源盆地南部铀成矿的地质、水文地质和水文地球化学条件 ,分析了区内放射性水异常的产出、分布特征和控制因素 ,认为坝口等地段水的循环深度大 ,深部氧化 还原过渡带发育 ,大面积、交互叠加的放射性水异常是寻找大型隐伏铀矿床的重要标志。  相似文献   

吐哈盆地十红滩铀矿床水文地球化学特征   总被引：6，自引：0，他引：6  

乔海明  张天太  张复新  尚高峰  宋哲 《铀矿地质》2005,21(6):345-352

本文根据水化学资料的研究,探讨了十红滩铀矿床含矿含水层高矿化度地下水的成因,分析了高矿化度水对铀溶解迁移的影响及碳酸盐的形成机理.  相似文献   

水文信息处理系统研究     

舒大兴 王健郑召平  刘易娜肖泰峰 李丽华 《水文》2005,25(3):26-29

水文信息处理系统是在Windows环境下、用Visual Basic 6．0高级语言研制开发的智能水文资料整编软件，引用数据库存储信息，调用Excel输出整编成果。该软件实现了水位、流量、泥沙等要素关系线的自动生成和人工辅助定线，并完成全部整编计算工作，结束了我国水文资料电算整编工作中依靠手工定线整编的历史，解决了计算机定线、推流和成果输出一次完成的技术难题，真正实现了水文资料整编计算机化。  相似文献   

MapGIS下空间数据库的建立及其典型问题研究   总被引：4，自引：0，他引：4  

李定平  胡光道  程路 《武汉大学学报(信息科学版)》2005,30(11):1029-1032

以云南省地质图、水文地质图空间数据库的建立为例,通过对空间数据库建设中资料准备、图形矢量化、空间数据处理及文件转换四个过程的分析,总结了在进行回溯型空间数据库建库过程中需要注意的一些典型问题,并提出了解决的办法。论述了在MapGIS下空间数据库建立过程中的一些技巧及经验。  相似文献   

构建土地利用规划评审体系的思路     

周炜  余宝林 《河北国土资源》2005,(2):12-14

土地利用规划(以下简称土地规划)评审，就是对土地规划行为(包括编制、实施)的技术评价、法律审查与行政授权活动。土地规划评审体系包括评审机构、制度及准则等，属于广义的土地规划管理范畴(狭义的规划管理仅指规划对建设引导和制约行为)。如果说土地规划是对土地资源利用的调控，规划评审就是对土地规划的调控，只有对“龙头”驾驭得当，  相似文献