The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol. 相似文献
Subsidence mechanisms that may have controlled the evolution of the eastern Black Sea have been studied and simulated using a numerical model that integrates structural, thermal, isostatic and surface processes in both two- (2-D) and three-dimensions (3-D). The model enables the forward modelling of extensional basin evolution followed by deformation due to subsequent extensional and compressional events. Seismic data show that the eastern Black Sea has evolved via a sequence of interrelated tectonic events that began with early Tertiary rifting followed by several phases of compression, mainly confined to the edges of the basin. A large magnitude (approximately 12 km) of regional subsidence also occurred in the central basin throughout the Tertiary. Models that simulate the magnitude of observed fault controlled extension (β=1.13) do not reproduce the total depth of the basin. Similarly, the modelling of compressional deformation around the edges of the basin does little to enhance subsidence in the central basin. A modelling approach that quantifies lithosphere extension according to the amount of observed crustal thinning and thickening across the basin provides the closest match to overall subsidence. The modelling also shows that deep crustal and mantle–lithosphere processes can significantly influence the rate and magnitude of syn- to post-rift subsidence and shows that such mechanisms may have played an important role in forming the anomalously thin syn-rift and thick Miocene–Quaternary sequences observed in the basin. It is also suggested that extension of a 40–45 km thick pre-rift crust is required to generate the observed magnitude of total subsidence when considering a realistic bathymetry. 相似文献
We have investigated a well-ordered sample of natural Cr-bearing dickite from Nowa Ruda (Lower Silesia, Poland) using electron
paramagnetic resonance (EPR) at X- and Q-band frequencies (9.42 and 33.97 GHz, respectively) and optical diffuse reflectance
spectroscopy. The observation of the spin-forbidden transitions at 15500 and 14690 cm−1 allows us to unambiguously identify the major contribution of octahedrally coordinated Cr3+ ions in the optical spectrum. The X- and Q-band EPR spectra show two superposed Cr3+ signals. The corresponding fine-structure parameters were determined at room temperature and 145 K. These results suggest
the substitution of Cr3+ for Al3+ in equal proportions in the two unequivalent octahedral sites of the dickite structure. In kaolin group minerals, the distortion
around Cr3+ ions (λ≈ 0.2–0.4) in Al sites is significantly less rhombic than that observed around Fe3+ ions (λ≈ 0.6–0.8).
Received: 29 June 2001 / Accepted: 22 October 2001 相似文献
As a result of the collapse of the Aznalcollar mine tailings dam, a large extension of the Guadiamar valley in SW Spain was covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil, constituting a potential source of water pollution. A column experiment was carried out in order to determine the rate of sludge oxidation in the soil, and the existence of metal retention processes. The column was filled with a mixture of sludge and a sandy soil common in the region. At different time intervals, the column was leached with water and the resulting solution analysed.
The pH of the water dropped to values around 2 after 260 days and then remained constant due to the buffering role of silicate dissolution. The concentration of Zn, Cd and Co in the leachates matched the expected values from flow-through experiments at atmospheric oxygen pressure. This indicates that oxygen diffusion in the pores was complete. Moreover, no efficient processes existed for retaining Zn, Cd and Co, which formed soluble salts and were entirely incorporated into the infiltrating water. During the first 2 months of the experiment, when pH was higher than 4.5, the concentrations of Fe and Al were very low. Saturation indices showed that the solution was in equilibrium with amorphous Fe(OH)3 and Al(OH)3. Subsequently, at lower pH values, jarosite [(Na,K)Fe3(SO4)2(OH)6] formed. This solid phase was identified by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Jarosite was also responsible for the depletion of As, Pb, Sb and probably Tl in the water resulting from infiltration. 相似文献
Magma mixing structures from the lava flow of Lesbos (Greece) are analyzed in three dimensions using a technique that, starting from the serial sections of rock cubes, allows the reconstruction of the spatial distribution of magmas inside rocks. Two main kinds of coexisting structures are observed: (i) “active regions” (AR) in which magmas mix intimately generating wide contact surfaces and (ii) “coherent regions” (CR) of more mafic magma that have a globular shape and do not show large deformations. The intensity of mingling is quantified by calculating both the interfacial area (IA) between interacting magmas and the fractal dimension of the reconstructed structures. Results show that the fractal dimension is linearly correlated with the logarithm of interfacial area allowing discrimination among different intensities of mingling.
The process of mingling of magmas is simulated using a three-dimensional chaotic dynamical system consisting of stretching and folding processes. The intensity of mingling is measured by calculating the interfacial area between interacting magmas and the fractal dimension, as for natural magma mixing structures. Results suggest that, as in the natural case, the fractal dimension is linearly correlated with the logarithm of the interfacial area allowing to conclude that magma mixing can be regarded as a chaotic process.
Since chemical exchange and physical dispersion of one magma inside another by stretching and folding are closely related, we performed coupled numerical simulations of chaotic advection and chemical diffusion in three dimensions. Our analysis reveals the occurrence in the same system of “active mixing regions” and “coherent regions” analogous to those observed in nature. We will show that the dynamic processes are able to generate magmas with wide spatial heterogeneity related to the occurrence of magmatic enclaves inside host rocks in both plutonic and volcanic environments. 相似文献
Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn2+- and Fe3+-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE). 相似文献
