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51.
The Upper Miocene and Pliocene evaporite deposits of the Atacama Desert of northern Chile (Hilaricos and Soledad Formations) are among the few non‐marine evaporites in which aridity not only formed the deposits, but has also preserved them almost unaltered under near‐surface conditions. These deposits are largely composed of displacive Ca sulphate and halite together with minor amounts of glauberite, thenardite and polyhalite. However, at the base and top of these deposits, there are also beds of gypsum crystal pseudomorphs that originally formed as free‐growth forms within shallow brine bodies, rather than as displacive sediments. The halite is present as interstitial cement, displacive cubes and shallow‐water, bottom‐growth chevron crusts. Most of the calcium sulphate is presently anhydrite, pseudomorphous after gypsum, that was the primary depositional sulphate mineral. The secondary anhydrite formed under early diagenetic conditions after slight burial (some metres) resulting from the effect of strongly evolved pore brines. The anhydrite has been preserved without rehydration during late diagenetic and exhumation stages on account of the arid environment of the Atacama Desert. Both the Hilaricos and the Soledad Formations contain geochemical markers indicating that these Neogene evaporites had a largely non‐marine origin. Bromine content in the halite is very low (few p.p.m.), indicating neither a sedimentological relation with sea water nor the likelihood of direct recycling of prior marine halites. Moreover, the δ34S of sulphates (+4·5‰ to +9‰) also reflects a non‐marine origin, with a strong volcanic influence, although some recycling of Mesozoic marine sulphates cannot be ruled out. δ34S of dissolved sulphate from hot springs and streams in the area commonly displays positive values (+2‰ to +10‰). Leaching of oxidized sulphur and chlorine compounds from volcanoes and epithermal ore bodies, very common in the associated drainage areas, have been the main contribution to the accumulation of evaporites. The sedimentary and diagenetic evolution of the Hilaricos and Soledad evaporites (based on lithofacies analysis) provides information about the palaeohydrological conditions in the Central Depression of northern Chile during the Neogene. In addition, the diagenesis and exhumation history of these evaporites confirms the persistence of strongly arid conditions from Late Miocene until the present. A final phase of tectonism took place permitting the internal drainage to change and open to the sea, resulting in dissolution and removal of a significant portion of these deposits. Despite the extensive dissolution, the remaining evaporites have undergone little late exhumational hydration.  相似文献   
52.
硫代金刚烷在原油中普遍存在,其独特的分子结构和形成过程使其在石油工业中具有广泛应用。对目前在硫代金刚烷分析鉴别、成因机制、热稳定性和在油气领域应用等方面的研究进展及存在问题进行了系统总结。结果表明:目前原油中硫代金刚烷主要包括烃源岩生烃演化和热化学硫酸盐还原(TSR)作用两种成因机制,其中烃源岩生烃演化可形成原油中初始含量的硫代金刚烷,TSR作用可进一步生成大量的硫代金刚烷;硫代金刚烷的笼数越高热稳定性越高,在高成熟时可以发生热裂解作用;硫代金刚烷随TSR作用增强而不断富集,是TSR作用可靠的分子标志物;硫代金刚烷的δ^34S值通过TSR作用来改变,能够反映TSR作用的成因类型;在未遭受TSR作用的前提下,原油中硫代金刚烷的初始含量和δ^34S值代表着原始烃源岩的特征,可以应用于原油族群的划分。从目前的研究现状来看,硫代金刚烷的具体成因机制和详细的热稳定性界限还不甚明确;应用硫代金刚烷的含量来判识TSR作用时,要结合硫同位素和其他指标参数等结果才最为可靠;硫代金刚烷目前主要应用于TSR作用判识研究,在油-油对比和油-源对比方面的研究尚待进一步加强。  相似文献   
53.
An orbital solution for the MACHO*05:34:41.3–69:31:39 eclipsing binary system is presented, based on the published light curve and spectral data obtained with the 2.15-m telescope at CASLEO. Based on these spectroscopic observations, the binary components of this system were classified as O3 If* and O6:V respectively. The radial velocity data along with the published light curve were analysed with the Wilson–Devinney code to derive the following masses and radii for the components of this system:             and     The solution shows that the system is in overcontact, as one would expect from the derived masses and the very short orbital period (∼1.4 d).  相似文献   
54.
The globule CB 34, which harbours a cluster of class 0 young stellar object (YSO) protostars, has been investigated through a multiline SO and SiO survey at millimetre wavelengths. The SO data reveal that the globule consists of three quiescent high-density (∼105 cm−3) clumps, labelled A, B and C, with sizes of ∼  0.2–0.3 pc  . The SiO data provide evidence for high-velocity gas across the globule. Most likely, the high-velocity gas is distributed in three distinct high-velocity outflows associated with the YSOs in each of the three clumps. High-velocity SO features have been detected only towards the two brightest SiO outflows. These broad SO components exhibit spatial and spectral distributions which are consistent with those of the SiO emission, so they can also be used as tracers of the outflows.
The comparison between the spatial and spectral properties of the SO and SiO emissions in the three clumps suggests different evolutionary stages for the embedded YSOs. In particular, the YSO associated with clump C exhibits some peculiarities, namely smaller SiO linewidths, lower SiO column densities, a lack of extended SiO structure and of SO wings, and the presence of a SO spatial distribution which is displaced with respect to the location of the YSO. This behaviour is well explained if the SiO and SO molecules which were produced at high velocities in the shocked region have been destroyed or slowed down because of the interaction with the ambient medium, and the chemistry is dominated again by low-temperature reactions. Thus our observations strongly suggest that the YSO in clump C is in a more evolved phase than the other members of the cluster.  相似文献   
55.
研究1类具有2个零特征根和1个4n2 2n 1阶奇点的2n 1次系统,并给出了极限环存在与否的条件。  相似文献   
56.
The present study employs a method for analysis of the sulfur isotopic composition of trace sulfate extracted from carbonates collected in Namibia in order to document secular variations in the sulfur isotopic composition of Neoproterozoic oceanic sulfate and to assess variations in the sulfur cycle that may have accompanied profound climatic events that have been described as the snowball Earth hypothesis. The carbonates in the Otavi Group of Northwest Namibia contain 3-295 ppm sulfate. Positive excursions, to a high of 40‰ (CDT), occur above the lower (Chuos Formation) and upper (Ghaub Formation) glacial intervals in the Rasthof and Maieberg cap carbonates, respectively. Positive excursions at the top of the Rasthof Formation (reaching 51‰) and within the overlying Gruis Formation (34‰) do not appear to correspond to glaciation. The δ34Ssulfate values within the Ombaatjie Formation exhibit shifts over relatively short stratigraphic intervals (tens of meters), varying between ∼15 and 25‰. Cap carbonates from Australia exhibit positive δ34Spyrite trends with amplitudes similar to those of Namibian δ34Ssulfate, although, more data are necessary to firmly establish these δ34S trends as global in nature. δ34Ssulfate excursions found in Namibian cap carbonates are consistent with the snowball Earth hypothesis in that they appear to reflect nearly complete reduction of sulfate in an isolated, anoxic global ocean, although, there are other mechanisms that may have facilitated these large shifts in δ34Ssulfate. Regardless, the low sulfate concentrations in Otavi carbonates, the high amplitude variability of the δ34Ssulfate curve, and the apparently full reduction of sulfate (as implied from δ34Spyrite data), even in strata low in Corg, suggest that Neoproterozoic oceanic sulfate concentrations were much lower than modern values. Additionally, the buildup of ferrous iron and banded-iron formations during the Sturtian glacial event would indicate that Fe supply exceeded sulfide availability during the glacials and/or that all sulfide was fixed and buried. This could be construed as further evidence in support of low oceanic sulfate (and sulfide) at this time.  相似文献   
57.
河北平原地下水硫酸盐34S和18O同位素演化特征   总被引:1,自引:0,他引:1  
地下水中硫酸盐的34Ss和18O在探寻地下水的水质演化规律、赋存环境特征方面具有重要的研究意义,笔者选取保定-河间-沧州-黄骅剖面采集深层地下水水样,分析测试了其主要阴阳离子含量、δ18O、δD、14C及δ34Sso42-和δ18Oso42-各项指标,在此基础上首次探讨了河北平原地下水中硫酸盐的硫、氧同位素分布特征与演化机理.研究发现研究区地下水硫酸盐的δ34Sso42-值沿地下水流向增大,δ18Oso42-值则在一个较小的范围内波动,最终接近一个常数值,二者间呈现较好的负相关关系;δ34Sso42-值随地下水14C年龄的增加而增加,δ34Sso42-则随地下水14C年龄的增加而趋于稳定;34Sso42-值与r(so42-)/r(C1-)的值呈负相关关系,δ18Oso42-值与r(SO42-)/r(C1-)的值则呈正相关关系.在研究区地下水中硫酸盐的34S和18O同位素的分布演变特征主要由SO42-和水之间的同位素交换反应、微生物硫酸盐的还原作用、硫化氢的再氧化作用所影响,其中微生物硫酸盐的还原作用的结果使地下水中的硫酸盐富集34S,SO42-和水之间的同位素交换反应是影响地下水的δ18Oso42-值的主导因素,使地下水的δ18Oso42-取决于地下水的氧同位素组成.  相似文献   
58.
The Nobeoka Thrust of Southwest Japan is an on‐land example of an ancient megasplay fault that provides an excellent record of deformation and fluid flow at seismogenic depths. The present study reports: (i) temporal stress changes for the seismogenic period of the Nobeoka Thrust; and (ii) spatial heterogeneities in driving pressure ratios P* obtained from mineral veins around the Nobeoka Thrust fault zone. Many quartz veins that filled mode I cracks can be observed in the hanging wall and footwall of the thrust. Inversion for stress orientation suggests that normal faulting dominated in both the hanging wall and footwall, with similar stress axis orientations in both. The orientation of σ3 for the estimated stress regime is parallel to the slip direction of the Nobeoka Thrust. The detected normal‐faulting‐type stress regimes likely resulted from post‐seismic stress buildup after megathrust earthquakes. The hanging wall of the Nobeoka Thrust has smaller P* values than the footwall. Two possible explanations are proposed for the observed spatial variations in the driving pore fluid pressure ratio, P*: spatial variations in pore fluid pressure Pf are directly responsible for P* variations, or P* variations are controlled by differences in mechanical properties between the hanging wall and footwall.  相似文献   
59.
This paper reports on the erosion, transport, and deposition processes associated with an overbank deposit formed by the flooding of the Abu River on July 28, 2013, in Yamaguchi City, Japan. At the study site, river flows overtopped the levee revetment upstream of a meander bend cutting it off and flowing back into the main channel downstream. In this sequential process, it deposited large amounts of sediments, ranging from mud to cobbles, on the floodplain. The surface of paddy fields adjacent to a railway line, located at the center of the affected floodplain, was severely eroded by the flood flows. Overbank deposits composed of both upstream finer sediments and eroded coarser terrestrial sediments are laid down in the affected area. Large amounts of pebbles and cobbles originating from the eroded terrestrial area formed a gravelly pile on top of the sand and gravel sediments derived from the river. This finding indicates that sands and gravels were deposited prior to the formation of the gravelly pile, probably before and during peak flood flows. An inverse grading structure is evident in the lower to middle part of these comparatively thick deposits, most likely due to differences in transport pattern between entrained terrestrial gravels and upstream finer sediments.  相似文献   
60.
Given the unquestioned impacts of recent/future environmental changes on human societies, it is reasonable to posit that past societal responses could be used as proxies of contemporaneous environmental forcing and might help identify the drivers of these, particularly where independent evidence of the effects of these events is inadequate. Such areas include Pacific oceanic islands for most of which there is evidence of a societal perturbation in the 14th and 15th centuries that saw the outbreak of region‐wide conflict, abandonment of coastal settlements and the abrupt end of long‐distance cross‐ocean voyaging networks. The contemporaneity of these effects across a vast region requires a driver that is external to particular island groups with the only possibility that of oceanic origin, most likely large waves (tsunamis or storm surges) or rapid sea‐level change. The explanation is less important than the principle that societal changes can be used as proxies for environmental activity.  相似文献   
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