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21.
Sequential extraction of Hg was performed in a core collected from intertidal area in Ulhas Estuary in order to characterize the downward distribution and diagenetic behavior of Hg in a polluted estuary. Concentration of total Hg ranged between 0.46 and 6.40 μg g−1 with significant decrease in surficial sediment as a result of closing of two Hg-cell based chlor-alkali plants. Results of sequential extraction showed that >65% Hg was strongly bound to organo-sulphur and inorganic sulphide species that are not bioavailable. Flux of only 18.8% of Hg was found compared to its value deposited on sediment–water interface. Hence, it is concluded that there is no significant diagenetic remobilization of Hg in Ulhas Estuary. This core also has been analyzed for 210Pb geochronology. The estimated sedimentation rate is 0.31 cm y−1 in the present sampling region. 相似文献
22.
《Chemie der Erde / Geochemistry》2019,79(1):178-187
In this research, we have worked on the evaluation of heavy metal contamination in the sediments taken from the intertidal zone of Asaluyeh region using Modified Community Bureau of Reference sequential extraction method (mBCR), the simplified bioaccessibility extraction test (SBET), and calculated enrichment factor (EF). Also, potential influencing factors including sediment characteristics that may affect the heavy metals bioavailability and bioaccessibility were investigated. mBCR extraction analysis indicated that among the metals, Mn, Zn, V, Cu, and Cd exhibit relatively higher mobility, while Ti, Pb, Cr, and Ni occur mainly in the residual fractions. Based on the mean values, the bioaccessibility of metals decreased in the order: Mn (50.01%)>Cd (46.26%)>Zn (14.61%)>V (13.97%)>Pb (10.88%)>Ni (9.2%)>Ti (8.43%)>Cr (6.66%)>Cu (6.23%). The obtained results from the principal component analysis (PCA), EF and mBCR extraction showed that most anthropogenic-derived metals with higher solubility are more bioaccessible compared to those of natural origin. Multiple linear regression analysis demonstrated that the main physicochemical variables of the sediment influencing the bioaccessibility of metals include cation exchange capacity (CEC), pH, and particle size fraction. 相似文献
23.
Camamu Bay (Bahia, Brazil) is an Environmental Protected Area with mangroves of economic and ecological importance. The objective of this study was to elucidate, through the distribution of the benthic macrofauna and its relationships with trace metals and bioavailabilty, if the current quality of the mangrove sediments of Camamu Bay is acceptable for the protection of aquatic life. Seven sampling stations were selected as representative of the meso-littoral region of Camamu Bay. It was found 581 macrobenthic organisms distributed in 38 species. The highest values of metals occurred at stations located in areas that influenced by barite extraction, while the lowest concentrations were found in areas with relatively lower anthropogenic influence. Analysis of acid volatile sulphide and simultaneously extracted metals showed the occurrence of the ratio SEM/AVS >1, indicative of possible bioavailability of metals, at only one station. The results suggested that Camamu Bay is a nearly pristine area. 相似文献
24.
This paper aims to determine the correlation between Cd, Cu and Pb concentration in the sediment and in five aquatic plants
sampled during wet, normal and dry seasons. Analyses of the sediment showed that concentrations of exchangeable Cd and Cd
after acid reduction were higher during the wet season (October) than on other sampling dates with mean values of 0.18 and
0.29 μg g−1, respectively. The concentration of Cu in the organic oxidation phase was higher in the normal season (January) than on other
sampling dates with a mean value of 11.1 μg g−1. The concentrations of exchangeable Pb and that in the residual phase were higher during the wet season than on other sampling
dates with mean values of 1.05 and 9.18 μg g−1, respectively. Cd and Pb concentrations in the leaves, stems and roots varied between sampling dates with a reduced concentration
during dry season (July) and the highest metal concentrations (Cd and Pb) during wet season. There were positive correlations
between Cd and Cu concentrations in the plant tissues (leaves, stems and roots) of most aquatic plants in the acid reduction
fraction. Conversely, there was no positive correlation between Pb concentration in the plant tissues of all aquatic plants
and the acid reduction fraction of the sediment. 相似文献
25.
Bioavailability of dissolved organic phosphorus compounds to typical harmful dinoflagellate Prorocentrum donghaiense Lu 总被引：4，自引：0，他引：4
The bioavailability of dissolved organic phosphorus (DOP) compounds to harmful alga Prorocentrum donghaiense Lu and its alkaline phosphatase activity (APA) were studied. Results showed that P. donghaiense could utilize the test DOP compounds such as glucose-6-phosphate (G-6-P), adenosine triphosphate (ATP) and ribonucleic acid (RNA) to sustain its growth. Nutrition between the test DOP compounds and orthophosphate was comparable. P. donghaiense could utilize intracellular phosphorus to sustain growth under depletion of dissolved phosphorus. Variation of APA in different test DOP compounds was addressed; the controlling mechanism of APA in different DOP media was discussed. 相似文献
26.
Yamini Gopalapillai Ismail I. Fasfous John D. Murimboh Tahir Yapici Parthasarathi Chakraborty Chuni L. Chakrabarti 《Aquatic Geochemistry》2008,14(2):99-116
Free metal ion concentration is generally considered a useful indicator of a metal’s bioavailability and ecotoxicity to aquatic
biota. This article reports the speciation of nickel in mining and municipal effluents from Sudbury (Ontario, Canada), and
also in model solutions containing a fully characterized laurentian fulvic acid (LFA) at environmentally relevant concentrations.
A column ion exchange technique (IET) using a cation exchange resin (Dowex 50W-X8) was applied to determine free nickel ion
concentrations. In model solutions, reasonable correlation was found between the predictions of an equilibrium-based computer
speciation code, Windermere Humic Aqueous Model (WHAM) VI, and the results obtained by IET at low nickel-to-fulvic acid ratios.
However at higher mole ratios, the WHAM VI predicted higher free nickel ion concentrations than IET. Only three out of six
effluent samples showed reasonable agreement between the IET and the WHAM VI results, indicating the need for further development
of IET for application to effluent waters. 相似文献
27.
Mercury speciation was performed in excess activated sewage sludge (ASS) and in marine sediments collected at the AAS disposal site off the Mediterranean coast of Israel in order to characterize the spatial and vertical distribution of different mercury species and assess their environmental impact. Total Hg (HgT) concentrations ranged between 0.19 and 1003ng/g at the polluted stations and 5.7 and 72.8ng/g at the background station, while the average concentration in ASS was 1181+/-273ng/g. Only at the polluted stations did HgT concentrations decrease exponentially with sediment depth, reaching background values at 16-20cm, the vertical distribution resulting from mixing of natural sediment with ASS solids and bioturbation by large populations of polycheates. Average Methyl Hg (MeHg) concentration in ASS was 39.7+/-7.1ng/g, ca. 3% of the HgT concentration, while the background concentrations ranged between 0.1 and 0.61ng/g. MeHg concentrations in surficial polluted sediments were 0.7-5.9ng/g (ca. 0.5% of the HgT) and decreased vertically, similar to HgT. A positive correlation between MeHg and Hg only at the polluted stations, higher MeHg concentrations at the surface of the sediment and not below the redoxline, and no seasonality in the concentrations suggest that the MeHg originated from the ASS and not from in situ methylation. By doing selective extractions, we found that ca. 80% of the total Hg in ASS and polluted sediments was strongly bound to amorphous organo-sulfur and to inorganic sulfide species that are not bioavailable. The fractions with potential bioaccessible Hg had maximal concentrations in the range in which biotic effects should be expected. Therefore, although no bioaccumulation was found in the biota in the area, the concentration in the polluted sediments are not negligible and should be carefully monitored. 相似文献
28.
Khairul N. Mohamed Sebastian Steigenberger Maria C. Nielsdottir Martha Gledhill Eric P. Achterberg 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(11):1049-1059
On voyages in the Iceland Basin in 2007 and 2009, we observed low (ca. 0.1 nM) total dissolved iron concentrations [dFe] in surface waters (<150 m), which increased with depth to ca. 0.2–0.9 nM. The surface water [dFe] was low due to low atmospheric Fe inputs combined with biological uptake, with Fe regeneration from microbial degradation of settling biogenic particles supplying dFe at depth. The organic ligand concentrations [LT] in the surface waters ranged between 0.4 and 0.5 nM, with conditional stability constants (log K′FeL) between 22.6 and 22.7. Furthermore, [LT] was in excess of [dFe] throughout the water column, and dFe was therefore largely complexed by organic ligands (>99%). The ratio of [LT]/[dFe] was used to analyse trends in Fe speciation. Enhanced and variable [LT]/[dFe] ratios ranging between 1.6 and 5.8 were observed in surface waters; the ratio decreased with depth to a more constant [LT]/[dFe] ratio in deep waters. In the Iceland Basin and Rockall Trough, enhanced [LT]/[dFe] ratios in surface waters resulted from decreases in [dFe], likely reflecting the conditions of Fe limitation of the phytoplankton community in the surface waters of the Iceland Basin and the high productivity in the Rockall Trough.Below the surface mixed layer, the observed increase in [dFe] resulted in a decrease of the [LT]/[dFe] ratios (1.2–2.6) with depth. This indicated that the Fe binding ligand sites became occupied and even almost saturated at enhanced [dFe] in the deeper waters. Furthermore, our results showed a quasi-steady state in deep waters between dissolved organic Fe ligands and dFe, reflecting a balance between Fe removal by scavenging and Fe supply by remineralisation of biogenic particles with stabilisation through ligands. 相似文献
29.
具有生物活性的元素Fe被认为限制了海洋生物生产力,其在海洋生态系统中的生物地球化学循环对全球碳循环起到调节作用,全球40％～50％的海洋因“高叶绿素低营养盐”(HNLC)“缺Fe”而初级生产力较低.然而,关于生物活性元素Fe的研究不仅涉及海洋科学,还与大气科学、环境科学、地球科学等学科紧密联系.近些年,围绕生物活性元素“Fe”开展的研究不仅是地球科学领域的前沿问题,还是海洋学家与环境学家共同关注的热点问题.目前,尽管对于生物活性元素Fe的研究已取得很大的进展,但模型、室内实验及野外观测之间仍存在很大的挑战与不确定性.系统地总结了生物活性元素Fe最重要的自然来源方式,详细介绍了影响生物活性元素Fe溶解度的主要因素,最后,对将来的工作提出建议,为我国未来开展类似的研究提供参考. 相似文献
30.
