库车坳陷侏罗系煤成气动力学模拟研究   总被引：1，自引：0，他引：1  

周强  李贤庆  杨园园  田辉  申家贵 《中国煤田地质》2006,18(1):24-27

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。  相似文献   

近地层O3和CO2浓度变化对冬小麦影响的数值模拟：Ⅱ模拟结果和分析   总被引：4，自引：2，他引：4  

郑昌玲  王春乙 《气象学报》2005,63(2):192-203

针对CO2和O3浓度变化对冬小麦影响,改进了农田生态系统碳氮生物化学模型(DNDC),并利用模型模拟了O3和CO2浓度变化对冬小麦生长发育和产量的影响,检验了模型的模拟效果.通过对原DNDC模型适用性的调整,使之适用于固城站,为进一步改进作物模型打下了可靠的基础.通过试验资料验证表明,模型较好地反映了O3和CO2浓度变化对冬小麦生长发育和产量形成的影响.通过敏感性分析得出,模型对温度变化反映灵敏;在CO2浓度倍增情况下,O3浓度变化对冬小麦的复合影响分析看出,一定浓度范围内,CO2可缓解O3对作物影响的负效应,O3对CO2带来的正效应有削弱作用.  相似文献   

dC Variations in Late Jurassic Carbonates, Jaisalmer Formation, Western India     

Anil Maheshwari  A.N. Sial  S.C. Mathur  R.P. Tripathi 《Gondwana Research》2003,6(4):931-934

The carbon isotope measurements, carried out on subsurface carbonate samples from Oxfordian Jaisalmer Formation, western India, yield positive d¹³C values up to +3.17%. The most positive Oxfordian C-isotope value corresponds to the carbon isotope excursion measured in samples from from other late Jurassic basins of world. The latest Oxfordian C-isotope values of Jaisalmer Basin fluctuate around 2% while the C-isotope values of 1.50% mark the base of Kimmeridgian. The Oxfordian C-isotope excursion appears to correspond to a time of overall increased organic carbon burial triggered by increased nutrient transfer from continents to oceans during a time of rising global sea level.  相似文献   

The climatic impacts of land surface change and carbon management, and the implications for climate-change mitigation policy   总被引：4，自引：0，他引：4  

Gregg Marland  Roger A. Pielke Sr. 《Climate Policy》2003,3(2):149-157

Strategies to mitigate anthropogenic climate change recognize that carbon sequestration in the terrestrial biosphere can reduce the build-up of carbon dioxide in the Earth’s atmosphere. However, climate mitigation policies do not generally incorporate the effects of these changes in the land surface on the surface albedo, the fluxes of sensible and latent heat to the atmosphere, and the distribution of energy within the climate system. Changes in these components of the surface energy budget can affect the local, regional, and global climate. Given the goal of mitigating climate change, it is important to consider all of the effects of changes in terrestrial vegetation and to work toward a better understanding of the full climate system. Acknowledging the importance of land surface change as a component of climate change makes it more challenging to create a system of credits and debits wherein emission or sequestration of carbon in the biosphere is equated with emission of carbon from fossil fuels. Recognition of the complexity of human-caused changes in climate does not, however, weaken the importance of actions that would seek to minimize our disturbance of the Earth’s environmental system and that would reduce societal and ecological vulnerability to environmental change and variability.  相似文献   

Replacing carbon lost from forests: an assessment of insurance, reserves, and expiring credits     

Susan Subak 《Climate Policy》2003,3(2):107-122

Concern over the “non-permanence” or reversibility of carbon sequestration projects has been prominent in discussions over how to develop guidelines for forest project investments under the Clean Development Mechanism (CDM) of the UNFCCC Kyoto Protocol. Accordingly, a number of approaches have been proposed that aim to help ensure that parties do not receive credit for carbon that is lost before project obligations are fulfilled. These approaches include forest carbon insurance, land reserves, and issuance of expiring credits. The potential costs of each of these different approaches are evaluated using a range of assumptions about project length, risk and discount rate, and a comparison of costs is ventured based on the estimated reduction in value of these credits compared with uninsured, and permanent credits. Obstacles to participation in the different approaches are discussed related to problems of long-term commitments, project scale, rising replacement costs, and low credit value. It is concluded that a system of expiring credits, which could be coupled with insurance or reserves, could guarantee obligations that span time-scales longer than that of conventional insurance policies while maintaining incentives for long-term sequestration.  相似文献   

Length-specific carbon content of theDaphnia population in a large subalpine lake, Lago Maggiore (Northern Italy): The importance of seasonality     

Marina Manca  Patrizia Comoli  Teresa Spagnuolo 《Aquatic Sciences - Research Across Boundaries》1997,59(1):48-56

We compared three methods for calculating the standing stock biomass ofDaphnia hyalina galeata population in Lago Maggiore during a single year. We applied body length/carbon regression equations (LCR) obtained under controlled laboratory conditions and directly from field data on carbon and body length to field data on length-specific abundance. Laboratory-derived equations satisfactorily described our field estimates of length-specific carbon content in spring. As the length-standardized carbon content decreased exponentially along the season, we included time of the year as an auxiliary variable, and tested whether it affected slope, intercept or both. The decrease had no effect on slope but reduced the intercept of the LCR. We also calculated biomass, using a single mean value from the literature. By comparing the results with those obtained by simple conversion of individuals number into carbon we might discriminate between the effect of changes in the size frequency distribution of the population and the decrease with time of the length-standardized carbon content. Although we tested the different models for non-ovigerous females, the results did not change when we included also data on females with eggs in the first three developmental stages, whereas they changed substantially when we included females with embryos. We formulate two hypotheses to explain this result and discuss possible implications for the calculation of the standing stock biomass ofDaphnia population.  相似文献   

The Influence of Advection on the Short Term CO 2 -Budget in and Above a Forest Canopy     

C. Feigenwinter  C. Bernhofer  R. Vogt 《Boundary-Layer Meteorology》2004,113(2):201-224

An experimental micrometeorological set-up was established at the CARBOEURO-FLUX site in Tharandt, Germany, to measure all relevant variables for the calculation of the vertical and horizontal advective fluxes of carbon dioxide. The set-up includes two auxiliary towers to measure horizontal and vertical CO₂ and H₂O gradients through the canopy, and to make ultrasonic wind measurements in the trunk space. In combination with the long-term flux tower an approximately even-sided prism with a typical side-length of 50 m was established. It is shown that under stable (nighttime) conditions the mean advective fluxes have magnitudes on the same order as the daily eddy covariance (EC) flux, which implies that they play a significant, but not yet fully understood, role in the carbon budget equation. The two advective fluxes are opposite and seem to cancel each other at night (at least for these measurements). During the day, vertical advection tends to zero, while horizontal advection is still present implying a flow of CO₂ out of the control volume. From our measurements, a mean daily gain of 2.2 gC m^–2 d^–1 for the horizontal advection and a mean daily loss of 2.5 gC m^–2d^–1 for the vertical advection is calculated for a period of 20 days. However the large scatter of the advective fluxes has to be further investigated. It is not clear yet whether the large variability is natural or due to measurement errors and conceptual deficiencies of the experiment. Similar results are found in the few comparable studies.  相似文献   

徐州地区下古生界碳酸盐岩的碳、氧同位素研究   总被引：12，自引：2，他引：12  

桑树勋  郑永飞张华徐磊  范炳恒 《岩石学报》2004,20(3):707-716

在已有的对徐州地区下古生界碳酸盐岩详细岩石学研究基础上，系统测试了碳酸盐岩方解石和白云石的碳、氧同位素组成特征；地球化学和岩石学研究相结合，综合提取了碳酸盐岩碳、氧同位素组成的沉积、成岩地质信息；初步探讨了同位素组成的地层变化及其意义。研究结果表明：碳酸盐岩碳同位素组成特征可以指示沉积环境及其演化，开阔陆表海、灰质障壁砂坝、局限陆表海、潮下带、潮渠、藻坪诸沉积相间碳酸盐岩的δ^13C值表现出规律性变化，碳同位素组成变化曲线上的显著正偏移与海侵有关；碳酸盐岩氧同位素组成对成岩环境及其演化有明显响应，淡水成岩环境、潮上成岩环境、潮间成岩环境、潮下成岩环境和埋藏成岩环境具有不同的碳酸盐岩氧同位素组成特征；徐州地区大北望寒武系剖面地层界线附近都有碳、氧同位素组成变化的特征显示，研究工作证实了徐州地区下古生界同位素地层划分的可行性。  相似文献   

Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)   总被引：2，自引：0，他引：2  

Yongqiang Xiong  Ansong Geng  Jingzhong Liu 《Chemical Geology》2004,213(4):325-338

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.  相似文献   

Inclusions in diamonds from the K14 and K10 kimberlites, Buffalo Hills, Alberta, Canada: diamond growth in a plume?     

Rondi M. Davies  William L. Griffin  Suzanne Y. O''Reilly  Tom E. McCandless 《Lithos》2004,77(1-4):99-111

Analyses of mineral inclusions, carbon isotopes, nitrogen contents and nitrogen aggregation states in 29 diamonds from two Buffalo Hills kimberlites in northern Alberta, Canada were conducted. From 25 inclusion bearing diamonds, the following paragenetic abundances were found: peridotitic (48%), eclogitic (32%), eclogitic/websteritic (8%), websteritic (4%), ultradeep? (4%) and unknown (4%). Diamonds containing mineral inclusions of ferropericlase, and mixed eclogitic-asthenospheric-websteritic and eclogitic-websteritic mineral associations suggests the possibility of diamond growth over a range of depths and in a variety of mantle environments (lithosphere, asthenosphere and possibly lower mantle).

Eclogitic diamonds have a broad range of C-isotopic composition (δ¹³C=−21‰ to −5‰). Peridotitic, websteritic and ultradeep diamonds have typical mantle C-isotope values (δ¹³C=−4.9‰ av.), except for two ¹³C-depleted peridotitic (δ¹³C=−11.8‰, −14.6‰) and one ¹³C-depleted websteritic diamond (δ¹³C=−11.9‰). Infrared spectra from 29 diamonds identified two diamond groups: 75% are nitrogen-free (Type II) or have fully aggregated nitrogen defects (Type IaB) with platelet degradation and low to moderate nitrogen contents (av. 330 ppm-N); 25% have lower nitrogen aggregation states and higher nitrogen contents (30% IaB; <1600 ppm-N).

The combined evidence suggests two generations of diamond growth. Type II and Type IaB diamonds with ultradeep, peridotitic, eclogitic and websteritic inclusions crystallised from eclogitic and peridotitic rocks while moving in a dynamic environment from the asthenosphere and possibly the lower mantle to the base of the lithosphere. Mechanisms for diamond movement through the mantle could be by mantle convection, or an ascending plume. The interaction of partial melts with eclogitic and peridotitic lithologies may have produced the intermediate websteritic inclusion compositions, and can explain diamonds of mixed parageneses, and the overlap in C-isotope values between parageneses. Strong deformation and extremely high nitrogen aggregation states in some diamonds may indicate high mantle storage temperatures and strain in the diamond growth environment. A second diamond group, with Type IaA–IaB nitrogen aggregation and peridotitic inclusions, crystallised at the base of the cratonic lithosphere. All diamonds were subsequently sampled by kimberlites and transported to the Earth's surface.  相似文献