‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry     

Haosheng Wu  Roman Bttger  Frdric Couffignal  Jens Gutzmer  Joachim Krause  Frans Munnik  Axel D. Renno  Ren Hübner  Michael Wiedenbeck  Ren Ziegenrücker 《Geostandards and Geoanalytical Research》2019,43(4):531-541

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.  相似文献   

Discussion on establishing monitoring networks for temperature fields of shallow thermal energy in Shandong,China     

ZHOU Bo  WEI Shan-ming  WANG Tao  NIE Yu-peng  WANG Chuan-qi 《地下水科学与工程》2019,7(1):86-93

In the recent decade, the construction projects related to shallow geothermal energy engineering have undergone rapid development in Shandong Province. The predominant type of these developments and applications was heat exchange through buried tubes and the main targets were residential and office buildings. However, an overwhelming majority of the completed geothermal heat pump projects lacked monitoring devices so that they were unable to comprehensively reflect the background values for the geothermal fields within the province and few researches were conducted on their influence on the geological environment. In this paper, locations for monitoring shallow geothermal energy and their validity of the monitoring point deployment were studied in view of the development and application status as well as geological background conditions of various projects located in multiple cities providing data support for analyzing the fluctuation trend and influence of large-scale shallow geothermal energy applications on the shallow geothermal and the feasibility and parameter designs of newly built systems in Shandong Province in the future.  相似文献   

夏季我国干旱、半干旱区陆面过程能量平衡及其局地大气环流   总被引：28，自引：10，他引：18  

布和朝鲁  纪立人  崔茂常 《气候与环境研究》2002,7(1):61-73

利用NCEP资料分析得出,夏季我国干旱,半干旱区在整个欧亚大陆上是陆面感热通量最强的地方,与此对应的陆面潜热通量则最弱.陆面所接收的太阳短波辐射主要以感热和长波辐射的能量形式释放.该区降水量很少,降水量的年际变率也很弱;因此,该区的陆面热量通量都显出很弱的年际变率;然而,这些通量的年代际变率信号则比较显著.我国干旱、半干旱区大气环流的热力过程与其陆面过程特征密切相关.该区对流层大气的辐射冷却很强,达-3 K d-1.由于缺乏水汽和上升运动,大尺度凝结加热率、深对流加热率、浅对流加热率都非常弱.因此,600hPa以上的大气以绝热下沉加热来平衡辐射冷却;600hPa以下,陆面感热引起的垂直扩散加热率非常强,多达8 K d-1,它除了平衡辐射冷却以外还制造对流层低层的对流运动,以绝热上升冷却来平衡多余的垂直扩散加热.总之,我国干旱、半干旱区的陆面过程特征决定了该区大气运动的特殊垂直结构,即对流层低层对流上升运动及其上层的下沉运动.我国干旱、半干旱区陆面能量平衡及其局地大气环流的年代际变率,是全球气候系统年代际变率的必然结果.  相似文献   

Hypo‐elastic and hyper‐elastic equations of soils          下载免费PDF全文

Koichi Hashiguchi 《国际地质力学数值与分析法杂志》2018,42(13):1554-1564

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Towards Regional Synergy: Reconciling Rangeland Ecological Functioning with Forage Production of Cultivated Pasture     

SHI Peili  ZHANG Xianzhou 《资源与生态学报(英文版)》2020,11(3):247-252

Animal husbandry and crop farming are specialized for development in separate areas on the Tibetan Plateau. Such a pattern of isolation has led to current concerns of rangeland and farming system degradation due to intensive land use. The crop-livestock integration, however, has been proven to increase food and feed productivity thorough niche complementarity, and is thereby especially effective for promoting ecosystem resilience. Regional synergy has emerged as an integrated approach to reconcile rangeland livestock with forage crop production. It moves beyond the specialized sectors of animal husbandry and intensive agriculture to coordinate them through regional coupling. Therefore, crop-livestock integration (CLI) has been suggested as one of the effective solutions to forage deficit and livestock production in grazing systems. But it is imperative that CLI moves forward from the farm level to the regional scale, in order to secure regional synergism during agro-pastoral development. The national key R & D program, Technology and Demonstration of Recovery and Restoration of Degraded Alpine Ecosystems on the Tibetan Plateau, aims to solve the problems of alpine grassland degradation by building up a grass-based animal husbandry technology system that includes synergizing forage production and ecological functioning, reconciling the relationship between ecology, forage production and animal husbandry, and achieving the win-win goals of curbing grassland degradation and changing the development mode of animal husbandry. It is imperative to call for regional synergy through integrating ecological functioning with ecosystem services, given the alarming threat of rangeland degradation on the Tibetan Plateau. The series of papers in this issue, together with those published previously, provide a collection of rangeland ecology and management studies in an effort to ensure the sustainable use and management of the alpine ecosystems.  相似文献   

Cotton canopy reflectance under variable solar zenith angles: Implications of use in evapotranspiration models     

Christopher M. U. Neale  Maria P. Gonzalez-Dugo  Angelica Serrano-Perez  Isidro Campos  Luciano Mateos 《水文研究》2021,35(6):e14162

Evapotranspiration (ET) is an important parameter in hydrologic processes and modelling. In agricultural watersheds with competing uses of fresh water including irrigated agriculture, estimating crop evapotranspiration (ET_c) accurately is critical for improving irrigation system and basin water management. The use of remote sensing-based basal crop coefficients is becoming a common method for estimating crop evapotranspiration for multiple crops over large areas. The Normalized Difference Vegetation Index (NDVI) and the Soil Adjusted Vegetation Index (SAVI), based on reflectance in the red and near-infrared bands, are commonly used for this purpose. In this paper, we examine the effects of row crop orientation and soil background darkening due to shading and soil surface wetness on these two vegetation indices through modelling, coupled with a field experiment where canopy reflectance of a cotton crop at different solar zenith angles, was measured with a portable radiometer. The results show that the NDVI is significantly more affected than the SAVI by background shading and soil surface wetness, especially in north–south oriented rows at higher latitudes and could lead to a potential overestimation of crop evapotranspiration and irrigation water demand if used for basal crop coefficient estimation. Relationships between the analysed vegetation indices and canopy biophysical parameters such as crop height, fraction of cover and leaf area index also were developed for both indices.  相似文献   

A review of the impacts of pumped hydro energy storage construction on subalpine and alpine biodiversity: lessons for the Snowy Mountains pumped hydro expansion project     

Anna Normyle  Jamie Pittock 《The Australian geographer》2020,51(1):53-68

ABSTRACT

The Australian government’s proposal to expand the Snowy Hydro Scheme to include a second pumped hydro energy storage (PHES) system, and support for feasibility studies for PHES in Tasmania, offer an opportunity to incorporate more intermittent renewable energy generation into the National Energy Market. However, the infrastructure construction required for PHES expansion may have negative effects for biodiversity in subalpine and alpine areas. To identify the potential effects of PHES on biodiversity in Kosciuszko National Park (KNP), this systematic literature review assesses: (i) the key environmental disturbances likely to arise from PHES construction; and (ii) the specific impacts of these construction processes on biodiversity in subalpine and alpine environments. We find that the effects of PHES construction-related disturbances are likely to be negative for subalpine and alpine biodiversity, with impacts including the proliferation of exotic flora, habitat loss resulting from vegetation clearing, altered landscape hydrology and reduced water quality. Management recommendations to limit these impacts are provided and further research is recommended to assess: (i) the effects of PHES on fish populations in alpine reservoirs; (ii) the utility of spoil as artificial habitat for endemic fauna; and (iii) the chemical and physical impacts of spoil dumping in alpine reservoirs.  相似文献   

Magnitude of latent heat in thermally loaded clays     

Sergio Samat  Laurent Brochard  Ioannis Stefanou 《国际地质力学数值与分析法杂志》2020,44(14):1926-1957

Temperature changes are known to induce specific couplings in clay, in particular, an anomalously high thermal pressurization in undrained conditions or a thermal compaction in drained conditions, both of which are potential threats for the mechanical stability and sealing capacity of the geomaterials. Thermodynamical analysis of those peculiar thermomechanical couplings points to a potentially important latent energy, which in turn could limit the temperature change upon heating or cooling. The direct measurement of latent energy developed during a laboratory geomechanical test is challenging. Instead, proper identification of thermal hardening in conventional experiments with temperature changes provides an alternative route to estimate latent energy. In this work, existing laboratory thermomechanical tests of clays are analyzed with a rigorous thermodynamic framework to quantify the magnitude of latent energy in thermomechanically loaded clays. A thermodynamically consistent constitutive model for fully saturated clays that combines two key features, (a) the temperature dependence of the blocked energy and (b) the framework of bounding plasticity, is proposed. The performance of the model is validated by reproducing results obtained in laboratory tests for Boom and Opalinus clays. The thermomechanical loads considered to validate the model performance were then used to estimate the percentage of work that remains latent in the clayey material during plastic yielding. We find that the magnitude of latent energy is quite significant, typically a few tens of percent of the total dissipated energy, and increases significantly with temperature. Accordingly, it is expected to play an important role in the thermomechanical response of clays.  相似文献   

Energy flux partitioning and evapotranspiration in a sub‐alpine spruce forest ecosystem          下载免费PDF全文

Zhu Gaofeng  Lu Ling  Su Yonghong  Wang Xufeng  Cui Xia  Ma Jinzhu  He Jianhua  Zhang Kun  Li Changbin 《水文研究》2014,28(19):5093-5104

In this study, we examined the year 2011 characteristics of energy flux partitioning and evapotranspiration of a sub‐alpine spruce forest underlain by permafrost on the Qinghai–Tibet Plateau (QPT). Energy balance closure on a half‐hourly basis was H + λE = 0.81 × (R_n ? G ? S) + 3.48 (W m^?2) (r² = 0.83, n = 14938), where H, λE, R_n, G and S are the sensible heat, latent heat, net radiation, soil heat and air‐column heat storage fluxes, respectively. Maximum H was higher than maximum λE, and H dominated the energy budget at midday during the whole year, even in summer time. However, the rainfall events significantly affected energy flux partitioning and evapotranspiration. The mean value of evaporative fraction (Λ = λE/(λE + H)) during the growth period on zero precipitation days and non‐zero precipitation days was 0.40 and 0.61, respectively. The mean daily evapotranspiration of this sub‐alpine forest during summer time was 2.56 mm day^?1. The annual evapotranspiration and sublimation was 417 ± 8 mm year^?1, which was very similar to the annual precipitation of 428 mm. Sublimation accounted for 7.1% (30 ± 2 mm year^?1) of annual evapotranspiration and sublimation, indicating that the sublimation is not negligible in the annual water balance in sub‐alpine forests on the QPT. The low values of the Priestley–Taylor coefficient (α) and the very low value of the decoupling coefficient (Ω) during most of the growing season suggested low soil water content and conservative water loss in this sub‐alpine forest. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

The impacts of mountain pine beetle disturbance on the energy balance of snow during the melt period          下载免费PDF全文

Christopher M. Welch  Paul C. Stoy  F. Aaron Rains  Aiden V. Johnson  Brian L. McGlynn 《水文研究》2016,30(4):588-602

Mountain snowpacks provide most of the annual discharge of western US rivers, but the future of water resources in the western USA is tenuous, as climatic changes have resulted in earlier spring melts that have exacerbated summer droughts. Compounding changes to the physical environment are biotic disturbances including that of the mountain pine beetle (MPB), which has decimated millions of acres of western North American forests. At the watershed scale, MPB disturbance increases the peak hydrograph, and at the stand scale, the ‘grey’ phase of MPB canopy disturbance decreases canopy snow interception, increases snow albedo, increases net shortwave radiation, and decreases net longwave radiation versus the ‘red’ phase. Fewer studies have been conducted on the red phase of MPB disturbance and in the mixed coniferous stands that may follow MPB‐damaged forests. We measured the energy balance of four snowpacks representing different stages of MPB damage, management, and recovery: a lodgepole pine stand, an MPB‐infested stand in the red phase, a mixed coniferous stand (representing one successional trajectory), and a clear‐cut (representing reactive management) in the Tenderfoot Creek Experimental Forest in Montana, USA. Net longwave radiation was lower in the MPB‐infested stand despite higher basal area and plant area index of the other forests, suggesting that the desiccated needles serve as a less effective thermal buffer against longwave radiative losses. Eddy covariance observations of sensible and latent heat flux indicate that they are of similar but opposite magnitude, on the order of 20 MJ m^?2 during the melt period. Further analyses reveal that net turbulent energy fluxes were near zero because of the temperature and atmospheric vapour pressure encountered during the melt period. Future research should place snow science in the context of forest succession and management and address important uncertainties regarding the timing and magnitude of needlefall events. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献