矿物热敏参数测试仪及其在地质找矿中的应用     

赵亨达  王忠荣 《岩石矿物学杂志》1994,13(2):175-186

介绍了国内外第一台矿物热敏参数测试仪研制的原理、应用范围和对一些金属矿物、半导体矿物的测试情况以及仪器在浙江、赣南等地区金矿找矿中的初步应用。  相似文献   

A Decametric Scale Investigation of the Gravitational Constant     

M. Oldham  F. J. Lowes  R. J. Edge 《Geophysical Journal International》1993,113(1):83-94

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Prediction of the abiotic degradability of organic compounds in the troposphere     

Hans Güsten  Leo Klasinc  Dubravko Marić 《Journal of Atmospheric Chemistry》1984,2(1):83-93

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.  相似文献   

FTIR studies of reactions between the nitrate radical and haloethenes     

I. M. W. Noremsaune  J. Hjorth  C. J. Nielsen 《Journal of Atmospheric Chemistry》1995,21(3):223-250

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.  相似文献   

The radio frequency dielectric properties of the stratified UG1–UG2 geological unit in the Bushveld Complex     

Marc Rütschlin  Johannes H. Cloete  Iain M. Mason  Keith D. Palmer   《Journal of Applied Geophysics》2007,62(4):354-360

A new measurement technique enables the complex dielectric properties of the geological strata comprising the UG1–UG2 (Upper Group 1–Upper Group 2) unit of the Bushveld Complex in South Africa to be determined with unprecedented detail at radio frequencies (RF). Results of non-destructive laboratory measurements of representative diamond drill core samples from the UG1–UG2 unit are presented at 25 MHz. These data establish that the UG1 and UG2 chromitite layers are embedded in rock strata (norite, pyroxenite and anorthosite) which are translucent in the HF spectral band, whereas the chromitite layers themselves exhibit significant velocity contrast, making them good radar reflectors. The data presented here is useful for calibration of the radar system, and for predicting the range and resolution performance of borehole radars operating in both the hanging and footwalls of the economically important platiniferous UG2 reef.  相似文献   

可变电荷土壤和恒电荷土壤与氢离子相互作用机理   总被引：2，自引：4，他引：2  

朱茂旭  蒋新  杨杰文  季国亮  王芳 《地球化学》2001,30(2):194-199

研究了可变电荷土壤和恒电荷土壤与H相互作用的机理，并比较了它们之间的差别，研究结果表明，氢离子输入土壤后可以转化为表面正电荷，可溶性铝和可交换性酸，但是由于土壤的组成和性质不同，不同土壤中H＋三种去向的贡献不同。H＋转化为表面正电荷是由于土壤表面Fe-OH,Al-OH的质子化造成的，因此H＋转化为表面正电荷的能力与土壤中氧化铁的含量密切相关，从而可变电荷土壤中H＋转化为表面正电荷的贡献比恒电荷土壤中的大。H＋转化为可溶性铝的能力与土教育部 的矿物组成密切相关，随着H＋输入量的增加，土壤中可溶性铝的含量也增加。可变电荷土壤中可溶性铝增加的顺序为红壤＞赤红壤＞铁质砖红壤，在H＋的加入量小于15mmol/kg时，黄棕壤的可溶性铝介于红壤和赤红壤之间，当H＋的加入量大于约15mmol/kg时，黄棕壤的可溶性铝略小于赤红壤，棕壤的可溶性铝明显小于红壤和赤红壤，但比铁质砖红壤高，恒电荷土壤的可变性酸量明显大于可变电荷土壤，但从总的看来，H＋加入量的变化对可交换性酸量的影响不大。  相似文献   

Delineation of sulphide ore-zones by borehole radar tomography at Hellyer Mine, Australia     

Binzhong Zhou  Peter K. Fullagar   《Journal of Applied Geophysics》2001,47(3-4)

Velocity and absorption tomograms are the two most common forms of presentation of radar tomographic data. However, mining personnel, geophysicists included, are often unfamiliar with radar velocity and absorption. In this paper, general formulae are introduced, relating velocity and attenuation coefficient to conductivity and dielectric constant. The formulae are valid for lossy media as well as high-resistivity materials. The transformation of velocity and absorption to conductivity and dielectric constant is illustrated via application of the formulae to radar tomograms from the Hellyer zinc–lead–silver mine, Tasmania, Australia. The resulting conductivity and dielectric constant tomograms constructed at Hellyer demonstrated the potential of radar tomography to delineate sulphide ore zones.  相似文献   

混合物电导率和介电常数的研究   总被引：2，自引：0，他引：2       下载免费PDF全文

李剑浩 《地球物理学报》1996,39(Z1):364-370

应用电场理论研究混合物的电性，得出了混合物的电导率公式和介电常数公式．这一结果表明：混合物的电导率决定于混合物各成分电导率的均值和方差；混合物的介电常数决定于混合物各成分介电常数的均值和方差．作为所得结果的应用，给出了岩石的电导率公式和介电常数公式．  相似文献   

1962—1986年JYD1968.0地极坐标的均匀化及其与BIH的比较   总被引：2，自引：0，他引：2  

陆佩珍  须同祺 《测绘学报》1995,24(2):67-72

本文研究了１９６２－１９８６年ＪＹＤ１９６８．０地极坐标均匀中星表系统差，章动系列的变动和光行星常数变动的影响，并将经过改正后的ＪＹＤ１９６８．０地极坐标系统和ＢＩＨ系统作了比较。  相似文献   

IP效应对电磁感应响应的影响研究     

游子余 《矿产与地质》1993,7(2):140-151

严密的推理和大量精确的计算结果,揭示了IP效应对EM响应的影响.在野外常见的极化条件下,在电磁法工作频率范围(1～1000Hz)内,绝对影响过极大值.相对影响可达10%以上.充电率m越大.极化时间常数T对球体本身的感应时间常数r之比越小、频率响应系数c越小.影响越大,山响的频率越高.  相似文献